锦纶基磁性纤维的制备及其性能

doi:10.13475/j.fzxb.20180907307

纺织学报 ›› 2019, Vol. 40 ›› Issue (11): 26-31.doi: 10.13475/j.fzxb.20180907307

锦纶基磁性纤维的制备及其性能

李昌龄¹, 王文聪¹, 华东², 周建平², 阚建兴², 王鸿博¹()

1.生态纺织教育部重点实验室(江南大学), 江苏无锡 214122
2.江苏纺织研究所股份有限公司, 江苏无锡 214024

收稿日期:2018-09-28 修回日期:2019-06-13 出版日期:2019-11-15 发布日期:2019-11-26
通讯作者: 王鸿博
作者简介:李昌龄(1995—),女,硕士生。主要研究方向为磁性功能纺织材料。
基金资助:
国家重点研发计划项目(2017YFB0309100);江苏省产学研前瞻性研究项目(BY2016022-23);国家自然科学基金项目(51703085);中央高校基本科研业务费专项资金资助项目(JUSRP1907A);江苏省自然科学基金项目(BK20170189)

Preparation and properties of polyamide-based magnetic fibers

LI Changling¹, WANG Wencong¹, HUA Dong², ZHOU Jianping², KAN Jianxing², WANG Hongbo¹()

1. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
2. Jiangsu Textile Research Institute Co., Ltd., Wuxi, Jiangsu 214024, China

Received:2018-09-28 Revised:2019-06-13 Online:2019-11-15 Published:2019-11-26
Contact: WANG Hongbo

摘要/Abstract

摘要：

为满足市场对磁性纺织品的需求,通过在锦纶纺丝熔体中分别添加磁性材料,成功制备锦纶基磁性纤维。借助红外光谱仪、X射线衍射仪、扫描电子显微镜、X射线能谱仪、差示扫描量热仪以及强力机等对锦纶基磁性纤维的分子结构、结晶结构、形态结构以及各项性能进行表征。结果表明:锦纶基磁性纤维中均匀分散着铁氧体磁粉;磁粉添加量对纤维的熔点影响较小;随磁粉添加量的增加,锦纶基磁性纤维的断裂强力逐渐减小,但即使磁粉含量为25%时,纤维的强力仍达2.50 cN/dtex,可满足织造要求;用锦纶基磁性纤维织制了3种不同规格的针织物,其磁感应强度均介于0.02~0.1 mT之间,随着纤维中磁粉添加量的增加,织物的磁感应强度增大。

关键词: 锦纶, 铁氧体磁性粉末, 磁性纤维, 磁感应强度

Abstract:

In order to meet the market demand for health-care textiles, polyamide-based magnetic fibers were successfully prepared by adding magnetic materials into polyamide spinning melt. The Fourier transform infrared spectrometry, X-ray diffraction, scanning electron microscopy, X-ray energy dispersive spectroscopy, differential scanning calorimetry, and tensile strength tester were carried out to analyze the chemical structure, crystal structure, morphology and various properties of the magnetic fibers. The results show that the ferrite magnetic powders are uniformly dispersed in nylon-based magnetic fibers; the magnetic powder content does not have much influence on the melting point of the nylon fiber; the breaking strength decreases with the increase of the magnetic powder content, but even if the magnetic powder content is up to 25%, the strength of the fiber is still 2.50 cN/dtex, which can meet the weaving requirements; and three different sizes of knitted fabrics were woven with nylon-based magnetic fibers, the three kinds of fabric have a magnetic flux density between 0.02 mT and 0.1 mT, and the magnetic flux density of the fabric increases with the content of the magnetic powder.

Key words: polyamide, magnetic powder, magnetic fiber, magnetic flux density

中图分类号:

TS151

李昌龄, 王文聪, 华东, 周建平, 阚建兴, 王鸿博. 锦纶基磁性纤维的制备及其性能[J]. 纺织学报, 2019, 40(11): 26-31.

LI Changling, WANG Wencong, HUA Dong, ZHOU Jianping, KAN Jianxing, WANG Hongbo. Preparation and properties of polyamide-based magnetic fibers[J]. Journal of Textile Research, 2019, 40(11): 26-31.

