基于短链含氟丙烯酸酯细乳液的棉织物拒水拒油整理

doi:10.13475/j.fzxb.20180300107

纺织学报 ›› 2019, Vol. 40 ›› Issue (03): 83-89.doi: 10.13475/j.fzxb.20180300107

基于短链含氟丙烯酸酯细乳液的棉织物拒水拒油整理

钱海洪¹^,², 王鸿博¹^,²(), 杜金梅¹^,², 傅佳佳¹^,², 王文聪¹^,²

1.江南大学江苏省功能纺织品工程技术研究中心, 江苏无锡 214122
2.生态纺织教育部重点实验室(江南大学), 江苏无锡 214122

收稿日期:2018-03-01 修回日期:2018-08-21 出版日期:2019-03-15 发布日期:2019-03-15
通讯作者: 王鸿博
作者简介:钱海洪(1992—),女,硕士生。主要研究方向为功能纺织材料。
基金资助:
国家重点研发计划资助项目(2017YFB0309100);江苏省产学研前瞻性研究项目(BY2016022-23)

Water and oil repellent finishing of cotton fabric based on fluoroacrylate miniemulsion

QIAN Haihong¹^,², WANG Hongbo¹^,²(), DU Jinmei¹^,², FU Jiajia¹^,², WANG Wencong¹^,²

1. Jiangsu Engineering Technology Research Center of Functional Textiles, Jiangnan University, Wuxi, Jiangsu 214122, China
2. Key Laboratory of Eco-Textiles(Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China

Received:2018-03-01 Revised:2018-08-21 Online:2019-03-15 Published:2019-03-15
Contact: WANG Hongbo

摘要/Abstract

摘要：

针对织物拒水拒油整理过程中出现的环境污染、整理效果不佳以及耐洗牢度差等问题,通过细乳液聚合法合成了四碳短链含氟丙烯酸酯细乳液,考察了其对棉织物的拒水拒油整理效果。以单因素分析法探讨预处理方式、细乳液质量浓度、预烘工艺及焙烘工艺对棉织物的水油接触角的影响,得到等离子体预处理棉织物拒水拒油整理的最佳工艺条件:细乳液质量浓度为60 g/L,浸渍时间为30 min,80 ℃预烘3 min,160 ℃焙烘3 min。在此最佳条件下,棉织物对水、橄榄油和十六烷的接触角分别为160°、154°、135°;经30次洗涤后,棉织物对水、橄榄油和十六烷的接触角分别为145°、133°、113°;整理后棉织物的折皱回复角提高36%,断裂强力及白度均无明显下降。

关键词: 含氟丙烯酸酯, 拒水拒油整理, 棉织物, 等离子体预处理

Abstract:

In view of the problems of environmental pollution,poor finishing effect and washing fastness in the process of water and oil repellent finishing, a C₄ short chain fluorinated acrylate miniemulsion was synthesized by miniemulsion polymerization,and its influence on water and oil repellent finishing of cotton fabric was investigated. The influence of pretreatment method, mass concentration of miniemulsion and drying/curing process on the contact angle of cotton fabric were discussed by univariate analysis. The experimental results show that the water and oil repellent properties of cotton fabric achieve the optimal effect under the conditions of the mass concentration of miniemulsion 60 g/L,the immersion time 30 min, drying at 80 ℃ for 3 min and curing at 160 ℃ for 3 min. In this process, the contact angle of cotton fabric to water is 160°,to olive oil is 154°,to hexadecane is 135°. After 30 times of washing,the contact angle of cotton fabric to water is 145°,to olive oil is 133° and to hexadecane is 113°. In addition, the crease recovery angle of the treated fabric increases by 36%, and the breaking strength and whiteness have no significant decrease.

Key words: fluoroacrylate, water and oil repellent finishing, cotton fabric, plasma pretreatment

中图分类号:

TS195.5

钱海洪, 王鸿博, 杜金梅, 傅佳佳, 王文聪. 基于短链含氟丙烯酸酯细乳液的棉织物拒水拒油整理[J]. 纺织学报, 2019, 40(03): 83-89.

QIAN Haihong, WANG Hongbo, DU Jinmei, FU Jiajia, WANG Wencong. Water and oil repellent finishing of cotton fabric based on fluoroacrylate miniemulsion[J]. Journal of Textile Research, 2019, 40(03): 83-89.

