纺织学报 ›› 2021, Vol. 42 ›› Issue (04): 26-32.doi: 10.13475/j.fzxb.20200904907
摘要:
针对我国目前高度依赖进口石油和聚酰胺66主要原料己二胺被国外公司垄断的局面,顺应我国早日实现碳中和的战略目标,在简要回顾生物基聚酰胺发展历程的基础上,对生物基聚酰胺56纤维的特性作了详细描述,对其制备技术与应用领域的研究进展进行了综述。生物基聚酰胺56纤维具有良好的力学性能、吸湿性、柔软性、耐磨性、染色性、耐热性、耐化学性与阻燃性,适合应用于服装、家纺、产业用纺织品等领域,但生物基聚酰胺56纤维大规模推广还面临生物原料供给与成本控制、生产中能耗降低及副产物综合利用等问题,今后需要继续在生物基单体发酵与纯化、聚合、纺丝及应用等领域加大研发投入,不断降低生产成本,才能促进生物基聚酰胺56纤维在纺织领域的大规模应用。
中图分类号:
[1] | GENAS M. Rilsan (polyamid 11), synthese und eigenschaften[J]. Angewandte Chemie, 1962,74(15):535-540. |
[2] | Arkema. Rilsan® PA11:created from a renewable source(product data sheet)[M]. Puteeaux:Arkema, 2009: 61-62. |
[3] |
KIND S, KREYE S, WITTMANN C. Metabolic engineering of cellular transport for overproduction of the platform chemical 1,5-diaminopentane in corynebacte-rium glutamicum[J]. Metab Eng, 2001,13:617-627.
pmid: 21821142 |
[4] | 董奎勇, 杨婷婷, 王学利, 等. 生物基聚酯与聚酰胺纤维的研发进展[J]. 纺织学报, 2020,41(1):174-183. |
DONG Kuiyong, YANG Tingting, WANG Xueli, et al. Research and development of bio-based polyester and polyamide fibers[J]. Journal of Textile Research, 2020,41(1):174-183. | |
[5] | 刘博. 国产尼龙56长丝一步法纺牵联合机的探究[J]. 价值工程, 2016,35(27):107-110,111. |
LIU Bo. Research on one-step spinning and drawing combined machine of domestic nylon 56 filament[J]. Value Engineering, 2016,35(27):107-110,111. | |
[6] | 徐凯. 国产聚酰胺56工业丝纺牵联合机的探究[J]. 价值工程, 2019,38(24):122-125. |
XU Kai. Exploration of industrial silk spinning joint machine for domestic polyamide 56[J]. Value Engineering, 2019,38(24):122-125. | |
[7] | 于维才. 尼龙56的物理性能及可纺性探析[J]. 聚酯工业, 2014,27(1):38-39. |
YU Weicai. Analysis of the physical properties and spinnability of nylon 56[J]. Polyester Industry, 2014,27(1):38-39. | |
[8] | 张晨. 生物基聚己二酸戊二胺聚合物与长丝性能研究[D]. 上海:东华大学, 2015: 4-6. |
ZHANG Chen. Study on properties of bio-based polypentamethylene adipate polymer and filament[D]. Shanghai: Donghua University, 2015: 4-6. | |
[9] | 吴田田. 生物基尼龙 56 的结晶、动态热力学及流变性能研究[D]. 上海:东华大学, 2017: 3-6. |
WU Tiantian. Study on the crystallization, dynamic thermodynamics and rheological properties of bio-based nylon 56[D]. Shanghai:Donghua University, 2017: 3-6. | |
[10] | 郝新敏, 郭亚飞. 生物基聚酰胺纤维引领产业绿色发展[J]. 纺织科学研究, 2020(2):74-75. |
HAO Xinmin, GUO Yafei. Bio-based polyamide fiber leads the green development of the industry[J]. Textile Science Research, 2020(2):74-75. | |
[11] | 江苏太极实业新材料有限公司, 上海凯赛生物技术股份有限公司. 聚酰胺56高强力工业丝及其制备方法: 201910430213.0[P]. 2019-07-26. |
