纺织学报 ›› 2023, Vol. 44 ›› Issue (05): 220-227.doi: 10.13475/j.fzxb.20220403902

• 综合述评 • 上一篇    下一篇

液体分散染料研发技术现状及其应用前景

艾丽1,2, 朱亚伟3()   

  1. 1.武汉纺织大学 化学与化工学院, 湖北 武汉 430200
    2.武汉纺织大学 湖北省生物质纤维与生态染整重点实验室, 湖北 武汉 430200
    3.苏州大学 现代丝绸国家工程实验室, 江苏 苏州 215123
  • 收稿日期:2022-04-12 修回日期:2023-02-15 出版日期:2023-05-15 发布日期:2023-06-09
  • 通讯作者: 朱亚伟(1963—), 男, 教授, 博士。主要研究方向为纺织化学的微量聚合系统研究及产业化。E-mail:yaweizhu@suda.edu.cn。
  • 作者简介:艾丽(1985—), 女, 讲师, 博士。主要研究方向为节能减排印染新技术及精细功能化学品。

Technology progress and application prospects of liquid disperse dyes

AI Li1,2, ZHU Yawei3()   

  1. 1. College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing, Wuhan Textile University, Wuhan, Hubei 430200, China
    3. National Engineering Laboratory for Modern Silk, Soochow University, Suzhou, Jiangsu 215123, China
  • Received:2022-04-12 Revised:2023-02-15 Published:2023-05-15 Online:2023-06-09

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摘要：

针对液体分散染料明显区别于粉状分散染料的应用性能和生态环保性,简述了液体分散染料发展历程和染料研磨技术要点,从染料应用性能方面评述了液体分散染料的质量控制因素及分析了已建立的液体分散染料稳定性快速评价指标的合理性,阐述了液体分散染料替代粉状分散染料的应用进展及连续热熔染色的新用途和需要解决的新问题。指出:液体分散染料应建立区别于粉状分散染料的稳定性和应用性能相协调的评价指标及质量标准;染色中选择较小的轧槽容积和均匀轧车以及增加轧前的喷淋装置都有利于染料对织物的渗透和织物着色均匀性;同时,研究集染色和功能性于一浴的功能液体分散染料,将是一种可从源头满足印染行业的重大节能减排技术需求。

关键词: 液体分散染料, 热熔染色, 分散剂, 液体染料稳定性, 生态染色, 节能减排

Abstract:

Significance Disperse dyes are special dyes for polyester fiber dyeing, commercially available mainly in powder and liquid forms. Powdered disperse dyes are widely used because of their excellent storage and application stability, while liquid disperse dyes are restricted by their stability. In recent years, with the great demand for energy conservation and emission reduction in printing and dyeing, liquid disperse dyes have attracted much attention, because of the advantages over the powdered disperse dyes in higher utilization rate of dye, low discharge of wastewater and waste residue and low energy consumption. Although the stability of liquid disperse dyes restricts its development to a certain extent, with the progress of the preparation technology of liquid disperse dyes, the stability has been effectively improved, and has been gradually replacing the traditional powdered disperse dyes.

Progress The lapping technology of liquid disperse dyes were briefly introduced. Selecting suitable anionic/non-ionic surfactants and anti-sedimentation agents was recognized as the key factor to prepare liquid disperse dyes with excellent stability and application performance. The main processing parameters affecting the properties of liquid disperse dyes were analyzed, and the influence of rheological property and ambient temperature on the stability of liquid disperse dyes were clarified. As the second attempt, the principle of high temperature dispersion, low temperature dispersion and double electric layer diffusion of liquid disperse dyes were analyzed. It was indicated that the viscosity increasing temperature (T0 value) and the absorbance change rate of water dilution (A10) could be used as indexes to evaluate rapidly the stability of liquid dyes. Then, the energy conservation and environmental friendliness and advantages of liquid disperse dyes in high temperature and high pressure dyeing, round mesh and screen printing are analyzed, and the new applications in continuous hot melt dyeing are analyzed, and the prospect of dyeing and finishing in the same bath processing was pointed out.

Conclusion and Prospect Although the preparation process of liquid disperse dyes is similar to that of powdered disperse dyes, liquid disperse dyes use less water and a small amount of additives (anionic/non-ionic mixture) as fillers. The difference in the performance of the two types of disperse dyes leads to the realization of low water consumption and near-zero emission printing and dyeing technology of liquid disperse dye, which could form a major energy conservation and emission reduction technology to meet the needs of printing and dyeing industry from the source. Liquid disperse dyes have been widely used, but their potential advantages have not been fully utilized. Therefore, the establishment of liquid disperse dye commodity standards, control of dye standardized quality, research and development of new bath dyeing and functional finishing technology are imperative to meet our 'carbon emissions and carbon neutrality' source pollution control printing and dyeing technology needs.

