层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用

doi:10.13475/j.fzxb.20180708905

纺织学报 ›› 2019, Vol. 40 ›› Issue (02): 114-118.doi: 10.13475/j.fzxb.20180708905

层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用

刘菲¹^,², 李秋瑾¹^,²^,³(), 巩继贤¹^,², 李政¹^,², 刘秀明¹^,²^,³, 张健飞¹^,²^,⁴

1.天津工业大学纺织科学工程学院, 天津 300387
2.天津工业大学先进纺织复合材料教育部重点实验室,天津 300387
3.东华大学生态纺织教育部重点实验室, 上海 201620
4.山东省生态纺织协同创新中心, 山东青岛 266071

收稿日期:2018-07-30 修回日期:2018-11-05 出版日期:2019-02-15 发布日期:2019-02-01
通讯作者: 李秋瑾
作者简介:刘菲(1994—),女,硕士生。主要研究方向为复合材料与功能材料。
基金资助:
国家重点研发计划资助项目(2017YFB0309800);天津市应用基础及前沿技术研究计划资助项目(15JCYBJC18000)

Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel

LIU Fei¹^,², LI Qiujin¹^,²^,³(), GONG Jixian¹^,², LI Zheng¹^,², LIU Xiuming¹^,²^,³, ZHANG Jianfei¹^,²^,⁴

1. School of Textile Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
2. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China
3. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
4. Collaborative Innovation Center for Eco-Textiles of Shangdong Province, Shandong, Qingdao 266071, China

Received:2018-07-30 Revised:2018-11-05 Online:2019-02-15 Published:2019-02-01
Contact: LI Qiujin

摘要/Abstract

摘要：

为制备生物相容性功能纺织材料,采用层层自组装技术将带有不同电荷的海藻酸钠(Alg)、壳聚糖(Chi)、透明质酸(HA)组装到碳酸钙模板上,利用乙二胺四乙酸(EDTA)去除模板,得到Alg/ Chi/ HA生物多糖微胶囊;利用超景深三维显微镜、扫描电子显微镜、红外光谱、综合热分析仪研究了微胶囊的形貌结构及热稳定性。结果表明:Alg/Chi/HA多糖微胶囊具有很好的中空结构及较强的稳定性;考察了多糖微胶囊吸附释放行为及其随pH值的变化规律,发现Alg/Chi/HA多糖微胶囊具有良好的pH值响应性;进一步将Alg/Chi/HA多糖微胶囊整理至棉纤维上,以制备缓释型功能纺织材料,为功能纺织品开发提供有益的实践经验与技术储备。

关键词: 层层自组装, 多糖微胶囊, 响应性, 缓释, 织物整理

Abstract:

The oppositely charged sodium alginate (Alg), chitosan (Chi), hyaluronic acid (HA) were coated onto the CaCO₃ template via layer-by-layer (LBL) self-assembled technique. The template was removed by using ethylenediaminetetraacetic acid (EDTA) to obtain hollow Alg/Chi/HA microcapsules. The purpose is to prepare biosafety functional fabrics.The morphology and thermal stability of microcapsules were studied by optical microscope with a large-depth-of-field, scanning electron microscope, infrared spectroscopy and comprehensive thermal analyzer. The results show that Alg/Chi/HA microcapsules have good hollow structure and strong stability. The pH-stimuli release behavior of microcapsules were investigated. These Alg/Chi/HA microcapsules were finished in the cotton fiber to manufacture the sustained releasing textile. This work is beneficial for the development of functional fabrics.

Key words: layer-by-layer self-assembly, polysaccharide microcapsule, stimuli-responsive, controlled release, fabric modification

中图分类号:

TS195.5

刘菲, 李秋瑾, 巩继贤, 李政, 刘秀明, 张健飞. 层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用[J]. 纺织学报, 2019, 40(02): 114-118.

LIU Fei, LI Qiujin, GONG Jixian, LI Zheng, LIU Xiuming, ZHANG Jianfei. Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel[J]. Journal of Textile Research, 2019, 40(02): 114-118.

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参考文献 11

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样品编号	初始质量 W₀/g	0.5 h后质量 W₁/g	1 h后质量 W₂/g	透湿量/ (g·m^-2·d^-1)
1	251.80	252.39	253.61	7 612
2	251.56	252.11	253.27	7 237

层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用

Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel

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