Jiangsu Taiji Industrial New Materials Co Ltd, Cathay Biotech Inc. High-strength industrial yarn for polyamide 56 and preparation method thereof: 201910430213.0[P]. 2019-07-26. | |
[12] | 东丽株式会社. 吸湿性纤维及其织造方法:201180016429.4[P]. 2012-12-19. |
Toray Industries. Hygroscopic fiber and its weaving method: 201180016429.4[P]. 2012-12-19. | |
[13] | YASSIR Abdel Gadir Rltahir Hashim. 新型尼龙56纤维的制备和表征[D]. 上海:东华大学, 2015: 2-30. |
YASSIR Abdel Gadir Rltahir Hashim. Preparation and characterization of new nylon fibers[D]. Shanghai: Donghua University, 2015: 2-30. | |
[14] | 优纤科技(丹东)有限公司,中国人民解放军总后勤部军需装备研究所,辽宁恒星精细化工有限公司. 一种锦纶56纤维的染色方法:201610428217.1 [P]. 2016-08-24. |
Youxian Technology (Dandong) Co Ltd, The Quartermaster Equipment Research Institute The General Logistic Department of PLA, Liaoning Fixed Star Fine Chemical Co Ltd. A dyeing method of nylon 56 fiber: 201610428217.1 [P]. 2016-08-24. | |
[15] | 李蒙蒙, 胡柳, 侯爱芹, 等. 生物基纤维尼龙PA56染色性能及产品开发研究进展[J]. 染料与染色, 2016(5):25-30. |
LI Mengmeng, HU Liu, HOU Aiqin, et al. Research progress on dyeing performance and product development of bio-based fiber nylon polyamide 56[J]. Dyestuffs and Coloration, 2016(5):25-30. | |
[16] | 马雪松, 高艺, 陈英, 等. 生物基尼龙PA56的活性染料染色性能[J]. 印染, 2019,45(18):9-13,29. |
MA Xuesong, GAO Yi, CHEN Ying, et al. Dyeing performance of bio-based nylon 56 with reactive dyes[J]. China Dyeing & Finishing, 2019,45(18):9-13,29. | |
[17] | 上海凯赛生物技术股份有限公司, CIBT 美国公司. 一种聚酰胺56纤维或聚酰胺56/棉混纺面料的靛蓝染色方法及其产品: 201710888976.0[P]. 2017-09-27. |
Cathay Biotech Inc, CIBT America Inc. Indigo dyeing method of polyamide 56 fiber or polyamide 56/cotton blended fabric and product thereof: 201710888976.0[P]. 2017-09-27. | |
[18] | 胡翱翔, 史晓军. 聚酰胺56 POY纤维的开发[J]. 纺织导报, 2019 (8):47-48. |
HU Aoxiang, SHI Xiaojun. Development of Polyamide 56 for POY Fiber[J]. China Textile Leader, 2019(8):47-48. | |
[19] | 于海龙. 锦纶56 DTY高弹丝的POY-DTY生产方法: 201410211175.7[P]. 2014-08-06. |
YU Hailong. POY-DTY production method of DTY high elastic yarn for nylon 56: 201410211175.7[P]. 2014-08-06. | |
[20] | 展颂股份有限公司. 消光聚酰胺56纤维及其制造方法: 201510087957.9[P]. 2018-08-03. |
Zhantong Inc. Dull fiber for polyamide 56 and its manufacturing method: 201510087957.9[P]. 2018-08-03. | |
[21] | 张俊辉, 丛洪莲. 生物基聚酰胺56长丝及面料性能研究[J]. 丝绸, 2018,55(12):25-31. |
ZHANG Junhui, CONG Honglian. Study on properties of filament and fabric for bio-based polyamide 56[J]. Journal of Silk, 2018,55(12):25-31. | |
[22] | 宁波福天新材料科技有限公司. 一种尼龙纤维及其制备方法以及一种纺织材料:201511026024.5[P]. 2017-07-07. |