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参考文献 13

[1]	刘飞飞. 纺织品微磁场测试实验方法的研究[D]. 天津:天津工业大学, 2009:1-3.
	LIU Feifei. Research on testing methods of magnetic flux density of textiles[D]. Tianjin: Tianjin Polytechnic University, 2009: 1-3.
[2]	张博亚, 张如全. 纺织品磁性整理的研究进展[J]. 纺织导报, 2017(3):64-66.
	ZHANG Boya, ZHANG Ruquan. Research and development of magnetic finishing of textiles[J]. China Textile Leader, 2017(3):64-66.
[3]	高雪妮. 磁性纤维针织面料的研究与开发[D]. 西安: 西安工程大学, 2013:2-3.
	GAO Xueni. Research and development of magnetic fiber knitted fabric[D]. Xi'an: Xi'an Polytechnic University, 2013:2-3.
[4]	于高杰. 磁保健织物表面磁性测试与评价研究[D]. 苏州:苏州大学, 2013: 3.
	YU Gaojie. Evaluation and measurement of magnetic fabric performance[D]. Suzhou: Soochow University, 2013: 3.
[5]	万倩华, 潘志娟, 柳艳, 等. 含纳米粉体功能性纤维的制备方法[J]. 纺织学报, 2009,30(7):135-141.
	WAN Qianhua, PAN Zhijuan, LIU Yan, et al. Fabricating methods of functional fibers containing nanoparticles[J]. Journal of Textile Research, 2009,30(7):135-141.
[6]	文永奋. 医用及保健纺织品的开发[J]. 高科技与产业化, 2005(z1):93-96.
	WEN Yongfen. Development of medical and health textiles[J]. High-Technology & Industrialization, 2005(z1):93-96.
[7]	王玉新, 荆妙蕾, 闫妍, 等. 丙纶磁性纤维仿毛织物舒适性的多元回归分析及混纺比优化[J]. 毛纺科技, 2013,41(2):15-18.
	WANG Yuxin, JING Miaolei, YAN Yan, et al. Multiple regression analysis on comfort property of PP magnetic fiber wool-like fabrics and blended ratio optimization[J]. Wool Textile Journal, 2013,41(2):15-18.
[8]	周建平, 何卫星, 阚建兴, 等. 锦纶磁性复合纤维及其生产方法: 201611119249[P]. 2016-12-08.
	ZHOU Jianping, HE Weixing, KAN Jianxing, et al. Preparation of nylon-based magnetic composite fibers: 201611119249[P]. 2016-12-08.
[9]	马跃起, 龙家杰, 赵建平, 等. 超临界CO₂流体处理对锦纶6纤维的影响[J]. 丝绸, 2010(9):4-10.
	MA Yueqi, LONG Jiajie, ZHAO Jianping, et al. Effects of supercritical CO₂ fluid treatment on polyamide-6 fibers[J]. Journal of Silk, 2010(9):4-10.
[10]	向军, 褚艳秋, 周广振, 等. 电纺制备多孔Ni1-xZnxFe₂O₄超细纤维的结构与磁性能[J]. 无机材料学报, 2012,27(4):363-368.
	XIANG Jun, CHU Yanqiu, ZHOU Guangzhen, et al. Structure and magnetic properties of porous Ni1-xZnxFe2O4 ultrafine fibers prepared by electro spinning technique[J]. Journal of Inorganic Materials, 2012,27(4):363-368. doi: 10.3724/SP.J.1077.2012.00363
[11]	田西光. 钴镍铜和钴镍锌铁氧体纳米纤维的制备及其磁性能研究[D]. 兰州:兰州理工大学, 2017:24-26.
	TIAN Xiguang. Cobalt nickel copper and cobalt nickel zinc ferrite nanofibers fabricated by electrospinning: their structure and magnetic properties research[D]. Lanzhou: Lanzhou University of Technology, 2017:24-26.
[12]	郭利. 钛白粉表面改性对全消光锦纶纤维性能的影响[D]. 上海:东华大学, 2014: 48-49.
	GUO Li. Effect of surface modification of titanla on the properties of full dull PA6 fibers[D]. Shanghai: Donghua University, 2014: 48-49.
[13]	ZHANG H, ZHENG J Y. Immobilization of magnetic magnetite nanoparticle film on polyamide fabric[J]. Journal of Applied Polymer Science, 2012,125(5):3771-3777.

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[11]	吴菲非于高杰陈雁. 磁性纤维针织物表面磁场的分布[J]. 纺织学报, 2014, 35(8): 32-0.
[12]	吴菲非于高杰陈雁. 磁性纤维含量对针织面料服用性能的影响[J]. 纺织学报, 2014, 35(3): 27-0.
[13]	钱红飞钱军施舒雯. 蚕丝和棉及锦纶织物对儿茶素的选择性吸附和媒染效应[J]. 纺织学报, 2014, 35(1): 82-0.
[14]	于高杰吴菲非左华丽陈雁. 磁性针织物表面磁性测试与评价[J]. 纺织学报, 2014, 35(1): 57-0.
[15]	张炜栋黄旭. 丙烯酸接枝改性对锦纶66染色性能的影响[J]. 纺织学报, 2013, 34(7): 85-89.

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工艺编号	织物编号	组织结构	纱线配置	纱线根数	机器型号
F-1	1^#		100%的纤维MPA-0
	2^#	平针组织	100%的纤维MPA-15	1	SM8-TOP2 MP2
	3^#		100%的纤维MPA-20
	4^#		100%的纤维MPA-25
F-2	5^#		50%的纤维MPA-0+50%的氨纶包芯纱
	6^#	添纱组织	50%的纤维MPA-15+50%的氨纶包芯纱	1	SM8-TOP2 MP2
	7^#		50%的纤维MPA-20+50%的氨纶包芯纱
	8^#		50%的纤维MPA-25+50%的氨纶包芯纱
F-3	9^#		100%的纤维MPA-0
	10^#	平针组织	100%的纤维MPA-15	4	台车
	11^#		100%的纤维MPA-20
	12^#		100%的纤维MPA-25

试样	熔点/℃	热焓/(J·g^-1)	结晶度/%
MPA-0	206.63	60.14	26.15
MPA-15	207.24	52.98	23.03
MPA-20	206.82	49.51	21.53
MPA-25	206.63	47.09	20.47

试样	断裂强度/ (cN·dtex^-1)	强度保持率/%	断裂伸长率/%	断裂伸长率保持率/%
MPA-0	3.64	100.00	77.01	100.00
MPA-15	3.16	86.81	63.82	82.87
MPA-20	2.93	80.49	61.80	80.25
MPA-25	2.50	68.68	59.01	76.62

织物编号
F-1	15	0.050	—
	20	0.055	10.10
	25	0.059	18.96
F-2	15	0.028	—
	20	0.034	22.17
	25	0.041	46.72
F-3	15	0.051	—
	20	0.059	16.46
	25	0.093	83.52

锦纶基磁性纤维的制备及其性能

Preparation and properties of polyamide-based magnetic fibers

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