植酸作用下锆离子修饰羽绒及其保温性能

doi:10.13475/j.fzxb.20200101907

纺织学报 ›› 2020, Vol. 41 ›› Issue (10): 94-100.doi: 10.13475/j.fzxb.20200101907

植酸作用下锆离子修饰羽绒及其保温性能

应丽丽¹, 李长龙¹, 王宗乾¹(), 王邓峰¹, 吴开明², 谢伟², 程欢¹

1.安徽工程大学纺织服装学院, 安徽芜湖 241000
2.安徽古麒绒材股份有限公司, 安徽芜湖 241008

收稿日期:2020-01-14 修回日期:2020-07-09 出版日期:2020-10-15 发布日期:2020-10-27
通讯作者: 王宗乾
作者简介:应丽丽(1996—),女,硕士生。主要研究方向为功能纺织品。
基金资助:
安徽省重点研究与开发计划项目(1804a09020077);安徽省重点研究与开发计划项目(202004a06020055);安徽省重大科技专项(201903a05020028);芜湖市科技计划项目(2020yf51);安徽省高校学科(专业)中青年拔尖人才学术资助项目(gxbjZD2020075)

Modification of down by zirconium ion with phytic acid and its thermal insulation performance

YING Lili¹, LI Changlong¹, WANG Zongqian¹(), WANG Dengfeng¹, WU Kaiming², XIE Wei², CHENG Huan¹

1. School of Textile and Garment, Anhui Polytechnic University, Wuhu, Anhui 241000, China
2. Anhui Guqi Down Material Incorporated Company, Wuhu, Anhui 241008, China

Received:2020-01-14 Revised:2020-07-09 Online:2020-10-15 Published:2020-10-27
Contact: WANG Zongqian

摘要/Abstract

摘要：

锆离子修饰可提升羽绒的保温性能,为进一步提高锆离子负载量和坚牢度,缩短工艺流程,采用植酸对羽绒进行预处理后,将其浸渍于硫酸锆溶液中,经螯合吸附制得锆离子修饰功能羽绒,借助扫描电子显微镜、X射线衍射光谱仪、电感耦合等离子光谱仪、红外光谱仪等对修饰羽绒的结构进行表征,远红外辐射发热仪、平板保温仪对修饰前后羽绒的红外温升及保温性能进行测试。结果表明:经植酸预处理的锆离子修饰工艺不损伤羽绒原有的绒小枝及夹角特征形貌,修饰羽绒的蓬松度、清洁度、残脂率指标满足羽绒标准要求;植酸预处理显著提升了羽绒对锆离子的吸附量,修饰羽绒的红外温升和保温系数分别提高40%和8.1%;锆离子、植酸与羽绒纤维之间主要以共价螯合方式结合,具有良好的水洗牢度,经9次水洗锆离子仍维持较高负载量。

关键词: 羽绒, 植酸, 锆离子, 保温性能, 保温机制

Abstract:

Zirconium ion (Zr⁴⁺) modification can improve the thermal insulation of down. For further improving the Zr⁴⁺ load to shorten the modification process, the Zr⁴⁺modified functional down was prepared through phytic acid pretreatment and direct impregnation with zirconium sulfate solution based on chelating adsorption. The modified down was characterized by scanning electron microscope, X-ray diffraction spectrometer, inductively coupled plasma spectrometer and infrared spectroscopy and so on. Meanwhile, far-infrared radiation calorimeter and flat insulation meter were used to test the infrared temperature rise and thermal insulation performance of down before and after modification. The results show that the original feather twigs and the angles are not damaged by the Zr⁴⁺ modification with the pretreatment of phytic acid, while the fluffy, cleanliness and residual fat ratio of modified down are found to meet the requirements of the down standard. The adsorption capacity to Zr⁴⁺of the treated down is significantly enhanced, and the infrared temperature rise and heat preservation coefficient of the modified down are increased by 40% and 8.1%, respectively. The Zr⁴⁺, phytic acid and down fibers are mainly combined by covalent chelation, which has excellent washing fastness, and the load of Zr⁴⁺ on down fibers maintains a high level after 9 times of washing.

Key words: down, phytic acid, zirconium ion, thermal insulation performance, thermal insulation mechanism

中图分类号:

TS959.16

应丽丽, 李长龙, 王宗乾, 王邓峰, 吴开明, 谢伟, 程欢. 植酸作用下锆离子修饰羽绒及其保温性能[J]. 纺织学报, 2020, 41(10): 94-100.

YING Lili, LI Changlong, WANG Zongqian, WANG Dengfeng, WU Kaiming, XIE Wei, CHENG Huan. Modification of down by zirconium ion with phytic acid and its thermal insulation performance[J]. Journal of Textile Research, 2020, 41(10): 94-100.

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试样名称	C	N	O	P	Zr
羽绒原样	42.45	36.88	20.66
Zr⁴⁺修饰羽绒	45.84	21.65	19.03	5.21	8.27

样品名称	残液Zr⁴⁺浓度/ (mg·L^-1)	Zr⁴⁺吸附量/ (mg·g^-1)	相对标准偏差
羽绒原样	36.50	4.50	0.81
预处理羽绒	2.04	16.0	1.94

样品名称	保暖率/%	克罗值
羽绒原样	73.8	2.251
Zr⁴⁺修饰羽绒	81.9	2.936

类型	蓬松度/cm	耗氧量/ (mg·(100 g)^-1)	清洁度/mm	残脂率/%	外观	气味
羽绒原样	18.6	5.5	950	0.95	白色	无
Zr⁴⁺修饰羽绒	18.2	5.6	950	0.90	轻微色	无
国标要求	≥16.5	≤5.6	≥500	≤1.2	—	无

植酸作用下锆离子修饰羽绒及其保温性能

Modification of down by zirconium ion with phytic acid and its thermal insulation performance

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