棉纱线在活性染料皮克林乳液体系中的染色动力学

doi:10.13475/j.fzxb.20190600208

纺织学报 ›› 2020, Vol. 41 ›› Issue (07): 101-108.doi: 10.13475/j.fzxb.20190600208

棉纱线在活性染料皮克林乳液体系中的染色动力学

丁永生¹^,², 代亚敏¹^,², 钟毅¹^,²(), 徐红³, 毛志平¹^,⁴, 张琳萍¹^,², 陈支泽¹^,²

1.东华大学生态纺织教育部重点实验室, 上海 201620
2.东华大学化学化工与生物工程学院, 上海 201620
3.鲁泰纺织股份有限公司, 山东淄博 255000
4.东华大学纺织科技创新中心, 上海 201620

收稿日期:2019-06-03 修回日期:2020-01-15 出版日期:2020-07-15 发布日期:2020-07-24
通讯作者: 钟毅
作者简介:丁永生(1994—),男,硕士生。主要研究方向为活性染料清洁印染新技术。
基金资助:
泰山产业领军人才工程专项(tscy20170208)

Dyeing kinetics of reactive dye on cotton yarn in Pickering emulsion system

DING Yongsheng¹^,², DAI Yamin¹^,², ZHONG Yi¹^,²(), XU Hong³, MAO Zhiping¹^,⁴, ZHANG Linping¹^,², CHEN Zhize¹^,²

1. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
2. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
3. Lutai Textile Co., Ltd., Zibo, Shandong 255000, China
4. Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China

Received:2019-06-03 Revised:2020-01-15 Online:2020-07-15 Published:2020-07-24
Contact: ZHONG Yi

摘要/Abstract

摘要：

为探究SiO₂乳液(皮克林乳液)体系中活性染料在棉纱线上的染色机制,选用活性红M-3BF对棉染色动力学进行研究。首先对该染料在皮克林乳液和传统水浴体系中的染色性能进行对比,然后分别利用准一级和准二级动力学模型对该染料在皮克林乳液体系中上染棉纱线的数据进行拟合,计算各项动力学参数,并与传统水浴体系做对比。结果表明:在相同染料用量条件下,活性红M-3BF在皮克林乳液体系中的染料利用率高于传统水浴体系,耐皂洗色牢度相当;且2种体系中活性红M-3BF在棉纤维的上染都符合准二级动力学吸附模型方程,染料在皮克林乳液体系中的平衡吸附量高于传统水浴体系,吸附活化能小,半染时间缩短;硫酸钠能够提高平衡吸附量,加快上染速率。

关键词: 活性染料, 皮克林乳液体系, 棉纱线, 染色, SiO₂乳液

Abstract:

In order to explore the dyeing mechanism of reactive dye on cotton yarn in SiO₂ emulsion (Pickering emulsion)system, Reactive Red M-3BF was used to explore the kinetics for cotton dyeing. The dyeing performance of the dye in Pickering emulsion system and the traditional aqueous system were compared, before the data of cotton yarn dyed in Pickering emulsion system was fitted, and the kinetic parameters were calculated and compared with the traditional aqueous system. The results show that the dye utilization of Reactive Red M-3BF in the Pickering emulsion system are higher than that in the traditional aqueous bath dyeing system and the washing fastness is equivalent under the same dye dosages, and the dyeing of reactive Red M-3BF on cotton fibers in both systems conforms to the quasi-second-order kinetic adsorption model equation. The equilibrium adsorption capacity of dye in Pickering emulsion system is higher than that of traditional aqueous system, and the adsorption activation energy is smaller, the half-dyeing time is shortened. Sodium sulfate can increase the equilibrium adsorption capacity and speed up the dyeing rate.

Key words: reactive dye, Pickering emulsion system, cotton yarn, dyeing, silica emulsion

中图分类号:

TS193.5

丁永生, 代亚敏, 钟毅, 徐红, 毛志平, 张琳萍, 陈支泽. 棉纱线在活性染料皮克林乳液体系中的染色动力学[J]. 纺织学报, 2020, 41(07): 101-108.

DING Yongsheng, DAI Yamin, ZHONG Yi, XU Hong, MAO Zhiping, ZHANG Linping, CHEN Zhize. Dyeing kinetics of reactive dye on cotton yarn in Pickering emulsion system[J]. Journal of Textile Research, 2020, 41(07): 101-108.

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染色体系	温度/℃	R²
皮克林乳液体系	40	0.865 16
	60	0.604 27
	80	0.671 02
传统水浴体系	40	0.953 10
	60	0.898 17
	80	0.971 79

染色体系	温度/ ℃	q_e,exp/ (mg·g^-1)	准二级动力学参数
染色体系	温度/ ℃	q_e,exp/ (mg·g^-1)	k₂/ (g·mg^-1·min^-1)	q_e,cal/ (mg·g^-1)	R²
皮克林乳液体系	40	17.99	0.115	18.14	0.999 94
	60	17.90	0.164	18.01	0.999 97
	80	17.76	0.243	17.83	0.999 98
传统水浴体系	40	13.05	0.043	13.39	0.999 63
	60	12.10	0.071	12.38	0.999 64
	80	10.44	0.147	10.58	0.999 91

染色体系	温度/℃	半染时间t_1/2/min
皮克林体系乳液	40	0.48
	60	0.34
	80	0.23
传统水浴体系	40	1.78
	60	1.16
	80	0.65

染色体系	Na₂SO₄ 质量浓度	R²	q_e,exp	k₂	q_e,cal	t_1/2
皮克林乳液体系	40	1.000 00	19.23	0.260	19.29	0.20
	60	0.999 99	19.36	0.289	19.41	0.18
	80	0.999 99	19.57	0.409	19.60	0.12
传统水浴体系	40	0.999 51	9.80	0.068	13.39	1.50
	60	0.999 64	12.10	0.071	12.38	1.16
	80	0.999 88	13.37	0.076	10.58	0.98

染色体系	温度/℃	D×10¹⁶/(m²·s^-1)
皮克林乳液体系	40	3.475
	60	4.782
	80	6.419
传统水浴体系	40	2.546
	60	4.081
	80	5.775

棉纱线在活性染料皮克林乳液体系中的染色动力学

Dyeing kinetics of reactive dye on cotton yarn in Pickering emulsion system

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