Ningbo Futian New Materials Technology Co Ltd. A nylon fiber and its preparation method and a textile material: 201511026024.5[P]. 2017-07-07. | |
[23] | 东丽株式会社. 聚酰胺56纤维、橡胶增强帘子线和增强橡胶:2007236649[P]. 2011-12-07. |
Toray Industries. Polyamide 56 fiber, rubber reinforced cord and reinforced rubber: 2007236649[P]. 2011-12-07. | |
[24] | 东丽株式会社. 聚酰胺56细丝、含有它们的纤维结构、以及用气囊织物:200980118941.2 [P]. 2013-09-25. |
Toray Industries. Polyamide 56 filaments, fiber structures containing them, airbag fabrics: 200980118941.2[P]. 2013-09-25. | |
[25] | 上海凯赛生物技术股份有限公司, CIBT美国公司, 凯赛(乌苏)生物材料有限公司. 一种高粘聚酰胺56树脂、高强聚酰胺56工业丝及其制备方法与应用: 202010245867.9 [P]. 2020-07-07. |
Cayhay Biotech Inc, CIBT America Inc, Cathay(Wusu) Biomaterial Co Ltd. High-viscosity polyamide 56 resin, high-strength polyamide 56 industrial yarn and these preparation method and application: 202010245867.9 [P]. 2020-07-07. | |
[26] | 威海市山花地毯集团有限公司. 生物基尼龙56地毯膨体纱的生产方法: 201410415413.6 [P]. 2016-09-21. |
Weihai Mountain Flower Carpet Group Co Ltd. Production method of carpet bulked yarn for bio-based polyamide 56: 201410415413.6[P]. 2016-09-21. | |
[27] | 上海凯赛生物技术股份有限公司, CIBT美国公司. 一种阻燃柔软蓬松聚酰胺5X连续膨体长丝及其制备方法和应用:201710102959.X [P]. 2020-06-05. |
Cayhay Biotech Inc, CIBT America Inc. A flame-retardant, soft, fluffy, continuous bulked filament for polyamide 5X and its preparation method and application: 201710102959.X [P]. 2020-06-05. | |
[28] | 优纤科技(丹东)有限公司, 中国人民解放军总后勤部军需装备研究所, 辽宁恒星精细化工有限公司. 一种聚酰胺56短纤及其熔体直纺制备方法: 201610438659.4 [P]. 2016-08-24. |
Youxian Technology (Dandong) Co Ltd, The Quartermaster Equipment Research Institute The General Logisitic Department of PLA, Liaoning Fixed Star Fine Chemical Co Ltd. A method for preparing polyamide 56 staple fiber and its melt direct spinning: 201610438659.4 [P]. 2016-08-24. | |
[29] | 上海凯赛生物技术股份有限公司, CIBT美国公司. 一种聚酰胺5X短纤及其制备方法和应用:201710105921.8 [P]. 2019-07-26. |
Cayhay Biotech Inc, CIBT America Inc. Polyamide 5X staple fiber and its preparation method and application: 201710105921.8 [P]. 2019-07-26. | |
[30] | 上海凯赛生物技术股份有限公司, CIBT美国公司. 一种聚酰胺56割草丝及其制备方法:201710376174.1 [P]. 2018-12-07. |
Cayhay Biotech Inc, CIBT America Inc. Polyamide 56 mowing wire and preparation method: 201710376174.1[P]. 2018-12-07. | |
[31] | 凯赛(乌苏)生物材料有限公司, 上海凯赛生物技术股份有限公司, CIBT美国公司. 一种聚酰胺单丝及其制备方法和应用:201811085458.6 [P]. 2020-03-24. |
