纺织学报 ›› 2019, Vol. 40 ›› Issue (8): 85-88.doi: 10.13475/j.fzxb.20180803505

• 染整与化学品 • 上一篇    下一篇

基于斜投影的纯羊毛毛线中酸性红26的快速检测

张景清, 粟晖(), 梁晓芸, 陈维骥, 姚志湘   

  1. 广西科技大学 生物与化学工程学院, 广西 柳州 545006
  • 收稿日期:2018-08-13 修回日期:2019-04-30 出版日期:2019-08-15 发布日期:2019-08-16
  • 通讯作者: 粟晖
  • 作者简介:张景清(1992—),男,硕士生。主要研究方向为化工过程分析技术。
  • 基金资助:
    广西自然科学基金项目(2015GXNSFAA139038);广西大学生创新创业训练计划项目(201710594166)

Rapid detection of banned dye Acid Red 26 in pure wool thread based on oblique projection

ZHANG Jingqing, SU Hui(), LIANG Xiaoyun, CHEN Weiji, YAO Zhixiang   

  1. School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou, Guangxi 545006, China
  • Received:2018-08-13 Revised:2019-04-30 Online:2019-08-15 Published:2019-08-16
  • Contact: SU Hui

RichHTML

3

PDF (PC)

33

摘要：

针对用传统方式检测纺织品中禁用染料操作难、成本高、耗时长、危害大等弊端,以禁用染料酸性红26为例,采用可见反射光强光谱分析法与化学计量学结合,基于斜投影建立了一种纯羊毛毛线中酸性红26的定量分析方法。结果表明:纯羊毛毛线中酸性红26的含量在0.17~5.11 mg/g范围内时,与利用斜投影算法从混合组分信号中切割出的酸性红26的信号线性关系良好,所建立标准曲线方程的决定系数为0.995 8,相对标准偏差为1.79%;利用该方法预测未知样本中酸性红26的含量,预测值与真实值的相对误差均小于10%,该方法分析速度快,且分析过程操作简单,可实现对酸性红26的无损检测。

关键词: 斜投影算法, 可见反射光强光谱, 纯羊毛毛线, 酸性红26, 快速检测

Abstract:

In order to overcome the shortcomings of conventional methods for detecting banned dyes on textiles of difficult operation, high cost, long time and great hazard, a quantitative analysis method of Acid Red 26 on wool thread was established based on the oblique projection construction algorithm using the combination of visible reflection intensity spectrum analysis and chemometrics. The results show that the linear degree of the standard curve equation is high in the range of 0.17-5.11 mg/g (coefficient of determination is 0.995 8, relative standard deliation is 1.79%). The relative error about the content of Acid Red 26 in the unknown sample is lower than 10%. The detection method is simple in operation, high in detection efficiency, and realizes rapid non-destructive detection of Acid Red 26.

Key words: oblique projection algorithm, visible light intensity spectrum, wool thread, Acid Red 26, rapid detection

中图分类号: 

  • TQ610.7

图1

标准样本预处理前后的光谱对比"

图2

酸性红26的标准曲线图"

表1

样本中酸性红26的含量"

