纺织学报 ›› 2023, Vol. 44 ›› Issue (06): 91-97.doi: 10.13475/j.fzxb.20220407401

• 纺织工程 • 上一篇    下一篇

形状记忆合金复合纱线及其面料驱动性能

付驰宇1,2,3, 徐傲2, 齐硕2, 王凯2, 缪莹2, 尚路路2, 夏治刚1,2,4()   

  1. 1.武汉纺织大学 省部共建纺织新材料与先进加工技术国家重点实验室, 湖北 武汉 430200
    2.武汉纺织大学纺织科学与工程学院, 湖北 武汉 430200
    3.迪肯大学 前沿材料研究所, 澳大利亚 吉朗 3216
    4.省部共建生物多糖纤维成形与生态纺织国家重点实验室, 山东 青岛 226071
  • 收稿日期:2022-04-24 修回日期:2022-11-25 出版日期:2023-06-15 发布日期:2023-07-20
  • 通讯作者: 夏治刚
  • 作者简介:付驰宇(1993—),男,硕士生。主要研究方向为智能纺织新材料。
  • 基金资助:
    湖北省重大科技专项(2020BA082);省部共建生物多糖纤维成形与生态纺织国家重点实验室(青岛大学)开放课题(KF2020215)

Shape memory alloy composite yarn and its fabric actuation performance

FU Chiyu1,2,3, XU Ao2, QI Shuo2, WANG Kai2, MIAO Ying2, SHANG Lulu2, XIA Zhigang1,2,4()   

  1. 1. State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. College of Textile Science and Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    3. Institute for Frontier Materials, Deakin University, Geelong 3216, Australia
    4. State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 226071, China
  • Received:2022-04-24 Revised:2022-11-25 Published:2023-06-15 Online:2023-07-20
  • Contact: XIA Zhigang

摘要:

为研究开发高性能纺织基人工肌肉,设计并制备了以镍钛合金为芯丝、聚酰亚胺纤维为外包纤维的热驱动复合纱线致动器。利用该复合包芯纱成功制备了一种形状可编程的机织物致动器,并初步探索了复合纱线及其织物的力学性能和热驱动特性。研究结果表明:复合纱线及其织物受热驱动后将恢复到初始线性状态,加载的温度越高,形状记忆复合纱线的模量越大,回复应力也越大;该纱线具有良好的电加热和热稳定性能,加载的电流和电压越大,纱线温度越高,达到稳定态的时间越短;纱线在5 V电压下能在6.2 s内完成驱动。该复合织物致动器具有耐高温、形状可编程的特性,可实现不同模式的驱动。

关键词: 形状记忆合金长丝, 复合包芯纱, 软致动器, 可编程人工肌肉

Abstract:

