纺织学报 ›› 2024, Vol. 45 ›› Issue (03): 219-226.doi: 10.13475/j.fzxb.20221004802

• 综合述评 • 上一篇    下一篇

非溶相共混熔喷非织造技术的研究进展

秦子轩1, 张恒1(), 李晗1, 翟倩1, 甄琪2, 钱晓明3   

  1. 1.中原工学院 纺织学院, 河南 郑州 451191
    2.中原工学院 服装学院, 河南 郑州 451191
    3.天津工业大学 纺织科学与工程学院, 天津 300387
  • 收稿日期:2022-12-24 修回日期:2023-05-23 出版日期:2024-03-15 发布日期:2024-04-15
  • 通讯作者: 张恒
  • 作者简介:秦子轩(1996—),男,硕士生。主要研究方向为新型纤维材料的非织造成形技术及其评价方法。
  • 基金资助:
    国家自然科学基金项目(52003306);河南省高校科技创新人才支持计划资助项目(24HASTIT011);河南省高等学校重点科研项目(23A540003);河南省重大科技专项(231100320200)

Review on non-compatibility blend melt blowing nonwoven process

QIN Zixuan1, ZHANG Heng1(), LI Han1, ZHAI Qian1, ZHEN Qi2, QIAN Xiaoming3   

  1. 1. School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 451191, China
    2. School of Fashion Technology, Zhongyuan University of Technology, Zhengzhou, Henan 451191, China
    3. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
  • Received:2022-12-24 Revised:2023-05-23 Published:2024-03-15 Online:2024-04-15
  • Contact: ZHANG Heng

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摘要：

为明确非溶相共混熔喷非织造技术制备超细纤维材料过程中的微相分离机制,并进一步明晰超细纤维材料结构和性能的调控规律,挖掘熔喷非织造技术的产业化应用潜力,从非溶相共混熔喷机制出发,介绍了利用多种聚合物进行非溶相共混熔喷时的微相分离特点,综述了非溶相共混熔喷的聚合物匹配体系现状以及不同种类聚合物共混对超细纤维材料性能的影响,阐述了非溶相共混熔喷超细纤维材料的功能性应用形式和领域,最后探讨了非溶相共混熔喷目前存在问题及未来发展方向,以期为共混熔喷非织造技术制备超细纤维材料的进一步研究提供参考。

关键词: 熔喷, 非织造材料, 非溶相共混, 聚合物, 超细纤维

Abstract:

Significance Melt blowing method is a one-step preparation process for preparing microfibers nonwovens, which has attractive advantages of high production efficiency, low energy consumption, and low cost. The melt blown nonwovens show a diversified and functional application trend, such as medical protection, air filtration, and oil-water separation, owing to the increasing requirements of the good life. Blending modification is the main strategy to improve the performance of melt blown nonwovens, and the non-compatibility blend melt blowing nonwoven process using the raw materials of polymer with different solubility parameters, is an effective method of structure regulation, including adjusting the fiber diameter distribution and pore morphology, helps expand the application of microfibers materials. This is because the structure paraments of the microfiber materials are affected by the viscosity of the polymer melt and the phase separation during the melt blowing process. In addition, the phase separation is more obvious in the case of high-speed hot air drafting, because of the solubility parameter difference between components in the melt. However, to our best knowledge, there are limited reports about the review on the non-compatibility blend melt blowing nonwoven process. Thus, clarifying the phase separation mechanism and regulation rules of the microfiber material structure in the non-compatibility blend melt blowing nonwoven process help expand the industrialization of melt blowing nonwoven technology.

Progress Starting from the mechanism of non-soluble phase blending melt blowing, this paper presents that the blending system formed by different types of polymers is affected by the forces of each component between polymers during the melt blowing process, and the forces at different positions are different in the drawing process, thus enabling the formation of microfiber materials with large differences in fiber diameters. Thereafter, this paper reviews the performance enhancement of microfiber materials after using different types of polymer ratios. Firstly, the non-soluble phase blending of polymers with different ratios can enhance the toughness of the materials. Meanwhile, the melt blowing non-soluble phase blending can produce microfiber materials with large differences in fiber diameters, which can effectively enhance the filtration performance of the materials. In addition, inspired by the phase separation of components in melt blowing nonwoven materials, the removal of one of the components in the ultrafine fiber material can provide ideas for obtaining nanoscale ultrafine fiber materials. Finally, this paper reviews the functional application forms and fields of non-soluble phase co-blended melt blowing microfiber materials and discusses the current problems and future development directions of non-soluble phase co-blended melt blowing, in order to provide references for further research on the preparation of microfiber materials by co-blended melt blowing nonwovens technology.

