纺织学报 ›› 2017, Vol. 38 ›› Issue (12): 20-26.doi: 10.13475/j.fzxb.20160701807

• 纤维材料 • 上一篇    下一篇

兔毛白粉成分结构分析及其应用

  

  • 收稿日期:2016-07-06 修回日期:2017-09-11 出版日期:2017-12-15 发布日期:2017-12-18

Structural characterization and applicaion of rabbit whiting

  • Received:2016-07-06 Revised:2017-09-11 Online:2017-12-15 Published:2017-12-18

摘要:

为更好地开发利用兔毛纤维在纺纱过程中产生的兔毛白粉废弃物,采用扫描电子显微镜、双缩脲显色法、SDS?聚丙烯酰胺凝胶电泳法、傅里叶红外光谱、X 射线衍射以及差示扫描量热法对从兔毛纤维表面脱落的白粉进行表观结构和成分结构探究。结果表明:兔毛白粉是从兔毛表面鳞片脱离下来的物质,长度、宽度和厚度分别为20~50 μm、2.0~6.0 μm 和0.4~0.7 μm,兔毛白粉的成分中含有蛋白质,相对分子质量主要集中在11 ku左右,可被认为是提取角蛋白的良好材料;利用还原C 法从兔毛白粉中进一步提取角蛋白,将其作为一种紫外防护功能添加剂应用于化妆品中,在200~320 nm的紫外线下测试兔毛白粉,发现兔毛白粉的紫外线吸收能力优于防晒产品。

关键词: 兔毛白粉, 成分结构, 角蛋白, 紫外吸收

Abstract:

For a better development and ultilization of rabbit whiting produced in the spinning process of rabbit fiber,the rabbit whiting waste was tested by scanning electron microscopy (SEM),biuret test,sodium dodecyl sulfate polyacrylamide gel electropheresis (SDS-PAGE),fourier transform infrared spectroscopy,X-ray diffraction and differential scanning calorimetry (DSC) to characterize its apparent structure and composition. The experimental result prove that the rabbit whiting is from the surface exfoliate of rabbit hair,which the length,width and thickness are range of 20~50μm,2.0~6.0 μm and 0.4~0.7μm respectively. And keratin as the main composition with?molecular?weight?11kDa approximately. Therefore,rabbit whiting is regard as a good material for keratin extraction. The keratin was extracted from rabbit whiting further via sulphitolysis method,as a kind of anti-ultraviolet additive applied in cosmetic. The rabbiting whiting has better ultraviolet ray absorption than sunscreen products via UV test in the ultraviolet range of 200~320nm.

Key words: rabbit whiting, component structure, keratin, ultraviolet absorption

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