Key words: liquid disperse dye, hot melt dyeing, dispersant, liquid dye stability, eco-dyeing, energy conservation and emission reduction

中图分类号: 

  • TS194.43

图1

液体染料的相互作用"

图2

液体分散染料的流变类型 注:C1为起始黏度系数;C2为流体类型系数;C3为黏度变化系数;C4为剪切速率指数。"

图3

温度对液体分散染料黏度的影响"

[1] 艾丽, 朱亚伟. 液体分散染料的技术进步及应用[J]. 印染, 2019, 45(24): 47-52.
AI Li, ZHU Yawei. The development of liquid disperse dye and its application[J]. China Dyeing & Finishing, 2019, 45(24): 47-52.
[2] 丁志平. 一种环保型染料印花免蒸免洗浆料: ZL 20071001976.1[P]. 2009-2-07.
DING Zhiping. Environment-friendly dye printing non-steaming and non-washing printing paste:ZL 20071 001976.1[P]. 2009-2-07.
[3] 丁志平, 苗海青. 分散染料免蒸洗印花工艺: ZL 201010237182.6[P]. 2012-2-08.
DING Zhiping, MIAO Haiqing. Free-steaming and free-washing printing process with disperse dye: ZL 201010237182.6[P]. 2012-2-08.
[4] 丁志平, 苗海青. 分散染料免蒸洗印花探讨[J]. 丝绸, 2010(11): 62.
DING Zhiping, MIAO Haiqing. Discuss on non-steam and non-wash printing with disperse dye[J]. Journal of Silk, 2010(11): 62.
[5] 黄燕珠, 张亚坤, 黄丽珍. 分散染料色浆免蒸化水洗印花工艺[J]. 针织工业, 2019(6): 42-45.
HUANG Yanzhu, ZHANG Yakun, HUANG Lizhen. Color paste free-steaming and free-washing printing process of disperse dyes[J]. Knitting Industries, 2019(6): 42-45.
[6] 魏奕雯. 涤纶织物分散染料免蒸洗印花工艺[J]. 印染, 2019, 45(9): 24-27.
WEI Yiwen. Steaming-and washing-free printing of polyester fabric with disperse dyes[J]. China Dyeing & Finishing, 2019, 45(9): 24-27.
[7] 卜广玖, 王震, 陆前进, 等. 涤纶家纺面料的液体分散染料免洗印花[J]. 印染, 2020, 46(6):45-48.
BU Guangjiu, WANG Zhen, LU Qianjin, et al. Washing-free printing of polyester home textiles with new liquid disperse dyes[J]. China Dyeing & Finishing, 2020, 46(6): 45-48.
[8] 李必文, 孙素梅, 赖晶岩. 免水洗或少水洗印花和染色用WCD系列分散染料的应用[J]. 染整技术, 2020, 42(3): 31-35.
LI Biwen, SUN Sumei, LAI Jingyan. Application of WCD series of disperse dyes for water-free or less water-washing printing and dyeing[J]. Textile Dyeing and Finishing Journal, 2020, 42(3): 31-35.
[9] 艾丽. 液体分散染料的微量印花机理及应用[D]. 苏州: 苏州大学, 2018: 5-6.
AI Li. Mechanism and application of liquid disperse dyes for micro-printing technique[D]. Suzhou: Soochow University, 2018: 5-6.
[10] 朱亚伟, 丁志平, 高建波, 等. 一种浆状分散染料及其制备方法与应用: ZL 201510598484.9[P]. 2018-2-05.
ZHU Yawei, DING Zhiping, GAO Jianbo, et al. Preparation and application of disperse dye paste: ZL 201510598484.9[P]. 2018-2-05.
[11] 朱亚伟, 丁志平, 罗韬. 一种微量印花色浆及其制备方法与应用: ZL 201510598181.7[P]. 2017-2-07.
ZHU Yawei, DING Zhiping, LUO Tao. Preparation and application of micro printing paste: ZL 201510598181.7[P]. 2017-2-07.
[12] 朱亚伟, 丁志平, 胡必清, 等. 一种功能预聚体及其制备方法与应用: ZL 201510598169.6[P]. 2017-2-03.
ZHU Yawei, DING Zhiping, HU Biqing, et al. Preparation and application of functional prepolymer: ZL 201510598169.6[P]. 2017-2-03.
[13] 孙旭辰, 王鹏, 赵容慧, 等. 环保型液状分散染料组合物的制备[J]. 染料与染色, 2021, 58(5):15-18.
SUN Xuchen, WANG Peng, ZHAO Ronghui, et al. Preparation of an environment friendly liquid disperse dye composition[J]. Dyestuffs and Coloration, 2021, 58(5):15-18.
[14] 王召伟, 钟毅, 徐红, 等. 液体分散染料的制备及应用[J]. 印染, 2021, 47(10):6-10.
WANG Zhaowei, ZHONG Yi, XU Hong, et al. Preparation and application of liquid disperse dyes[J]. China Dyeing & Finishing, 2021, 47(10):6-10.
