纺织学报 ›› 2019, Vol. 40 ›› Issue (8): 124-129.doi: 10.13475/j.fzxb.20180805606

• 染整与化学品 • 上一篇    下一篇

光致变色纺织品的检测方法

赵博研(), 赵玉珠   

  1. 上海市质量监督检验技术研究院纤维检验所, 上海 200040
  • 收稿日期:2018-08-23 修回日期:2019-04-29 出版日期:2019-08-15 发布日期:2019-08-16
  • 作者简介:赵博研(1986—),女,硕士。主要研究方向为功能性纺织品检测。E-mail: zhaoby@sqi.org.cn
  • 基金资助:
    上海市市场监督管理局项目(2017-33)

Detection methods of photochromic textiles

ZHAO Boyan(), ZHAO Yuzhu   

  1. Shanghai Institute of Quality Inspection and Technical Research Institute of Fiber Inspection, Shanghai 200040, China
  • Received:2018-08-23 Revised:2019-04-29 Online:2019-08-15 Published:2019-08-16

摘要:

针对光致变色纺织品变色性能检测方法缺失的问题,以商品化的光致变色纺织品为研究对象,通过模拟光致激发环境,采用手持式分光测色仪测量样品的颜色变化,研究光致变色纺织品的变色和恢复机制,建立光致变色纺织品的检测方法。结果表明:受光照射后样品颜色变化呈先深后浅趋势,并在照射3 min左右达到稳定;太阳光辐照度不会影响样品的变色与恢复过程,采用AM1.5滤光片,辐照度为1 000 W/m 2的标准太阳光作为激发光源照射样品5 min,并遮光恢复30 min,分别使用人眼和仪器评级测定样品的变色和恢复色差,均可有效检测光致变色纺织品的变色性能;该检测方法简单易操作,可靠性强,可标准化。

关键词: 光致变色纺织品, 变色性能, 检测方法, 人眼评级, 色差测量

Abstract:

In order to provide the detection methods for the chromogenic performance of the photochromic textiles, taking commercial photochromic textiles as research objects, by simulating the excitation environment and measuring the color change of the commercial photochromic textiles with a portable spectrophotometer, the discoloration and recovery mechanism were studied and the detection methods of photochromic textiles were established. The results show that the color change of the samples increases first, then decreases and reaches stable after 3 min under irradiation. The discoloration and recovery processes are not influenced by the solar irradiance. One standard sunlight is provided as an excitation light source by using an AM1.5 filter and adjusting the irradiance to 1 000 W/m 2. The samples are irradiated for 5 min, and recovered for 30 min. The discoloration and recovery chromatic aberration of the photochromic textiles are determined by human eyes and instrument assessment to effectively detect the chromogenic performance of the photochromic textiles. The detection methods are simple, easy to operate,highly reliable, and can be standardized.

Key words: photochromic textile, chromogenic performance, detection method, eye rating, chromatic aberration measurement

中图分类号: 

  • TS107

图1

光致变色纺织品样品"

图2

氙灯光源与标准太阳光光谱对比图"

图3

光致变色纺织品1 000 W/m2下照射5 min的ΔEF曲线"

图4

光致变色能级图 注:ΔE为材料A到材料B的活化能势垒;ΔE'为材料B到材料A的活化能势垒;h为普朗克常量;v为激发光源的频率。"

图5

不同光致变色纺织品1 000和500 W/m2辐照度下ΔEF趋势图"

表1

光致变色纺织品恢复速率测试结果"

样品编号 ΔEF1 ΔEF2 νh/%
1# 41.20 10.34 75
2# 39.88 25.89 35
3# 26.95 19.50 28
4# 16.76 0.55 97
5# 12.92 0.72 94
6# 11.42 5.58 51

表2

不同保存时间下样品的人眼与仪器评级对比表"

样品
编号
照射5 min 遮光保
存5 min
遮光保
存10 min
遮光保
存30 min
人眼 仪器 人眼 仪器 人眼 仪器 人眼 仪器
1# 1 1 4~5 4 4~5 4 4~5 4~5
2# 2~3 1~2 4~5 3~4 4~5 3~4 4~5 4
3# 1 1 4~5 3~4 4~5 4 4~5 4~5
4# 1 1 3 3 4 3~4 4~5 4
5# 1 1 4~5 4~5 4~5 4~5 4~5 4~5
6# 2 2 4 4~5 4~5 4 4~5 4~5

表3

颜色变化ΔEF与变色灰卡级数GSc对应表"

ΔEF的范围 GSc/级 ΔEF的范围 GSc/级
<0.40 5 4.10≤ΔEF<5.80 2~3
0.40≤ΔEF<1.25 4~5 5.80≤ΔEF<8.20 2
1.25≤ΔEF<2.10 4 8.20≤ΔEF<11.6 1~2
2.10≤ΔEF<2.95 3~4 ≥11.6 1
2.95≤ΔEF<4.10 3