编
号		 真实值/
(mg·g-1)		 预测值/
(mg·g-1)		 偏差/
(mg·g-1)		 相对误差/
%
1 0.65 0.63 -0.02 2.48
2 0.83 0.84 0.02 1.85
3 1.05 1.00 -0.05 5.14
4 1.38 1.27 -0.11 7.65
5 1.59 1.69 0.10 6.28
6 1.79 1.66 -0.13 7.03
7 1.85 1.74 -0.11 5.71
8 2.01 1.84 -0.17 8.23
9 2.15 2.34 0.20 9.09
10 2.36 2.31 -0.05 2.27
11 2.64 2.68 0.04 1.49
12 2.88 2.77 -0.11 3.65
13 2.96 2.95 -0.02 0.58
14 3.27 3.17 -0.10 2.93
15 3.96 3.61 -0.35 8.94
16 4.30 3.96 -0.34 7.86
17 4.37 4.14 -0.23 5.23
18 4.80 4.60 -0.20 4.18
19 4.67 4.38 -0.29 6.15
[1] 魏亮, 陈小光, 黄波 , 等. 偶氮染料废水厌氧生物脱色强化[J]. 纺织学报, 2018,39(8):83-87.
WEI Liang, CHEN Xiaoguang, HUANG Bo , et al. Anaerobic biological decolorization enhancement of azo dye wastewater[J]. Journal of Textile Research, 2018,39(8):83-87.
[2] 姜红 . 薄层色谱法鉴别同种颜色涤棉纤维上的染料[J]. 印染助剂, 2002(1):52-54.
JIANG Hong . TLC method for the identification of dyes on the same color polyester fibres[J]. Textile Auxiliaries, 2002(1):52-54.
[3] 王倩, 卢鸯 . 基于超高压液相色谱串联质谱的致癌芳香胺同分异构体快速鉴别[J]. 现代纺织技术, 2015(3):62-64.
WANG Qian, LU Yang . Rapid identification of carcinogenic aromatic amine isomers based on tandem mass spectrometry with ultrahigh pressure liquid chromatography[J]. Advanced Textile Technology, 2015 ( 3):62-64.
[4] LI Xueyang, YANG Yongchao, YANG Xue . Determination of polycyclic aromatic hydrocarbons in textiles trometry and tandem mass spectrometry[J]. Chromatographia, 2010,72:85-93.
doi: 10.1365/s10337-010-1634-6
[5] YANG Fei, BIAN Zhaoyang, LI Zhonghao , et al. Determination of aromatic amines released from azo dyes in paper packaging by liquid chromatography-tandem mass spectrometry[J]. Journal of AOAC International, 2016,99(5):1370-1376.
doi: 10.5740/jaoacint.16-0068 pmid: 27318128
[6] 叶曦雯, 彭燕, 牛增元 . 超高效液相色谱-线性离子阱/静电场轨道阱高分辨质谱鉴别纺织品中禁用芳香胺及其异构体[J]. 色谱, 2014,32(9):1005-1012.
YE Xiwen, PENG Yan, NIU Zengyuan . Ultra-high performance liquid chromatography-linear ion trap/electrostatic field track well high resolution mass spectrometry for identification of prohibited aromatic amines and their isomers in textiles[J]. Chromatographic, 2014,32(9):1005-1012.
[7] HAN J, WANROOIJ J, VAN B M , et al. Characterisation of chemical components for identifying historical Chinese textile dyes by ultra high performance liquid chromatography-photodiode array-electrospray ionisation mass spectrometer[J]. Journal of Chromatography A, 2017,1479:87-96.
doi: 10.1016/j.chroma.2016.11.044 pmid: 27986289
[8] 李志刚 . 偶氮染料降解氧化产物苯胺的液相色谱/质谱联用法测定[J]. 纺织学报, 2015,36(5):69-73.
LI Zhigang . Determination of aniline by oxidation of azo dyes by liquid chromatography/mass spectrometry[J]. Journal of Textile Research, 2015,36(5):69-73.
[9] MA Qiang, BAI Hua, ZAHNG Qing , et al. Determination of carcinogenic and allergenic dyestuffs in toys by LC coupled to UV/Vis spectrometry and tandem mass spectrometry[J]. Chromatographia, 2010,72(1/2):85-93.
doi: 10.1365/s10337-010-1634-6
[10] COCHRAN K H, BARRY J A, MUDDIMAN D C , et al. Direct analysis of textile fabrics and dyes using infrared matrix-assisted laser desorption electrospray ionization mass spectrometry[J]. Analytical Chemistry, 2013,85(2):831-836.
doi: 10.1021/ac302519n pmid: 23237031
[11] AHLSTROM L H, RAAB J, MATHIASSON L , et al. Application of standard addition methodology for determination of banned azo dyes in different leather types[J]. China Leather, 2008,552(1):76-80.
[12] 杨向妮, 姚志湘, 粟晖 , 等. 斜投影-空间夹角判据用于苯扎氯铵紫外光谱定量分析[J]. 中国消毒学杂志, 2016,33(11):1037-1040,1043.
YANG Xiangni, YAO Zhixiang, SU Hui , et al. Oblique projection-space angle criterion for the quantitative analysis of the ultraviolet spectra of benzoyl chloride[J]. Chinese Journal of Disinfection, 2016,33(11):1037-1040,1043.
[13] 葛军, 姚志湘, 粟晖 , 等. 基于斜投影算法对混合染液不展开多波长薄层色谱定量分析[J]. 印染助剂, 2013,30(10):47-50.
GE Jun, YAO Zhixiang, SU Hui , et al. Quantitative analysis of multi-wavelength thin-layer chromatography based on oblique projection algorithm[J]. Textile Auxiliaries, 2013,30(10):47-50.
[14] BEHRENS R T, SCHARF L L . Signal processing applications of oblique projection operators[J]. IEEE Transactions on Signal Processing, 1994,42(6):1413-1424.
doi: 10.1109/78.286957
No related articles found!
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] 薛元;曹建达;孙明宝;孙世元. 芯鞘型长丝/短纤包芯纱织物悬垂特性的研究[J]. 纺织学报, 2004, 25(03): 19 -20 .
[2] 郭秉臣. 毛纺直型精梳机圆梳的梳理速度及梳理效能的分析[J]. 纺织学报, 1984, 5(09): 30 -32 .
[3] 魏静. 翻折领翘势的变化[J]. 纺织学报, 2005, 26(5): 103 -105 .
[4] 李伟锋. 基于RS-485总线的土工膜水力性能测试仪研制[J]. 纺织学报, 2005, 26(1): 107 -109 .
[5] 金大滨;李良才. 环锭纱动态捻度测定仪[J]. 纺织学报, 1982, 3(10): 19 -20 .
[6] 张寿欣. 两级分布式布机监测系统通过鉴定[J]. 纺织学报, 1986, 7(05): 27 .
[7] 李红;郑来久. 改性亚麻染色性能的研究[J]. 纺织学报, 2002, 23(06): 10 -11 .
[8] 吴小琴;王府梅. 差别化纤维织物蓬松丰满度的预测[J]. 纺织学报, 2003, 24(05): 33 -34 .
[9] 林子务. 老机新工艺整理全毛哔叽的探讨[J]. 纺织学报, 1997, 18(04): 46 -48 .
[10] 吕家华;陈水林;华载文. 合成纤维织物的抗静电整理[J]. 纺织学报, 1995, 16(06): 59 -61 .
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发