Conclusion and Prospect Considerable efforts have been developed in the non-compatibility blend melt blowing nonwoven process. Selecting appropriate polymer types and proportions based on functional applications to form an effective polymer matching system for non-compatibility blend melt blowing nonwoven process are the main measures taken, despite a wide variety of polymers that can be used. The effective selection of raw material and process optimization during the non-compatibility blend melt blowing nonwoven process is not only good for obtaining large scale fiber diameters distribution, but also useful for gain a variety of micro/nano fiber network structures such as horizontal branching and three-dimensional embedding. Thus, toughness and filtration and separation capabilities of microfibers materials are improved. Besides, the combination of non-compatibility blend melt blowing process and etching process can selectively remove a certain component of the melt blown nonwovens, thereby a nanofiber network structure and rough groove morphology was obtained. However, the green, and effective one-step preparation process still needs further research. Although the functional application in the fields of toughness enhancement, filter materials and oil-water separation has been made, the further application in the fields of smart wearables, construction and energy still needs to develop.

Key words: melt blowing technology, nonwoven, non-compatibility blending, polymer, microfiber

中图分类号: 

  • TS176

图1

熔喷非织造技术的工艺原理图"

图2

非溶相共混熔喷非织造工艺"

图3

非溶相共混的相分布及其共混成形原理"

图4

非溶相共混熔喷制备的超细纤维材料"

图5

非溶相共混熔喷-刻蚀工艺原理及形貌"

图6

非溶相共混熔喷非织造技术的应用场景图"