表4

光致变色纺织品人眼和仪器评级结果"

样品
编号
变色色差 恢复色差
人眼 仪器 人眼 仪器
1# 1 1 4~5 4~5
2# 2~3 1~2 4~5 4
3# 1 1 4~5 4~5
4# 1 1 4~5 4
5# 1 1 4~5 4~5
6# 2 2 4~5 4~5

图6

模拟色对比图"

[1] 苏启来, 杜文琴 . 光致变色织物研究进展[J]. 纺织导报, 2011(1):71-72.
SU Qilai, DU Wenqin . Reserch progress of photochromic fabrics[J]. China Textile Leader, 2011(1):71-72.
[2] 马倩, 王可, 王曙东 , 等. 感光变色防紫外面料的开发[J]. 上海纺织科技, 2016,44(9):8-10.
MA Qian, WANG Ke, WANG Shudong , et al. Development of photochromic fabric with anti-UV property[J]. Shanghai Textile Science & Technology, 2016,44(9):8-10.
[3] 戴淑娇 . 光致变色纺织品的制备及其发展趋势[J]. 轻纺工业与技术, 2014,43(5):24-26.
DAI Shujiao . Preparation and development trend of photochromic textiles[J]. Light and Textile Industry and Technology, 2014,43(5):24-26.
[4] DEFFIEUX A, HSIEH W C, SQUIRE D R , et al. Radiation-induced cationic polymerization of vinyl ethers in solution: 2: polymerization of ethyl vinyl ether in methylene dichloride solution[J]. Polymer, 1982,23(1):65-68.
[5] 樊美公, 姚建年, 佟振合 , 等. 分子光化学与光功能材料科学[M]. 北京: 科学出版社, 2009: 481.
FAN Meigong, YAO Jiannian, TONG Zhenhe , et al. Molecular Photochemical and Optical Functional Materials Science[M]. Beijing: Science Press, 2009: 481.
[6] 杨旭 . 光致变色材料在现代运动便装设计中的应用[D]. 天津:天津科技大学, 2015: 5-20.
YANG Xu . Photochromic materials in the application of the modern sports casual wear design[D]. Tianjin: Tianjin University of Science & Technology, 2015: 5-20.
[7] 万震, 王炜, 谢均 . 光敏变色材料及其在纺织品上的应用[J]. 针织工业, 2003(6):87-89.
WAN Zhen, WANG Wei, XIE Jun . Photochromic materials and their application in textiles[J]. Knitting Industries, 2003(6):87-89.
[8] 况子明 . 聚氨酯-螺噁嗪光致变色微胶囊的制备及对真丝织物整理[D]. 合肥:安徽农业大学, 2015: 1-15.
KUANG Ziming . Preparation of polyurethane-spirooxazine photochromic microcapsule and the finishing on silk fabric[D]. Hefei:Anhui Agricultural University, 2015: 1-15.
[9] 范菲 . 光致变色微胶囊杂化溶胶整理织物的湿舒适性研究[J]. 纺织科技进展, 2017(5):15-18,22.
FAN Fei . Research on wet comfort of the fabric treated with photochromic microcapsule hybrid sol[J]. Progress in Textile Science & Technology, 2017(5):15-18,22.
[10] 周华建 . 基于光热变色储能功能的微胶囊性能研究及应用[D]. 天津:天津工业大学, 2017: 3-17.
ZHOU Huajian . Research and application of microcapsule performance based on photothermal discoloration energy storage function[D]. Tianjin:Tianjin Polytechnic University, 2017: 3-17.
[11] 刘亚洁 . 光致变色储能材料的复合及性能研究[D]. 天津:天津工业大学, 2016: 20-25.
LIU Yajie . Research on the composite and properties of photochromic energy storage materials[D]. Tianjin:Tianjin Polytechnic University, 2016: 20-25.
[12] 阴俊, 谈建国 . 上海地区地面太阳紫外辐射的观测和分析[J]. 热带气象学报, 2006 ( 1):86-90.
YIN Jun, TAN Jianguo . Observation and analysis of surface solar ultraviolet radiation in Shanghai area[J]. Journal of Tropical Meteorology, 2006 ( 1):86-90.
[13] 刘小红, 陈海宏 . 光致变色功能织物的制备及应用[J]. 现代纺织技术, 2012,20(6):58-60.
LIU Xiaohong, CHEN Haihong . The preparation and application of photochromic functional fabrics[J]. Advanced Textile Technology, 2012,20(6):58-60.
[14] 冯社永, 顾利霞 . 光敏变色纤维材料[J]. 合成纤维工业, 1997(3):36-40.
FENG Sheyong, GU Lixia . Photochromic fiber mate-rial[J]. China Synthetic Fiber Industry, 1997(3):36-40.
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