黏合剂的合成及其在分散蓝79微水印花中的应用

doi:10.13475/j.fzxb.20180503108

纺织学报 ›› 2019, Vol. 40 ›› Issue (06): 50-57.doi: 10.13475/j.fzxb.20180503108

黏合剂的合成及其在分散蓝79微水印花中的应用

艾丽¹, 朱亚伟¹^,²()

1.苏州大学纺织与服装工程学院, 江苏苏州 215021
2.现代丝绸国家工程实验室, 江苏苏州 215123

收稿日期:2018-05-14 修回日期:2019-03-11 出版日期:2019-06-15 发布日期:2019-06-25
通讯作者: 朱亚伟
作者简介:艾丽(1985—),女,博士生。主要研究方向为染料商品技术及纺织品印染新技术。
基金资助:
江苏省重点企业研发机构提升项目(BM2011199二期);江苏省省级前瞻性研究专项项目(BE2014058);江苏省先进纺织工程技术中心项目(XJFZ/2016/17)

Synthesis of binder and application in polyester fabric with micro-water printing of disperse blue 79

AI Li¹, ZHU Yawei¹^,²()

1. School of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
2. National Engineering Laboratory for the Modern Silk (Suzhou), Suzhou, Jiangsu 215123, China

Received:2018-05-14 Revised:2019-03-11 Online:2019-06-15 Published:2019-06-25
Contact: ZHU Yawei

摘要/Abstract

摘要：

为降低分散染料直接印花废水废渣排放量,采用预乳化种子半连续乳液聚合法,以八甲基环四硅氧烷、丙烯酸丁酯、丙烯腈、苯乙烯、甲基丙烯酸、N-羟甲基丙烯酰胺为主要原料,制备了4种有机硅改性聚丙烯酸酯乳液。借助红外光谱、X射线光电子能谱表征了黏合剂的结构和性能;考察了黏合剂在液体分散蓝B-79微水印花中的作用;对比了微水印花和常规直接印花的后处理对废水排放及色牢度的影响。结果表明:黏合剂2和3应用于直接印花可提高染料固着率;微水印花织物仅需要80 ℃水洗,皂洗色牢度和干/湿摩擦色牢度都达4~5级;其废水化学需氧量值、残渣量和残留染料浓度仅是分散蓝H2GL直接印花的1/20、1/5和1/25,是一种绿色环保印花工艺。

关键词: 微水印花, 黏合剂, 分散染料, 色牢度, 化学需氧量

Abstract:

In order to reduce the disperse dye direct printing wastewater emission, the silicone-modified polyacrylate latex as polyester fiber binder was synthesized by the emulsion polymerization using butyl acrylate, styrene, acrylonitrile and octamethylcyclotetrasiloxane, methacrylic acid and N-methylol acrylamide as reactive monomers. The Fourier transform infrared spectrometer and X-ray photoelectron spectroscopy were adopted to characterize the chemical structure. The function of the silicone-modified polyacrylate binder in micro-water printing process of liquid disperse dye B-79 was investigated. The influence of post-treatment in conventional direct printing and micro-water printing on wastewater properties and color fastness was compared. The results show that the silicone-modified polyacrylates binder applied in directly printing can increase the dye uptake. After washing in hot water at 80 ℃, soaping fastness and dry/wet rubbing fastness are up to 4-5 level by the micro-water printing process. The value of chemical oxygen demand, the amount of residue and the dye concentration of wastewater are 1/20, 1/5and 1/25 of those by direct printing using disperse blue H2GL. Therefore, the proposed process is green and environment-friendly.

Key words: micro-water printing, binder, disperse dye, color fastness, chemical oxygen demand

中图分类号:

TS194.43

艾丽, 朱亚伟. 黏合剂的合成及其在分散蓝79微水印花中的应用[J]. 纺织学报, 2019, 40(06): 50-57.

AI Li, ZHU Yawei. Synthesis of binder and application in polyester fabric with micro-water printing of disperse blue 79[J]. Journal of Textile Research, 2019, 40(06): 50-57.

