纺织学报 ›› 2019, Vol. 40 ›› Issue (12): 63-67.doi: 10.13475/j.fzxb.20180801605

• 染整与化学品 • 上一篇    下一篇

拼混型黑色分散染料的配伍性及其染色性能

刘越1,2(), 莫林祥3, 陈丰3   

  1. 1.绍兴文理学院 纺织服装学院, 浙江 绍兴 312000
    2.浙江省清洁染整技术研究 重点实验室, 浙江 绍兴 312000
    3.浙江红绿蓝纺织印染有限公司, 浙江 绍兴 312030
  • 收稿日期:2018-08-06 修回日期:2019-08-22 出版日期:2019-12-15 发布日期:2019-12-18
  • 作者简介:刘越(1965—),男,教授,博士。研究方向为清洁染色技术及新型纺织材料染整技术。E-mail:liuyue846@163.com

Compatibility and dyeing properties of blending black disperse dyes

LIU Yue1,2(), MO Linxiang3, CHEN Feng3   

  1. 1. College of Textile and Garment, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
    3. Zhejiang R.G.B. Textile Printing & Dyeing Co., Ltd., Shaoxing, Zhejiang 312030, China
  • Received:2018-08-06 Revised:2019-08-22 Online:2019-12-15 Published:2019-12-18

摘要:

针对涤纶纺织品染色用黑色分散染料拼混各组分配伍性能差,染料提升力低等问题,对筛选的1组中温型拼色分散染料组分的配伍性能及其染色性能进行实验,并对染色样品进行剥色处理以及色牢度测试。结果表明:采用中温型单偶氮类分散染料分散紫SE-E、分散橙SE-G以及分散蓝SE-F进行黑色分散染料拼混,三者拼混比例为0.50∶1.85∶0.65时,可获得比商品液黑分散染料更低的明度值和优良的提升力,实现涤纶纺织品深黑色染色效果;染色样品上各染料组分浓度比值与拼混比例基本吻合,表明拼混黑色分散染料组分间具有良好的配伍性能和染色性能。

关键词: 黑色分散染料, 拼混染色, 配伍性, 染色性能

Abstract:

Aiming at poor compatibility and low dye lifting power of black disperse dyes for polyester textile dyeing, a set of medium temperature color-dispersed dye components were selected. The compatibility and dyeing properties were tested in dyeing. The results show that the medium temperature type monoazo disperse dyes of Disperse Purple SE-E, Disperse Orange SE-G and Disperse Blue SE-F were mixed for black disperse dyes, at a blending ratio of 0.50∶1.85∶0.65. The liquid black disperse dye has a lower brightness value and an excellent lifting force, realizing deep black dyeing effect of the polyester textile. In addition, the stripping and color fastness test data of the dyed samples shows that the concentration ratio of each dye component on the dyed sample is substantially consistents with the blending ratio, indicating that the blended black disperse dye components have good compatibility and dyeing properties.

Key words: black disperse dye, blending dyeing, compatibility, dyeing property

中图分类号: 

  • TS193.2

图1

色三角拼混实验方案"

表1

第1次拼混染样测色数据"

染色样编号 L* a* b* C K/S
1# 16.76 9.98 -17.43 20.08 25.09
2# 15.95 5.26 -7.36 9.05 25.85
3# 16.08 7.72 -16.06 17.82 26.35
4# 15.50 4.05 -3.06 5.08 26.37
5# 16.03 3.31 -7.45 8.15 25.13
6# 16.40 6.76 -15.96 17.34 25.74
7# 16.37 4.41 -1.04 4.53 24.45
8# 15.17 1.76 -3.44 3.87 26.77
9# 15.06 2.21 -6.80 7.15 27.62
10# 16.21 5.33 -14.47 15.42 26.08
11# 17.28 6.12 1.54 6.31 23.331
12# 15.40 1.02 -1.34 1.69 25.96
13# 15.66 0.63 -3.43 3.49 25.70
14# 15.82 1.46 -6.68 6.84 25.88
15# 15.94 4.42 -14.16 14.84 27.52
16# 18.75 10.52 5.89 12.06 25.74
17# 17.20 0.99 1.07 1.47 22.79
18# 16.13 -0.24 -1.28 1.30 24.51
19# 15.95 -0.11 -3.21 3.22 25.38
20# 16.21 0.43 -6.62 6.63 25.75
21# 16.74 3.10 -14.91 15.23 26.95
22# 39.78 40.74 42.24 58.69 25.56
23# 19.86 1.61 6.47 6.67 23.54
24# 17.46 -1.43 1.44 2.04 22.87
25# 16.50 -1.47 -0.84 1.70 24.76
26# 16.63 -1.52 -2.51 2.94 24.76
27# 17.14 -1.63 -6.08 6.30 25.29
28# 18.52 -0.09 -16.65 16.65 26.13

表2

3种染料在其最大波长下的吸收标准曲线及其相应线性数据"

染料名称 测试波长/nm 线性关系 复相关系数R2
分散蓝SE-F 597 Y=37.575x 0.999 8
466 Y=6.608 9x 0.999 4
565 Y=32.800x 0.999 6
分散橙SE-G 466 Y=35.786x 0.999 0
565 Y=2.860 6x 0.999 2
597 Y=0.636 8x 0.999 4
分散紫SE-E 466 Y=8.916 8x 0.999 8
597 Y=32.108x 0.999 1
565 Y=41.218x 0.999 3

表3

实验拼混黑色分散染料的染色提升力"

染料用量/
%(o.w.f)
拼混实验染料配方 商品液黑
L* K/S L* K/S
0.125 50.17 2.476
0.250 40.79 4.642
0.500 32.43 8.177
1.000 23.72 15.15 29.82 13.78
2.000 17.40 22.59 21.61 17.09
3.000 15.54 25.44 19.01 18.49
4.000 15.18 25.94 17.43 22.91
5.000 15.10 25.93 16.84 23.35
6.000 14.70 25.94 16.42 23.71
7.000 14.74 26.63 16.35 23.99
8.000 14.62 26.90 16.12 24.04
9.000 16.06 24.20
10.000 15.91 24.55

表4

不同黑色分散染料染色样品颜色数据"

染色样品 L* a* b* C
企业染样 14.80 0.17 -0.18 0.25
实验染样 13.77 0.22 -0.16 0.28

表5

实验黑色分散染料染样色牢度数据"

类别 耐水色牢度 耐酸汗渍色
牢度
耐碱汗渍色
牢度
耐摩擦
色牢度
变色 沾色 变色 沾色 变色 沾色
技术要求 ≥3 ≥3 ≥3 ≥3 ≥3 ≥3 ≥3
检测结果 4 3~4 4 3~4 4 3~4 4
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