[1] WANG Peter L, ROSCHLI Alex, PARANTHAMAN M Parans, et al. Recent developments in filtration media and respirator technology in response to COVID-19[J]. MRS Bulletin, 2021, 46(9): 822-831.
doi: 10.1557/s43577-021-00173-6
[2] ZHAO Chongxiang, MARK Lun Howe, KIM Sundong, et al. Recent progress in micro-/nano-fibrillar reinforced polymeric composite foams[J]. Polymer Engineering & Science, 2021, 61(4): 926-941.
[3] YU Yan, XIONG Siwei, HUANG Hao, et al. Fabrication and application of poly (phenylene sulfide) ultrafine fiber[J]. Reactive and Functional Polymers, 2020. DOI:10.1016/j.reactfunctpolym.2020.104539.
[4] 朱斐超, 张宇静, 张强, 等. 聚乳酸基生物可降解熔喷非织造材料的研究进展与展望[J]. 纺织学报, 2022, 43(1): 49-57.
ZHU Feichao, ZHANG Yujing, ZHANG Qiang, et al. Research progress and prospect on biodegradable polylactic acid-based melt-blown nonwovens[J]. Journal of Textile Research, 2022, 43(1): 49-57.
[5] BARLETTA Massimiliano, AVERSA Clizia, AYYOOB Muhammad, et al. Polybutylene succinate (PBS): materials, processing, and industrial applications[J]. Progress in Polymer Science, 2022. DOI:10.1016/j.progpolymsci.2022.101579.
[6] SANTOS A S, FREEEIRA P J T, MALONEY T. Bio-based materials for nonwovens[J]. Cellulose, 2021, 28(14):8939-8969.
doi: 10.1007/s10570-021-04125-w
[7] 赵家明, 孙辉, 于斌, 等. CuO/聚丙烯/乙烯-辛烯共聚物复合熔喷非织造材料的制备及其吸油性能[J]. 纺织学报, 2022, 43(2): 89-97.
ZHAO Jiaming, SUN Hui, YU Bin, et al. Preparation of CuO/polypropylene-ethylene-octene copolymer composite melt-blown nonwovens and their oil absorption properties[J]. Journal of Textile Research, 2022, 43(2): 89-97.
[8] 甄琪, 张恒, 朱斐超, 等. 聚丙烯/聚酯双组分微纳米纤维熔喷非织造材料制备及其性能[J]. 纺织学报, 2020, 41(2): 26-32.
ZHEN Qi, ZHANG Heng, ZHU Feichao, et al. Fabrication and properties of polypropylene/polyester bicomponen tmicro-nanofiber webs via melt blowing process[J]. Journal of Textile Research, 2020, 41(2): 26-32.
[9] DENG Nanping, HE Hongsheng, YAN Jing, et al. One-step melt-blowing of multi-scale micro/nano fabric membrane for advanced air-filtration[J]. Polymer, 2019, 165: 174-179.
doi: 10.1016/j.polymer.2019.01.035
[10] WEI Wei, SHIM Eunkyoung, BARNES William, et al. Structure-property relationship of melt spinning polypropylene fibers containing inorganic particulate CaCO3 fillers[J]. Textile Research Journal, 2021, 91(11/12): 1419-1435.
doi: 10.1177/0040517520982001
[11] AVERSA C, BARLETTA M, CAPPIELLO G, et al. Compatibilization strategies and analysis of morphological features of poly(butylene adipate-co-terephthalate) (PBAT)/poly(lactic acid) PLA blends: a state-of-art review[J]. European Polymer Journal, 2022.DOI:10.1016/j.eurpolymj.2022.111304.
[12] ZHU Jiqing, BALIEU Romain, WANG Haopeng. The use of solubility parameters and free energy theory for phase behaviour of polymer-modified bitumen: a review[J]. Road Materials and Pavement Design, 2021, 22(4): 757-778.
doi: 10.1080/14680629.2019.1645725
[13] HU Pingfan, JIAO Zeren, ZHANG Zhuoran, et al. Development of solubility prdiction models with ensemble learning[J]. Industrial & Engineering Chemistry Research, 2021, 60(30): 11627-11635.
doi: 10.1021/acs.iecr.1c02142
[14] ANSTEY Andrew, CHANG Eunse, KIM Eric S, et al. Nanofibrillated polymer systems: design, application, and current state of the art[J]. Progress in Polymer Science, 2021.DOI:10.1016/j.progpolymsci.2020.101346.
[15] ZHU Feichao, YU Bin, SU Juanjuan, et al. Study on PLA/PA11 bio-based toughening melt-blown non-wovens[J]. Autex Research Journal, 2020, 20(1): 24-31.
doi: 10.2478/aut-2019-0002
[16] CHANG Li, XING Xiaolu, ZHOU Yanfen, et al. Effects of EVA content on properties of PP/EVA blends and melt-blown nonwovens[J]. Fibers and Polymers, 2022, 23(4): 882-890.