Objective Artificial muscles have shown great importance in the development of wearable devices, exoskeletons, prosthetics and robotics in recent years. Although many artificial muscles based on the novel actuation technologies have been reported, challenges such as single actuation form, complex processing and limited flexibility remain to be addressed. Textile-based artificial muscles exhibit high flexible and light weight properties, but the actuation performance still needs to be enhanced. In order to investigate and develop textile-based artificial muscles with high-performance, it is highly desirable to combine the active materials with textiles.
Method A thermally driven composite yarn actuator with Ni-Ti alloy as the core and polyimide (PI) fiber as the sheath was designed. Specifically, the Ni-Ti alloy filaments were covered by the PI fiber on a friction machine. Due to the good thermal stability of the PI fibers and excellent thermal actuate performance of Ni-Ti alloy filaments, the fabricated yarns can respond to the heat. In addition, thanks to the good conductivity of the alloy filaments the fabricated yarn and fabric are able to be actuated by the electrothermal.
Results A shape-programmable woven fabric actuator was successfully prepared using the composite yarn, the mechanical properties and thermally driven characteristics of the composite yarn and its fabric were initially explored. The results showed that the composite yarns exhibit a hierarchical structure with PI fiber uniformly covering the shape memory alloy filament, which greatly enhanced the wearability of the fabrics. The phase transition temperature of the shape memory alloy was determined by differential scanning calorimetry (DSC) analysis. The mechanical performance test results showed that as the temperature increases, the shape memory alloy filament transformed from the martensitic phase to the austenitic phase, leading to an increase in the modulus of the filament. The obtained yarns showed excellent electrical and thermal properties with temperature up to 35 ℃ under 2.5 V. In addition, the composite yarn can remain a stable temperature, which demonstrates the potential to be applied at low voltage and ability of regulating the temperature by various applied voltages and currents. The results of electrical and thermal driving tests showed that the yarn exhibits good electrical heating and thermal stability, and the higher the loaded current and voltage, the higher the yarn temperature and the shorter the time to reach the steady state. The thermal induced actuation test results show that the composite yarn and its fabric will recover to the initial linear state after being thermally driven. The yarn can be actuated within 6.2 s under 5 V and the angle returned to 135° in 3.4 s, indicating the fast actuation characteristic of the composite yarn. In addition, the high temperature resistant and shape programmable composite fabric actuator prepared by woven interval weft method enables different shape actuation. Due to the programmable properties of memory alloys, fabrics that have been annealed at high temperatures are able to exhibit different actuation movements.
Conclusion In this work, a shape memory alloy-based composite yarn was designed. The yarn was fabricated by covering the PI fiber on the shape memory alloy filament via a friction spinning machine. A shape programmable fabric actuator was fabricated by weaving technique. The mechanical properties and thermal actuation characteristics of the composite yarn and fabric were systematically investigated. Through the test results, the following conclusions are obtained: ① The higher the temperature, the higher the reversion stress of the shape memory composite yarn. ② The shape memory composite yarn has good electrical heating and thermal stability performance. ③ The prepared composite yarn has good electric heating performance. The actuating action can be completed within 6.2 s at 5 V. ④ The composite fabric actuator with high temperature resistance and shape programmable was prepared by weaving method. The fabric was shape-programmed to achieve different actuation motions. The shape-memory composite yarn and fabric can be applied in the fields of smart wearable devices and medical rehabilitation.

Key words: shape memory alloy filament, composite corespun yarn, soft actuator, programmable artificial muscle

中图分类号: 

  • TB333

表1

形状记忆合金长丝及聚酰亚胺粗纱物理性能参数"

SMA丝 PI粗纱
化学成分占比/% 熔点/℃ 密度/
(g·cm-3)
相变温
度/℃
定量/
(g·(10 m)-1)
密度/
(g·cm-3)
分解温
度/℃
极限氧
指数/%
Ti Ni
43.76 56.20 1 310 6.45 25 4.2 1.41 560 38

图1

摩擦纺纱示意图和实际纺纱照片"

图2

复合纱线表观结构与横截面"

图3

形状记忆合金长丝的DSC实验结果"

图4

不同温度下形状记忆复合纱线应力-应变曲线"

图5

2%预拉伸形状记忆复合纱线回复应力-温度曲线"

图6

不同电压下形状记忆复合纱线的红外热成像照片"

图7

不同电压下形状记忆复合纱线的温度与时间的关系"

图8

不同电流下形状记忆复合纱线的温度与时间的关系"

图9

不同电压下形状记忆复合纱线的实际照片与红外热成像图"

图10

恒定热流下记忆合金复合织物的驱动性能"

图11

复合织物的形状可编程特性"