[15] 刘媛媛, 钟毅, 徐红, 等. 液体分散染料的超细化制备工艺[J]. 印染, 2021, 47(1):6-10.
LIU Yuanyuan, ZHONG Yi, XU Hong, et al. Ultrafine preparation of liquid disperse dyestuff[J]. China Dyeing & Finishing, 2021, 47(1):6-10.
[16] 钱春霞, 何权辉, 赵朋, 等. 液体分散染料的制备及分散剂的选择[J]. 染料与染色, 2021, 58(5):43-48,34.
QIAN Chunxia, HE Quanhui, ZHAO Peng, et al. Preparation of liquid disperse dyes and the dispersants used[J]. Dyestuffs and Coloration, 2021, 58(5):43-48,34.
[17] 邱靖斯, 刘越. 分散染料的细化分散及其对粒径影响研究进展[J]. 纺织学报, 2021, 42(8):194-201.
QIU Jingsi, LIU Yue. Research progress in superfine dispersion of disperse dyes and its effect on particle-size[J]. Journal of Textile Research, 2021, 42(8):194-201.
[18] 柏俊峰. 液体分散染料制备及微量印花技术研究[D]. 苏州: 苏州大学, 2020: 43-44.
BAI Junfeng. Study on preparation of liquid disperse dyes and trace printing technology[D]. Suzhou: Soochow University, 2020: 43-44.
[19] 胡会娜, 石瑜博, 朱亚伟, 等. 高力份分散橙288液体染料制备、稳定性及染色性能[J]. 丝绸, 2021, 58(1): 8-12.
HU Huina, SHI Yubo, ZHU Yawei, et al. Preparation, stability and dyeing performance of high strength disperse orange 288 liquid dye[J]. Journal of Silk, 2021, 58(1):8-12.
[20] 石瑜博, 艾丽, 肖瀛洲, 等. 水基液体分散染料的放置稳定性评价研究[J]. 丝绸, 2021, 58(7):44-50.
SHI Yubo, AI Li, XIAO Yingzhou, et al. Study on the evaluation of the storage stability of water-based liquid disperse dyes[J]. Journal of Silk, 2021, 58(7):44-50.
[21] 张建国, 赵霞霞, 钱琴芳, 等. 新型液体分散染料的染色工艺[J]. 印染, 2016, 42(12): 26-28,41.
ZHANG Jianguo, ZHAO Xiaxia, QIAN Qinfang, et al. Dyeing process with new liquid disperse dyestuff[J]. China Dyeing & Finishing, 2016, 42(12): 26-28,41.
[22] 卜广玖, 王震, 陆前进, 等. 涤纶浸染用高固色率液体分散染料[J]. 印染, 2020, 46(4):27-30,34.
BU Guangjiu, WANG Zhen, LU Qianjin, et al. Liquid disperse dyes with high fixation yield for exhaust dyeing of polyester[J]. China Dyeing & Finishing, 2020, 46(4): 27-30,34.
[23] 高建波, 钱琴芳, 陆叶洪, 等. 合成增稠剂的流变性及在涤纶印花中的应用[J]. 丝绸, 2016, 53(5):6-11.
GAO Jianbo, QIAN Qinfang, LU Yehong, et al. Rheological property of synthetic thickener and its application in polyester printing[J]. Journal of Silk, 2016, 53(5):6-11.
[24] 艾丽, 曹红梅, 朱亚伟, 等. 基于液体分散染料的微量印花技术[J]. 纺织学报, 2018, 39(9):77-83.
AI Li, CAO Hongmei, ZHU Yawei, et al. Ultralow pollution micro-printing method based on liquid disperse dyes[J]. Journal of Textile Research, 2018, 39(9): 77-83.
[25] 柏俊峰, 胡会娜, 徐明, 等. 液体分散染料在涤纶双绉织物上的微量印花性能[J]. 印染, 2020, 46(3): 31-35.
BAI Junfeng, HU Huina, XU Ming, et al. Micro-printing properties of liquid disperse dyes on polyester fabrics[J]. China Dyeing & Finishing, 2020, 46(3):31-35.
[26] 张永高, 徐华君, 章金芳, 等. 分散染料印花用复配糊料的性能[J]. 印染, 2018, 44(18):37-39,44.
ZHANG Yonggao, XU Huajun, ZHANG Jinfang, et al. Performance of compound paste for disperse dye printing[J]. China Dyeing & Finishing, 2018, 44(18): 37-39,44.
[27] 崔松松, 王莉莉, 吴明华. 新型有机硅改性黏合剂及其分散染料免水洗印花应用研究[J]. 印染助剂, 2018, 35(10): 47-51.
CUI Songsong, WANG Lili, WU Minghua. Novel silicone modified adhesive and its application in disperse dye washing-free printing[J]. Textile Auxiliaries, 2018, 35(10): 47-51.
[28] 艾丽, 朱亚伟. 黏合剂的合成及其在分散蓝79微水印花中的应用[J]. 纺织学报, 2019, 40(6):51-58.
