生物基聚酯与聚酰胺纤维的研发进展

doi:10.13475/j.fzxb.20190801610

纺织学报 ›› 2020, Vol. 41 ›› Issue (01): 174-183.doi: 10.13475/j.fzxb.20190801610

生物基聚酯与聚酰胺纤维的研发进展

董奎勇¹^,², 杨婷婷¹^,³, 王学利³, 何勇³(), 俞建勇³

1.东华大学材料科学与工程学院, 上海 201620
2.中国纺织信息中心, 北京 100020
3.东华大学纺织科技创新中心, 上海 201620

收稿日期:2019-08-07 修回日期:2019-10-28 出版日期:2020-01-15 发布日期:2020-01-14
通讯作者: 何勇
作者简介:董奎勇(1975—),男,教授级高级工程师,博士生。主要研究方向为新型纤维材料制备及表征技术。
基金资助:
国家重点研发计划资助项目(2017YFB0309400)

Research and development progress of bio-based polyester and polyamide fibers

DONG Kuiyong¹^,², YANG Tingting¹^,³, WANG Xueli³, HE Yong³(), YU Jianyong³

1. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
2. China Textile Information Center, Beijing 100020, China
3. Innovation Center for Textile Science and Technology,Donghua University, Shanghai 201620, China

Received:2019-08-07 Revised:2019-10-28 Online:2020-01-15 Published:2020-01-14
Contact: HE Yong

摘要/Abstract

摘要：

为促进我国化纤行业转型升级与持续发展,对以生物基聚对苯二甲酸乙二醇酯纤维、聚对苯二甲酸-1,3-丙二醇酯纤维、聚乳酸纤维、聚呋喃二甲酸乙二醇酯纤维、聚呋喃二甲酸丙二醇酯纤维,以及生物基聚酰胺56纤维为代表的生物基聚酯、聚酰胺纤维的国内外生产现状,市场需求、技术发展及趋势进行了综述,对全球生物基纤维专利的分布、各主要开发机构的专利战略及技术情况进行了梳理及剖析。在此基础上结合国内高分子材料产业实际,对我国生物基聚酯、聚酰胺纤维的发展建言应重点攻关生物基乙二醇、对苯二甲酸、己二胺等战略性生物基单体制备的核心技术,同时就重点任务和发展路径提出了建议。

关键词: 生物基纤维, 聚酯纤维, 聚酰胺纤维, 聚酰胺56纤维, 生物基单体

Abstract:

To promote the transformation, upgrading and sustainable development of China's chemical fiber industry, this paper reviewed the global market, technology development and trend of bio-based polyester and polyamide fibers with bio-based polyethylene terephthalate, polytrimethylene terephthalate, polylactic acid, poly(ethylene furandicarboxylate), poly(propylene furandicaboxylate), polyamide 56 fibers as representatives, summarized and analyzed the global patent distribution of bio-based fibers, the patent strategy and technology of the major organizations in the world. Based on this and the actual situation of domestic industry of polymer materials, the key item was suggested to break through the core technology in preparation of strategic bio-based monomers such as ethylene glycol, terephthalic acid and 1,6-hexanediamine. At the same time, some advices were put forward on the major tasks and development path for research and development of bio-based polyester and polyamide fibers in China.

Key words: bio-based fiber, polyester fiber, polyamide fiber, polyamide 56 fiber, bio-based monomer

中图分类号:

TB332

董奎勇, 杨婷婷, 王学利, 何勇, 俞建勇. 生物基聚酯与聚酰胺纤维的研发进展[J]. 纺织学报, 2020, 41(01): 174-183.

DONG Kuiyong, YANG Tingting, WANG Xueli, HE Yong, YU Jianyong. Research and development progress of bio-based polyester and polyamide fibers[J]. Journal of Textile Research, 2020, 41(01): 174-183.

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机构名称	PEF专利数量	机构名称	PEF专利数量
Furanix	31	花王	5
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机构名称	PTF专利数量	机构名称	PTF专利数量
杜邦	10	Aurign	4
佳能	5	长春应化所	1
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ADM	2	三菱	1
江南大学	2	东丽	1

生物基聚酯与聚酰胺纤维的研发进展

Research and development progress of bio-based polyester and polyamide fibers

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年份	PLA	PET	PTT	PEF	PA
2011	18	50	9	0	6
2012	19	60	9	0	6
2013	19	64	11	0	8
2014	20	65	12	0	10
2015	20	64	12	0	12
2016	21	64	15	0	16
2017	21	55	16	1	25
2018	21	55	16	2	25
2019	23	53	17	2	26
2020	24	51	16	4	26
2021	24	51	16	5	27
2022	33	50	17	7	27

机构名称	专利数量	机构名称	专利数量
凯赛	42	军需所/恒星	9
东丽	36	中石化	6
东华大学	20	广东威林	4
三菱	16	罗地亚	4

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