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参考文献 10

[1]	单良, 李战雄, 臧雄, 等. 核壳型含氟丙烯酸酯乳液的合成及其在棉织物整理中的应用[J]. 纺织学报, 2015,36(1):123-128.
	SHAN Liang, LI Zhanxiong, ZHANG Xiong, et al. Synjournal of fluoro-acrylate emulsion with core-shell syructure and its application on cotton fabric finishing[J]. Journal of Textile Research, 2015,36(1):123-128.
[2]	安恩来. 新型含氟丙烯酸酯共聚物的合成及应用[D]. 西安:西安工程大学, 2015: 2-3.
	AN Enlai. Synthesis and application of new fluorinated acrylate copolymer[D].Xi'an:Xi'an Polytechnic University, 2015: 2-3.
[3]	LINDSTROM A B, STRYNAR M J, LIBELO E L. Polyfluorinated compounds:past,present,and future[J]. Environmental Science & Technology, 2011,45(19):7954-7961. doi: 10.1021/es2011622 pmid: 21866930
[4]	HENRIK B S, STEL J M, MARJIN V D, et al. Acute and chronic toxicity of short chained perfluoroalkyl substances to daphnia magna[J] . Environmental Pollution, 2015,198:47-53. doi: 10.1016/j.envpol.2014.12.025 pmid: 25553346
[5]	JIANG J, ZHANG G, WANG Q, et al. Novel fluorinated polymers containing short perfluorobutyl side chains and their super wetting performance on diverse subs-trates[J]. Acs Appl Mater Interfaces, 2016,8(16):10513-10523. pmid: 27052113
[6]	ZHANG Q, WANG Q, ZHAN X, et al. Synjournal and performance of novel fluorinated acrylate polymers:preparation and reactivity of short perfluoroalkyl group containing monomers[J]. Industrial & Engineering Chemistry Research, 2014,53(19):18026-18034.
[7]	李晓伟. 新型含全氟短碳链拒水拒油整理剂的合成与应用[D]. 上海:东华大学, 2014: 50-51.
	LI Xiaowei. Preparation and application of novel water and oil-repellent finishing agent containing a short perfluoroalkyl chain[D]. Shanghai:Donghua University, 2014: 50-51.
[8]	DONG C, LU Z, ZHANG F, et al. Preparation and properties of cotton fabrics treated with a novel polysiloxane water repellent and flame retardant[J]. Materials Letters, 2015,152:276-279. doi: 10.1016/j.matlet.2015.03.132
[9]	隋智慧, 杨康乐, 陈杰, 等. 含氟聚丙烯酸酯乳液整理剂的性能及其应用[J]. 纺织学报, 2016,37(9):100-105.
	SUI Zhihui, YANG Kangle, CHEN Jie, et al. Properties and application of fluorine-containing acrylate copolymer emulsion as finishing agent[J]. Journal of Textile Research, 2016,37(9):100-105.
[10]	DENG B, CAI R, YU Y, et al. Laundering durability of superhydrophobic cotton fabric[J]. Advanced Materials, 2010,22(48):5473. doi: 10.1002/adma.201002614 pmid: 20941799

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预处理方法	接触角
预处理方法	水	橄榄油	十六烷
原样	148	138	114
等离子体预处理	151	140	120
超声波预处理	150	138	117

焙烘温度/℃	接触角/(°)			白度/%
焙烘温度/℃	水	橄榄油	十六烷	白度/%
140	153	149	128	75
150	156	152	130	70
160	160	154	135	69
170	157	153	133	61
180	158	151	132	57

试样	C	O	F
棉织物原样	66.49	33.51	—
整理后棉织物	41.15	16.25	42.60

织物	断裂强力/N		折皱回复角/(°)
织物	经向	纬向	急弹	缓弹
棉织物原样	674	332	136	157
最佳工艺整理棉织物	667	316	185	213
变化率/%	-1.2	-4.8	36.1	36.0

基于短链含氟丙烯酸酯细乳液的棉织物拒水拒油整理

Water and oil repellent finishing of cotton fabric based on fluoroacrylate miniemulsion

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焙烘时间/min	接触角/(°)			白度/%
焙烘时间/min	水	橄榄油	十六烷	白度/%
1	152	147	125	76
2	157	150	129	74
3	160	154	135	73
4	159	151	136	69
5	158	150	132	62