纺织学报 ›› 2018, Vol. 39 ›› Issue (03): 92-97.doi: 10.13475/j.fzxb.20161104106

• 染整与化学品 • 上一篇    下一篇

羊毛角蛋白的制备及其对涤纶织物的整理

  

  • 收稿日期:2016-11-16 修回日期:2017-12-14 出版日期:2018-03-15 发布日期:2018-03-09

Preparation of wool keratin and its modification to polyester fabrics

  • Received:2016-11-16 Revised:2017-12-14 Online:2018-03-15 Published:2018-03-09

摘要:

针对涤纶织物吸湿透气性差、易产生静电等问题,将不同质量分数的羊毛角蛋白溶液涂覆于经化学刻蚀处理的涤纶织物上,获得角蛋白涂覆涤纶织物。借助红外光谱及扫描电子显微镜等测试仪器对整理前后织物的结构及形貌进行表征,考察了整理前后织物的吸湿透气性、力学性能、抗静电性、耐水洗及悬垂性等的变化。结果表明:碱减量处理后涤纶织物的透气率提高57.7%;角蛋白整理后涤纶织物的回潮率增加3.3 倍,断裂强度和断裂伸长率略有降低,织物的悬垂性变差,且静悬垂性较动悬垂性好;整理后织物的静电压峰值和静电压衰减时间几乎为0,改善了织物的抗静电性能。若作为服饰用织物,质量分数为20%的角蛋白溶液处理的织物较柔软舒适,且其涂覆质量增加率为9.7%。

关键词: 羊毛角蛋白, 涤纶织物, 涂覆, 化学刻蚀, 功能整理

Abstract:

In order to solve the problems of poor moisture absorption and breathability of polyester fabric with poor antistatic properties, keratin-coated polyester fabric was obtained by coating different mass fraction of wool keratin solutions on chemically eroded polyester fabric. Subsequently, the structure and morphology of the fabric before and after finishing were characterized by using transform infrared spectrometry and scanning electron microscopy electrom microscopy. In addition, breathability, breathability, mechanical properties, antistatic properties, washable properties and drapability were studied. The results show that breathability rate of the chemically eroded polyester fabrics is increased by 57.7%. After keratin coating, the moisture regain ratio of the fabrics is increased by 3.3 times, and breaking strength and elongation of the fabrics are slightly reduced. Moreover, the drapability of the treated fabrics is deteriorated, and the static drape is better than the dynamic drape. The static voltage peak and static voltage decay time of treated fabrics are almost zero, and the antistatic property of the fabrics is obviously improved. As a garment cloth, the polyester fabric treated with a keratin solution of a mass fraction of 20% is relatively soft and comfortable, and the mass increase ratio after coating rraches 9.7%.

Key words: wool keratin, polyester fabric, coating, chemical etching, function finishing

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