doi: 10.1007/s12221-022-4212-2
[17] 孟兵, 郑金辉, 孙建丽. 不同分子量PCL增韧PLA的结构与性能[J] 工程塑料应用, 2016, 44(5): 107-111.
MENG Bing, ZHENG Jinhui, SUN Jianli. Property and structure of PLA toughened by different molecular weight PCL[J]. Engineering Plastics Application, 2016, 44(5): 107-111.
[18] GUO Jianwei, LIU Xiao, LIU Ming, et al. Effect of molecular weight of poly(ethylene glycol) on plasticization of poly(L-lactic acid)[J]. Polymer, 2021.DOI:10.1016/j.polymer.2021.123720.
[19] RAHMAN M, 朱斐超, 杨潇东, 等. 热塑性聚氨酯增韧聚乳酸及其熔喷非织造材料研究[J]. 丝绸, 2021, 58(10): 28-35.
RAHMAN M, ZHU Feichao, YANG Xiaodong, et al. Study on toughened polylactic acid and its meltblown nonwovens by thermoplastic polyurethane[J]. Journal of Silk, 2021, 58(10): 28-35.
[20] PENG Mengna, JIA Huiying, JIANG Liang, et al. Study on structure and property of PP/TPU melt-blown nonwovens[J]. Journal of The Textile Institute, 2019, 110(3): 468-475.
doi: 10.1080/00405000.2018.1485461
[21] 席立锋, 周衡书, 周忠成, 等. 丙烯基弹性体增韧聚乳酸熔喷成型及性能[J] 工程塑料应用, 2022, 50(3): 32-37.
XI Lifeng, ZHOU Hengshu, ZHOU Zhongcheng, et al. Preparation and properties of PBE/PLA melt-blown nonwovens[J]. Engineering Plastics Application, 2022, 50(3): 32-37.
[22] MUIRURI Joseph K, LIU Songlin, TEO Wern Sze, et al. Highly biodegradable and tough polylactic acid-cellulose nanocrystal composite[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(5): 3929-3937.
[23] GUG Jeongin, SOBKOWICZ Margaret J. Improvement of the mechanical behavior of bioplastic poly(lactic acid)/polyamide blends by reactive compatibi-lization[J]. Journal of Applied Polymer Science, 2016.DOI:10.1002/app.43350.
[24] GUO Yichen, ZUO Xianghao, XUE Yuan, et al. Enhancing impact resistance of polymer blends via self-assembled nanoscale interfacial structures[J]. Macromolecules, 2018, 51(11): 3897-3910.
doi: 10.1021/acs.macromol.8b00297
[25] HE Xuelian, SHI Jiaji, WU Lei, et al. Study on synergistic toughening of polypropylene with high-density polyethylene and elastomer-olefin block copolymers under ultrasonic application[J]. Composites Science and Technology, 2018, 161: 115-123.
doi: 10.1016/j.compscitech.2018.03.044
[26] GUAN Jipeng, LUO Wentao, LU Shifang, et al. Synchronous toughening and strengthening of the immiscible polylactic acid/thermoplastic poly-urethane (PLLA/TPU) blends via the interfacial compatibilization with Janus nanosheets[J]. Composites Science and Technology, 2022.DOI:10.1016/j.compscitech.2022.109611.
[27] HUANG Jintao, ZOU Wei, LUO Yue, et al. Phase morphology, rheological behavior, and mechanical properties of poly (lactic acid)/poly (butylene succinate)/hexamethylene diisocyanate reactive blends[J]. ES Energy & Environment, 2021, 12: 86-94.
[28] ZHANG Heng, ZHEN Qi, LIU Yong, et al. One-step melt blowing process for PP/PEG micro-nanofiber filters with branch networks[J]. Results in Physics, 2019, 12: 1421-1428.
doi: 10.1016/j.rinp.2019.01.012
[29] YU Bin, SUN Hui, CAO Yongmin, et al. Effects of poly(ε-caprolactone) on structure and properties of poly(lactic acid)/poly(ε-caprolactone) meltblown nonwoven[J]. Polymer-Plastics Technology and Engineering, 2014, 53(17): 1788-1793.
doi: 10.1080/03602559.2014.935396
[30] ZHOU Yanfen, JIANG Liang, JIA Huiying, et al. Study on spinnability of PP/PU blends and preparation of PP/PU bi-component melt blown nonwovens[J]. Fibers and Polymers, 2019, 20(6): 1200-1207.
doi: 10.1007/s12221-019-8111-0
[31] 孙焕惟, 张恒, 甄琪, 等. 丙烯基纳微米弹性过滤材的熔喷成型及其过滤性能[J]. 纺织学报, 2020, 41(10): 20-28.
