毛纱上浆用丁二酸酐酰化明胶浆料的制备及其性能

doi:10.13475/j.fzxb.20200400208

纺织学报 ›› 2021, Vol. 42 ›› Issue (04): 93-100.doi: 10.13475/j.fzxb.20200400208

毛纱上浆用丁二酸酐酰化明胶浆料的制备及其性能

杨雯静¹, 武海良¹(), 马建华²^,³, 姚一军¹, 沈艳琴¹

1.西安工程大学纺织科学与工程学院, 陕西西安 710048
2.西安工程大学材料工程学院,陕西西安 710048
3.绍兴市柯桥区西纺纺织产业创新研究院, 浙江绍兴 312030

收稿日期:2020-04-01 修回日期:2021-01-05 出版日期:2021-04-15 发布日期:2021-04-20
通讯作者: 武海良
作者简介:杨雯静(1995—),女,硕士生。主要研究方向为新型毛纱用浆料及浆纱工艺。
基金资助:
国家重点研发计划资助项目(2017YFB0309100);陕西省重点研发计划项目(2019GY-177);西安工程大学研究生创新基金项目(chx2020003);西安工程大学柯桥纺织产业创新研究院产学研协同创新项目(19KQZD13)

Preparation and properties of succinic anhydride acylated gelatin sizing agent for wool yarn sizing

YANG Wenjing¹, WU Hailiang¹(), MA Jianhua²^,³, YAO Yijun¹, SHEN Yanqin¹

1. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
2. School of Materials Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
3. Shaoxing Keqiao West-Tex Textile Industry Innovative Institute, Shaoxing, Zhejiang 312030, China

Received:2020-04-01 Revised:2021-01-05 Online:2021-04-15 Published:2021-04-20
Contact: WU Hailiang

摘要/Abstract

摘要：

针对明胶在室温凝胶且在毛纱上浆时存在浆膜韧性差的问题,采用丁二酸酐(C₄H₄O₃)对明胶进行酰化改性,合成了一种毛纱室温上浆用改性明胶蛋白(Gel-C₄H₄O₃)浆料。借助红外光谱仪、X射线衍射仪、扫描电子显微镜及差示扫描量热仪对Gel-C₄H₄O₃浆料结构及玻璃化转变温度进行测试表征,系统研究了酰化度与Gel-C₄H₄O₃浆液和浆膜性能的关系。结果表明:C₄H₄O₃可与明胶分子链上的氨基发生酰化反应;与采用丙烯酸、丙烯酰胺、丙烯酸酯类单体接枝改性明胶浆料相比,C₄H₄O₃酰化改性后的明胶浆料在室温时不凝胶;当酰化度为0.96时,Gel-C₄H₄O₃浆液对毛纱表现出优良的黏附性,Gel-C₄H₄O₃浆膜的断裂强度和韧性显著增加。此研究为毛纱室温上浆提供了性能优良的浆料制备方法。

关键词: 改性明胶蛋白浆料, 毛纱上浆, 酰化度, 浆液性能, 浆膜性能, 丁二酸酐

Abstract:

To address the problems of gelatin gelling at room temperature and poor toughness of size film when gelatin is used to sizing wool yarns, the modified gelatin protein (Gel-C₄H₄O₃) for sizing at room temperature was prepared by acylation of gelatin with succinic anhydride (C₄H₄O₃). The structure and glass transition temperature of Gel-C₄H₄O₃ sizing agent were tested and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscope and differential scanning calorimeter. The relationship between the acylation degree and the size liquid and membrane properties of Gel-C₄H₄O₃ was systematically studied. The results show that C₄H₄O₃ can react with the amino groups on the gelatin molecular chain. Compared with the existing acrylic, acrylamide or acrylate monomers-grafted gelatin, Gel-C₄H₄O₃ exhibited no gel at room temperature. When the acylation degree is 0.96, Gel-C₄H₄O₃ size liquid showed excellent adhesion to wool yarn and the fracture strength and toughness of Gel-C₄H₄O₃ size membrane are significantly increased. It provides an excellent sizing agent preparation method for wool yarn sizing at room temperature.

Key words: modified gelatin protein sizing agent, wool yarn sizing, acylation degree, size liquid property, size membrane property, succinic anhydride

中图分类号:

TS103.846

杨雯静, 武海良, 马建华, 姚一军, 沈艳琴. 毛纱上浆用丁二酸酐酰化明胶浆料的制备及其性能[J]. 纺织学报, 2021, 42(04): 93-100.

YANG Wenjing, WU Hailiang, MA Jianhua, YAO Yijun, SHEN Yanqin. Preparation and properties of succinic anhydride acylated gelatin sizing agent for wool yarn sizing[J]. Journal of Textile Research, 2021, 42(04): 93-100.

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氨基酸种类	氨基酸含量
氨基酸种类	明胶	Gel-C₄H₄O₃浆料
天冬氨酸(Asp)	6.716	8.121
苏氨酸(Thr)	2.465	2.441
丝氨酸(Ser)	5.465	6.989
谷氨酸(Glu)	15.746	15.311
脯氨酸(Pro)	4.136	4.166
甘氨酸(Gly)	6.046	6.465
丙氨酸(Ala)	4.565	5.798
胱氨酸(Cys)	2.065	2.465
缬氨酸(Val)	6.444	6.426
甲硫氨酸(Met)	2.798	2.793
异亮氨酸(Ile)	3.313	3.465
亮氨酸(Leu)	5.265	7.465
酪氨酸(Tyr)	4.999	5.444
苯丙氨酸(Phe)	6.124	6.989
赖氨酸(Lys)	2.999	1.835
组氨酸(His)	2.466	2.311
精氨酸(Arg)	7.456	6.591

酰化度	重均分子量	酰化度	重均分子量
0.43	92 934	0.93	105 436
0.81	93 652	0.96	116 253
0.91	95 943

毛纱上浆用丁二酸酐酰化明胶浆料的制备及其性能

Preparation and properties of succinic anhydride acylated gelatin sizing agent for wool yarn sizing

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