图/表 9

表1

表2

图1

图2

表3

表4

图3

表5

表6

参考文献 17

[1]	CAI Z S, YANG C S, ZHU X M. Preparation of quaternized carboxymethyl chitosan and its capacity to flocculate COD from printing wastewater[J]. Journal of Applied Polymer Science, 2010,118(1):299-305.
[2]	BILIŃSKA L, GMUREK M, LEDAKOWICZ S. Comparison between industrial and simulated textile wastewater treatment by AOPs-biodegradability, toxicity and cost assessment[J]. Chemical Engineering Journal, 2016,306:550-559.
[3]	ZYDOWICZ N, NZIMBA-GANYANAD E, ZYDOWICZ N. PMMA microcapsules containing water-soluble dyes obtained by double emulsion/solvent evaporation technique[J]. Polymer Bulletin, 2002,47(5):457-463.
[4]	JI J L, CHEN S L, YANG X J, et al. The dyeing of nylon with a microencapsulated disperse dye[J]. Coloration Technology, 2007,123(5):333-338.
[5]	JUN J H, SAWADA K, UEDA M, et al. Application of perfluoropolyether reverse micelles in supercritical CO₂ to dyeing process[J]. Dyes & Pigments, 2004,61(1):17-22.
[6]	朱亚伟, 丁志平, 高建波 , 等.一种浆状分散染料及其制备方法与应用:102924970A [P]. 2015-12-02.
	ZHU Yawei, DING Zhiping, GAO Jianbo, et al. A slurry disperse dye and a preparation method and application: 102924970A [P]. 2015-12-02.
[7]	罗韬. 分散染料微量聚合印花技术研究[D]. 苏州:苏州大学, 2014: 5.
	LUO Tao. Research on a micro-polymerization printing of disperse dyes[D]. Suzhou:Soochow University, 2014: 5.
[8]	高建波, 钱琴芳, 陆叶洪, 等. 合成增稠剂的流变性及在涤纶印花中的应用[J]. 丝绸, 2016,53(5):6-11.
	GAO Jianbo, QIAN Qinfang, LU Yehong, et al. Rheological property of synthetic thickener and its application in polyester printing[J]. Journal of Silk, 2016,53(5):6-11.
[9]	SUI Z, PANG W, SONG J, et al. Preparation of silicone-modified acrylic ester emulsion adhesive with core-shell structure[J]. Asian Journal of Chemistry, 2014,26(14):4435-4438.
[10]	JIANG Xue, HU Huilu, BAI Yuci, et al. Synjournal and properties of the vinyl silicone oil modified polyacrylate core-shell latex as a binder for pigment printing[J]. Journal of Adhesion Science and Technology, 2013,27(2):1-11.
[11]	JIANG Xue, GU Jian, TIAN Xiuzhi, et al. Synjournal of the hydroxyl-containing poly(dimethyl siloxane) modified polyacrylate core-shell latex and the application as a novel binder for pigment printing of fabric[J]. Journal of Dispersion Science and Technology, 2010,32(9):1266-1272.
[12]	CAO S, LIU B, DENG X, et al. Core/shell particles containing 3-(methacryloxypropyl)-trimethoxysilane in the shell: synjournal, characterization, and app-lication[J]. Macromolecular Bioscience, 2005,5(7):669-676. doi: 10.1002/mabi.200500011 pmid: 16010694
[13]	BAHMANI S A, EAST G C, HOLME I. The application of chitosan in pigment printing[J]. Coloration Technology, 2010,116(3):94-99.
[14]	EL-SHISHTAWY R M, NASSAR S H. Cationic pretreatment of cotton fabric for anionic dye and pigment printing with better fastness properties[J]. Coloration Technology, 2002,118(3):115-120.
[15]	MENG Y, TANG B, XIU J, et al. Simple fabrication of colloidal crystal structural color films with good mechanical stability and high hydrophobicity[J]. Dyes & Pigments, 2015,123:420-426.
[16]	LI Xi, LIU Y, LI Jiawen, et al. Influence of the optical multi-film thickness on the saturation of the structural color displayed[J]. Advances in Natural Science, 2010,3(2):317-323.
[17]	CATHELL M D, SCHAUER C L. Structurally colored thin films of Ca²⁺-cross-linked alginate [J]. Biomacromolecules, 2007,8(1):33. doi: 10.1021/bm060433f pmid: 17206785

相关文章 15

[1]	王纯怡, 吴伟, 王健, 徐红, 毛志平. C.I.分散棕19 在超临界CO₂ 及水中溶解性的分子动力学模拟[J]. 纺织学报, 2020, 41(09): 95-101.
[2]	姬洪, 张阳, 陈康, 宋明根, 蒋权, 范永贵, 张玉梅, 王华平. 基于动力学特性的黑色高强聚酯工业丝研发[J]. 纺织学报, 2020, 41(04): 1-8.
[3]	王小艳, 杜金梅, 彭铃淇, 荆丽丽, 许长海. 涤纶针织物碱减量和染色一浴一步法工艺 [J]. 纺织学报, 2020, 41(01): 80-87.
[4]	刘越, 莫林祥, 陈丰. 拼混型黑色分散染料的配伍性及其染色性能[J]. 纺织学报, 2019, 40(12): 63-67.
[5]	江华, 张志恒, 蔡金芳, 陈维国, 崔志华, 孙岩峰. 芳伯胺染料对蚕丝织物的重氮化-偶合染色及工艺调控[J]. 纺织学报, 2019, 40(11): 100-105.
[6]	武奇奇, 李敏, 刘怡宁, 王乐军, 张丽平, 付少海. 聚乳酸织物载体染色性能[J]. 纺织学报, 2019, 40(01): 79-83.
[7]	艾丽曹红梅朱亚伟丁志平. 基于液体分散染料的微量印花技术[J]. 纺织学报, 2018, 39(09): 77-83.
[8]	梁静钟毅毛志平徐红张琳萍隋晓锋. 晶型对分散染料染色性能的影响[J]. 纺织学报, 2018, 39(07): 69-73.
[9]	吴海婷蒋小娟蔡再生. 环保阻燃型静电植绒黏合剂的合成及其应用[J]. 纺织学报, 2018, 39(06): 96-100.
[10]	舒大武房宽峻刘秀明刘曰兴蔡玉青门雅静李付杰. 活性染料无盐连续轧-蒸与冷轧堆染色效果的比较[J]. 纺织学报, 2018, 39(04): 77-81.
[11]	叶思佳杜奕铃张永高郑今欢. 涤纶起绒织物着色烂花印花中分散染料的耐碱性[J]. 纺织学报, 2018, 39(01): 98-103.
[12]	王晓春闫金龙张丽平赵国樑张健飞. 超高分子质量聚乙烯纤维分散染料染色性能[J]. 纺织学报, 2017, 38(11): 84-90.
[13]	郑环达胥维昌赵强岳成君单世宝闫俊郑来久. 涤纶筒纱超临界二氧化碳流体染色工程化装备与工艺[J]. 纺织学报, 2017, 38(08): 86-90.
[14]	傅伟松周乃锋陈华祥唐智勇. 利用分散染料废水的硫酸铵自动连续化制备[J]. 纺织学报, 2017, 38(07): 107-111.
[15]	冯艳荣袁剑民王文力李伟. 水性聚丙烯酸酯涂料染色黏合剂的合成及其性能[J]. 纺织学报, 2017, 38(04): 90-96.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