SUN Huanwei, ZHANG Heng, ZHEN Qi, et al. Filtrations of propylene-based micro-nano elastic filtres via melt blowing process[J]. Journal of Textile Research, 2020, 41(10): 20-28.
[32] BANERJI Aditya, JIN Kailong, MAHANTHAPPA Mahesh K, et al. Porous fibers templated by melt blowing cocontinuous immiscible polymer blends[J]. ACS Macro Letters, 2021, 10(10): 1196-1203.
doi: 10.1021/acsmacrolett.1c00456 pmid: 35549054
[33] WANG Zaifei, LIU Xiaotun, MACOSKO Christopher W, et al. Nanofibers from water-extractable melt-blown immiscible polymer blends[J]. Polymer, 2016, 101: 269-273.
doi: 10.1016/j.polymer.2016.08.058
[34] SOLTANI Iman, MACOSKO Christopher W. Influence of rheology and surface properties on morphology of nanofibers derived from islands-in-the-sea meltblow-nonwovens[J]. Polymer, 2018, 145: 21-30.
doi: 10.1016/j.polymer.2018.04.051
[35] JIN Kailong, EYER Sarah, DEAN William, et al. Bimodal nanofiber and microfiber nonwovens by melt-blowing immiscible ternary polymer blends[J]. Industrial & Engineering Chemistry Research, 2019, 59(12): 5238-5246.
doi: 10.1021/acs.iecr.9b04887
[36] ZHANG Xiuqin, JIN Gaoling, MA Wenjuan, et al. Fabrication and properties of poly(L-lactide) nanofibers via blend sea-island melt spinning[J]. Journal of Applied Polymer Science, 2015.DOI:10.1002/app.41228.
[37] 万艳霞, 朱志国, 王锐, 等. PPS/PP共混海岛超细纤维的制备及结构性能研究[J] 中国材料进展, 2014, 33(11): 677-681,689.
WAN Yanxia, ZHU Zhiguo, WANG Rui, et al. Preparation and structural performance of PPS/PP blend sea-island superfine fiber[J]. Materials China, 2014, 33(11): 677-681,689.
[38] ZHANG Heng, ZHEN Qi, CUI Jingqiang, et al. Groove-shaped polypropylene/polyester micro/nanofibrous nonwoven with enhanced oil wetting capability for high oil/water separation[J]. Polymer, 2020.DOI:10.1016/j.polymer.2020.122356.
[39] WANG Zaifei, ESPIN Leonardo, BATES Frank S, et al. Water droplet spreading and imbibition on super-hydrophilic poly(butylene terephthalate) melt-blown fiber mats[J]. Chemical Engineering Science, 2016, 146: 104-114.
doi: 10.1016/j.ces.2016.02.006
[40] 周忠成, 周衡书, 刘超, 等. 聚丙烯/聚乙二醇熔喷非织造材料的制备及其性能研究[J]. 湖南工程学院学报(自然科学版), 2021, 31(2): 79-83.
ZHOU Zhongcheng, ZHOU Hengshu, LIU Chao, et al. Study on preparation and properties of PP/PEG meltblown nonwoven material[J]. Journal of Hunan Institute of Engineering(Natural Science Edition), 2021, 31(2): 79-83.
[41] 陈永波, 李双武, 陈光剑, 等.一种高流动性聚乳酸材料:202210845038.3[P].2023-05-05.
CHEN Yongbo, LI Shuangwu, CHEN Guangjian, et al.A high fluidity polylactic acid material: 202210845038.3[P].2023-05-05.
[42] LIN Tingan, LIN Jiahorng, BAO Limin. Polypropylene/thermoplastic polyurethane blends: mechanical characterizations, recyclability and sustainable development of thermoplastic materials[J]. Journal of Materials Research and Technology, 2020, 9(3): 5304-5312.
doi: 10.1016/j.jmrt.2020.03.056
[43] 张恒, 甄琪, 刘雍, 等. 嵌入式聚丙烯/聚乙二醇微纳米纤维材料的结构特征及其气固过滤性能[J]. 纺织学报, 2019, 40(9): 28-34.
ZHANG Heng, ZHEN Qi, LIU Yong, et al. Air filtration performance and morphological features of polyethylene glycol/polypropylene composite fibrous materials with embedded structure[J]. Journal of Textile Research, 2019, 40(9): 28-34.
[44] ZHEN Qi, ZHANG Heng, LI Han, et al. Polypropylene-secondary alkane sulfonate micro/nanofibrous fabrics with aligned fibers for enhanced anisotropic wetting performances[J]. Applied Surface Science, 2022. DOI:10.1016/j.apsusc.2022.152486.
[45] LI Han, ZHANG Heng, HU Junjie, et al. Facile preparation of hydrophobic PLA/PBE micro-nanofiber fabrics via the melt-blown process for high-efficacy oil/water separation[J]. Polymers, 2022.DOI:10.3390/polym14091667.
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