AI Li, ZHU Yawei. Synthesis of binder and application in polyester fabric with micro-water printing of disperse blue 79[J]. Journal of Textile Research, 2019, 40(6): 51-58.
[29] WANG LL, CUI SS, NI HG. et al. Preparation and application of polyacrylate binder for washing-free printing on polyester with disperse dyes[J]. Textile Research Journal, 2019, 89(13):2721-2728.
doi: 10.1177/0040517518801193
[30] JIANG JT, SHEN YF, YU DY. et al. Sustainable washing-free printing of disperse dyes on polyester fabrics enabled by crosslinked fluorosilicone modified polyacrylate binders[J]. Polymers for Advanced Technologies, 2021, 32(2): 641-650.
doi: 10.1002/pat.v32.2
[31] ZHANG L, ZHOU Q Q, ZHANG Q P, et al. New washing-free printing binder based on fluorosilicone-modified polyacrylate for polyester fabric printing with a disperse dye[J]. Fibers and Polymers, 2021, 22(2): 396-404.
doi: 10.1007/s12221-021-9090-5
[32] WANG LL, CUI SS, NI HG, et al. New new washing-free printing binder based on organosilicon-modified polyacrylate for polyester fabric printing of disperse dyes[J]. Progress in Organic Coatings, 2018, 123:75-81.
doi: 10.1016/j.porgcoat.2018.06.009
[33] AI L, CAO HM, ZHU YW. Ultralow emission micro-printing process for PET fibers using liquid disperse dye[J]. Textile Research Journal, 2022, 92(5/6):788-800.
doi: 10.1177/00405175211045723
[34] AI L, CAO HM, ZHU YW. Preparation of silicone-modified acrylate latex and its application for low-emission printing of PET fibre[J]. AUTEX Research Journal, 2019, 19(3): 293-300.
doi: 10.1515/aut-2018-0061
[35] 秦经纬, 曹红梅, 朱亚伟. 液体分散染料在涤/锦织物上的印花性能[J]. 印染, 2017, 43(11):12-15,24.
QIN Jingwei, CAO Hongmei, ZHU Yawei. Printing performance of liquid disperse dyes on polyester/polyamide mixture[J]. China Dyeing & Finishing, 2017, 43(11):12-15,24.
[36] 徐成耀, 张弘. CC-HD高色牢度液体分散染料涤纶毛毯印花工艺[J]. 染整技术, 2020, 42(1):27-29,33.
XU Chengyao, ZHANG Hong. Printing technology of polyester blanket with CC-HD high fastness liquid disperse dye[J]. Textile Dyeing and Finishing Journal, 2020, 42(1):27-29,33.
[37] 卜广玖, 王震, 殷允杰, 等. MX型涤纶用液体分散染料[J]. 印染, 2017, 43(14):26-29.
BU Guangjiu, WANG Zhen, YIN Yunjie, et al. MX series liquid disperse dyes for polyester[J]. China Dyeing & Finishing, 2017, 43(14):26-29.
[38] 陈娟, 艾丽, 朱亚伟. 涤纶织物的热溶染色[J]. 印染, 2016, 42(12): 5-8.
CHEN Juan, AI Li, ZHU Yawei. Thermosol dyeing of polyester fabric[J]. China Dyeing & Finishing, 2016, 42(12): 5-8.
[39] 张德舜, 朱亚伟. 薄型涤纶织物的分散染料连续染色[J]. 印染, 2019, 45(2): 12-15,21.
ZHANG Deshun, ZHU Yawei. Continuous dyeing of thin polyester fabric using disperse dyes[J]. Dyeing & Finishing, 2019, 45(2): 12-15,21.
[40] 陈娟, 艾丽, 朱亚伟. 粘合剂对涤纶连续热熔染色的影响[J]. 丝绸, 2016, 53(10): 1-6.
CHEN Juan, Al Li, ZHU Yawei. Effect of adhesive on continuous thermosol dyeing of polyester[J]. Journal of Silk, 2016, 53(10): 1-6.
[41] 阮仕奔, 郭锐, 杨锋, 等. 厚重涤氨纶织物热熔染色匀染剂制备及应用[J]. 印染助剂, 2021, 38(4): 23-27.
RUAN Shiben, GUO Rui, YANG Feng, et al. Preparation and application of heavy polyester and spandex fabrics by levelling agent in thermosol dyeing[J]. Textile Auxiliaries, 2021, 38(4): 23-27.
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