黏合剂编号	Zeta电位/ mV	平均粒径 D₅₀/nm	PDI	稳定性
黏合剂编号	Zeta电位/ mV	平均粒径 D₅₀/nm	PDI	冻融	储存	稀释	力学	耐盐
1^#	-32.20	100	0.12	凝聚	少量沉淀	良好	良好	良好
2^#	-56.57	77	0.15	良好	良好	良好	良好	良好
3^#	-45.89	84	0.18	良好	良好	良好	良好	良好
4^#	-30.44	110	0.20	良好	微量沉淀	良好	良好	凝聚

黏合剂编号	m(BA)∶m(St)∶m(AN)∶m(D4)∶ m(MAA)∶m(NMA)	膜拉伸性			玻璃化转变温度/℃
黏合剂编号	m(BA)∶m(St)∶m(AN)∶m(D4)∶ m(MAA)∶m(NMA)	断裂强力/cN	断裂伸长率/%	黏弹性	玻璃化转变温度/℃
1^#	15.55∶1.90∶2.10∶15.45∶0∶0	-	-	-	-84.9
2^#	17.20∶2.85∶1.95∶9.50∶0.60∶0.90	83	1 008	较好	-65.7
3^#	15.00∶5.00∶5.00∶7.00∶0.30∶0.70	204	1 191	较好	-44.5
4^#	6.95∶7.50∶6.80∶8.20∶0.95∶2.60	1 259	145	硬	-24.7

黏合剂编号	染料量/(mg·L^-1)				固色率/%
黏合剂编号	皂洗前	皂洗后	皂洗液		固色率/%
1^#	912.50	836.65		75.85	91.69
2^#	988.36	932.04		56.31	94.30
3^#	995.21	945.83		42.52	95.04
4^#	1 020.53	949.28		71.25	93.02
无添加	1 022.83	941.24		81.60	92.02

黏合剂编号	未皂洗				皂洗				色差
	L^*	a^*	b^*	K/S值	L^*	a^*	b^*	K/S值	ΔL^*	Δa^*		Δb^*	ΔC^*	ΔH^*	ΔE_CMC
	1^#	40.69	1.20	-40.74	10.48	42.62	0.45	-40.85	9.17	1.93	-0.75		-0.11	0.09	0.75	1.17
2^#	39.00	2.25	-41.44	12.29	40.29	1.50	-41.18	10.50	1.29	-0.75		0.26	-0.29	0.74	0.86
3^#	37.90	2.60	-41.34	13.21	40.44	1.09	-40.85	10.42	2.54	-1.51		0.49	-0.56	1.49	1.62
4^#	39.00	1.63	-41.00	12.00	41.23	0.73	-40.86	10.08	2.23	-0.90		0.14	-0.17	0.90	1.29
无添加	39.08	2.40	-41.87	11.75	40.65	1.76	-41.89	10.12	1.57	-0.64		-0.02	-0.01	0.64	0.90

后处理条件	pH值	COD值/ (mg·L^-1)	残渣量/ (g·(100 g)^-1)	染料浓度/(mg·L^-1)
A2	6.5~7.0	48.3	3.45	1.43
B3	8.7	976.0	16.64	36.73

黏合剂的合成及其在分散蓝79微水印花中的应用

Synthesis of binder and application in polyester fabric with micro-water printing of disperse blue 79

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 17

相关文章 15

Metrics

本文评价

推荐阅读 0

后处理工艺	后处理			未后处理
后处理工艺	皂洗牢度	干摩擦牢度	湿摩擦牢度	皂洗牢度	干摩擦牢度	湿摩擦牢度
A1	4	4~5	4	4	4~5	4
A2	4~5	4~5	4~5
A3	4~5	4~5	4~5
A4	4~5	4~5	4~5
B1	4	4~5	4~5	2~3	3	2~3
B2	4	4~5	4~5
B3	4~5	4~5	4~5