[1] FU Chiyu, XIA Zhigang, HURREN Christopher, et al. Textiles in soft robots: current progress and future trends[J]. Biosensors and Bioelectronics, 2022. DOI: 10.1016/j.bios.2021.113690.
doi: 10.1016/j.bios.2021.113690
[2] HARTMANN Florian, BAUMGARTNER Melanie, KALTENBRUNNER Martin. Becoming sustainable, the new frontier in soft robotics[J]. Advanced Materials, 2021. DOI: 10.1002/adma.202004413.
doi: 10.1002/adma.202004413
[3] BÜTZER Tobias, LAMBERCY Olivier, ARATA Jumpei, et al. Fully wearable actuated soft exoskeleton for grasping assistance in everyday activities[J]. Soft Robotics, 2020, 8(2): 128-143.
doi: 10.1089/soro.2019.0135
[4] EBRAHIMI Nafiseh, BI Chenghao, CAPPELLERI David J, et al. Magnetic actuation methods in bio/soft robotics[J]. Advanced Functional Materials, 2021. DOI: 10.1002/adfm.202005137.
doi: 10.1002/adfm.202005137
[5] SANCHEZ Vanessa, WALSH Conor J, WOOD Robert J. Textile technology for soft robotic and autonomous garments[J]. Advanced Functional Materials, 2021. DOI: 10.1002/adfm.202008278.
doi: 10.1002/adfm.202008278
[6] SUN Wenjie, LI Bo, ZHANG Fei, et al. TENG-Bot: triboelectric nanogenerator powered soft robot made of uni-directional dielectric elastomer[J]. Nano Energy, 2021. DOI: 10.1016/j.nanoen.2021.106012.
doi: 10.1016/j.nanoen.2021.106012
[7] NIU Dong, LI Dachao, CHEN Jinlan, et al. SMA-based soft actuators with electrically responsive and photoresponsive deformations applied in soft robots[J]. Sensors and Actuators A: Physical, 2022. DOI: 10.1016/j.sna.2022.113516.
doi: 10.1016/j.sna.2022.113516
[8] MCCRACKEN Joselle M, DONOVAN Brian R, LYNCH Kelsey M, et al. Molecular engineering of mesogenic constituents within liquid crystalline elastomers to sharpen thermotropic actuation[J]. Advanced Functional Materials, 2021. DOI: 10.1002/adfm.202100564.
doi: 10.1002/adfm.202100564
[9] YING Binbin, LIU Xinyu. Skin-like hydrogel devices for wearable sensing, soft robotics and beyond[J]. iScience, 2021. DOI: 10.1016/j.isci.2021.103174.
doi: 10.1016/j.isci.2021.103174
[10] KHEIRIKHAH Mohammad Mahdi, RABIEE Samaneh,EDALAT Mohammad Ehsan. A review of shape memory alloy actuators in robotics[C]// RUIZ-DEL-SOLAR J, CHOWN E, PLÖGER PG. Robot Soccer World Cup XIV. Berlin: Springer, 2011: 206-217.
[11] MOHD JANI Jaronie, LEARY Martin, SUBIC Aleksandar, et al. A review of shape memory alloy research, applications and opportunities[J]. Materials & Design, 2014, 56: 1078-1113.
doi: 10.1016/j.matdes.2013.11.084
[12] YUEN M C, BILODEAU R A, KRAMER R K. Active variable stiffness fibers for multifunctional robotic fab-rics[J]. IEEE Robotics and Automation Letters, 2016, 1(2): 708-715.
[13] HAN Min Woo, AHN Sung Hoon. Blooming knit flowers: loop-linked soft morphing structures for soft robotics[J]. Advanced Materials, 2017. DOI: 10.1002/adma.201606580.
doi: 10.1002/adma.201606580
[14] HAN Min Woo, KIM Min Soo, AHN Sung Hoon. Shape memory textile composites with multi-mode actuations for soft morphing skins[J]. Composites Part B: Engineering, 2020. DOI: 10.1016/j.compositesb.2020.108170.
doi: 10.1016/j.compositesb.2020.108170
[15] 熊祥章, 裴泽光, 陈革. 基于形状记忆合金丝包覆纱的针织物致动器研究[J]. 纺织学报, 2020, 41(5): 50-57.
XIONG Xiangzhang, PEI Zeguang, CHEN Ge. Study on actuating force of knit actuator based on covered yarn with shape memory alloy wire as core[J]. Journal of Textile Research, 2020, 41(5): 50-57.
[16] SOOTHER Dileep Kumar, DAUDPOTO Jawaid, CHOWDHRY Bhawani Shankar. Challenges for practical applications of shape memory alloy actuators[J]. Materials Research Express, 2020. DOI: 10.1088/2053-1591/aba403.
doi: 10.1088/2053-1591/aba403
[17] XU Zhizhi, HAO Yanshuang, JI Yuanchao, et al. Simultaneously increasing the strength and decreasing the modulus in TiNi alloys via plastic deformation[J]. Scripta Materialia, 2022. DOI: 10.1016/j.scriptamat.2021.114374.
doi: 10.1016/j.scriptamat.2021.114374
[18] JIANG Surong, CHEN Bai, QI Fei, et al. A variable-stiffness continuum manipulators by an SMA-based sheath in minimally invasive surgery[J]. The International Journal of Medical Robotics and Computer Assisted Surgery, 2020. DOI: 10.1002/rcs.2081. 10.1002/rcs.2081.
doi: 10.1002/rcs.2081. 10.1002/rcs.2081
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