Cathay(Wusu) Biomaterial Co Ltd, Cayhay Biotech Inc, CIBT America Inc. Polyamide monofilament and its preparation method and application: 201811085458.6[P]. 2020-03-24. | |
[32] | 张若楠. 聚酰胺56/PET 复合纤维制备及性能研究[D]. 上海:东华大学, 2017: 15-30. |
ZHANG Ruonan. Study on preparation and performance of polyamide 56/PET composite fiber[D]. Shanghai: Donghua University, 2017: 15-30. | |
[33] | 赵辉. 新型生物基尼龙56异收缩混纤丝的制备及其产品性能研究[D]. 上海:东华大学, 2015: 3-8. |
ZHAO Hui. Study on the preparation and performance of differential shrinkage blended fiber for new bio-based nylon 56[D]. Shanghai: Donghua University, 2015: 3-8. | |
[34] | 王学利, 俞建勇, 刘修才, 等. 生物质尼龙56纤维/PBT纤维的FDY/POY异收缩混纤丝及其制备方法: 201610227057.4[P]. 2016-04-13. |
WANG Xueli, YU Jianyong, LIU Xiucai, et al. FDY / POY differential shrinkage blended fiber of biomass nylon 56 fiber/PBT fiber and its preparation method:201610227057.4 [P]. 2016-04-13. | |
[35] | 辽宁银珠化纺集团有限公司. 一种具有阻燃性能的聚酰胺56的制备方法和聚酰胺56纤维: 201610782169.6 [P]. 2017-02-22. |
Liaoning Yinzhu Chemtex Group Co Ltd. Preparation method of polyamide 56 with flame retardant properties and polyamide 56 fiber: 201610782169.6 [P]. 2017-02-22. | |
[36] | 张瀚誉, 钱思琦, 朱瑞淑, 等. 抗菌生物基聚酰胺56及纤维的制备与性能研究[J]. 合成纤维, 2020,49(12):1-7. |
ZHANG Hanyu, QIAN Siqi, ZHU Ruishu, et al. Preparation and study on properties of antimicrobial bio-based polyamide 56 and its fibers[J]. Synthetic Fiber in China, 2020,49(12):1-7. |
[1] | 杨婷婷, 高远博, 郑毅, 王学利, 何勇. 生物基聚酰胺56纤维的热降解动力学及其热解产物[J]. 纺织学报, 2021, 42(04): 1-7. |
[2] | 邢宇声, 胡毅, 程钟灵. Si/TiO2复合碳纳米纤维的制备及其性能[J]. 纺织学报, 2021, 42(03): 36-43. |
[3] | 董奎勇, 杨婷婷, 王学利, 何勇, 俞建勇. 生物基聚酯与聚酰胺纤维的研发进展[J]. 纺织学报, 2020, 41(01): 174-183. |
[4] | 吴娇, 于湖生, 万兴云, 田平, 李慧敏, 侯晓欣. 抗菌防螨防霉功能改性粘胶纤维的制备及其性能[J]. 纺织学报, 2019, 40(07): 19-23. |
[5] | 秦益民. 壳聚糖纤维的理化性能和生物活性研究进展[J]. 纺织学报, 2019, 40(05): 170-176. |
[6] | 崔婷婷 刘吉东 解安全 程恒洋 杜湘云 胡霞红 陈苏. 多功能纳米纤维微流体纺丝技术及其应用研究进展[J]. 纺织学报, 2018, 39(12): 158-165. |
[7] | 方玮 徐岚. 漏斗式喷气静电纺聚乙烯吡咯烷酮纳米纤维膜的制备及其表征[J]. 纺织学报, 2018, 39(10): 7-11. |
[8] | 杨晨啸 李鹂. 柔性智能纺织品与功能纤维的融合[J]. 纺织学报, 2018, 39(05): 160-169. |
[9] | 秦益民. 海藻酸盐纤维的生物活性和应用功效[J]. 纺织学报, 2018, 39(04): 175-180. |
[10] | 王松林 相恒学 徐锦龙 成艳华 周哲 孙宾 朱美芳. 通用合成纤维功能化基础问题与发展趋势[J]. 纺织学报, 2018, 39(03): 167-174. |
[11] | 张克勤 杜德壮. 石墨烯功能纤维[J]. 纺织学报, 2016, 37(10): 153-157. |
[12] | 秦益民. 海藻酸盐医用敷料的临床应用[J]. 纺织学报, 2014, 35(4): 148-0. |
[13] | 王锐 莫小慧 王晓东. 海藻酸盐纤维应用现状及发展趋势[J]. 纺织学报, 2014, 35(2): 145-0. |
[14] | 李新娥. 玄武岩纤维和织物的研究进展[J]. 纺织学报, 2010, 31(1): 145-152. |
[15] | 杨晓华;赵星洁;刘英华. 二安替比林甲烷分光光度法测定功能纤维中TiO2含量[J]. 纺织学报, 2007, 28(8): 8-11. |
|