纺织学报 ›› 2021, Vol. 42 ›› Issue (06): 128-132.doi: 10.13475/j.fzxb.20200607205

• 染整与化学品 • 上一篇    下一篇

液氨处理对锦纶/棉混纺织物性能的影响

张华1(), 张杰2, 高燕3   

  1. 1. 军事科学院系统工程研究院 军需工程技术研究所, 北京 100088
    2. 北京邦维高科特种纺织品有限责任公司, 北京 100043
    3. 中纺协(北京)检验技术服务有限公司/中国纺织工业联合会检测中心, 北京 100025
  • 收稿日期:2020-06-07 修回日期:2021-03-17 出版日期:2021-06-15 发布日期:2021-06-28
  • 作者简介:张华(1969—),男,高级工程师,博士。主要研究方向为功能纺织材料的开发及其应用。E-mail: stone1992@126.com

Influence of liquid ammonia treatment on properties of polyamide/cotton blended fabrics

ZHANG Hua1(), ZHANG Jie2, GAO Yan3   

  1. 1. Institute of Quartermaster Engineering & Technology, Institute of Engineering, Academy of Military Science, PLA, Beijing 100088, China
    2. Beijing BW Techtextile Co., Ltd., Beijing 100043, China
    3. United Testing Services (Beijing) Co., Ltd.,/CNTAC Testing Center, Beijing 100025, China
  • Received:2020-06-07 Revised:2021-03-17 Published:2021-06-15 Online:2021-06-28

摘要:

锦纶/棉混纺织物存在易折皱外观不平整的问题,制约了其在高档服装上的应用。为此,以锦纶/棉混纺织物为研究对象,在坯布预处理后染整前对其进行液氨处理,研究了液氨处理对织物拉伸强力、撕破强力、折皱回复角及表面性能的影响。通过平滑感、温暖感及柔软感3个定量指标,评价液氨处理前后锦/棉混纺织物的风格、手感变化情况。结果表明:液氨整理可以提升锦/棉织物的拉伸强力及撕破强力,处理后织物的折皱回复角从218°提升至252.3°,粗糙度波长与振幅之比从50.46降低至44.87,表明液氨处理后织物的抗皱性和平滑感均得到了明显改善;尽管液氨处理未明显改善织物的柔软感,但处理织物的热导率较未处理织物仍有一定程度降低,致使织物接触温暖感有所提升。

关键词: 液氨处理, 锦纶/棉织物, 表面性能, 折皱回复角, 织物手感

Abstract:

Polyamide/cotton blended fabrics prone to wrinkles and uneven appearance limiting their applications in high-quality clothing. Aiming at such problems, a polyamide/cotton blended fabric was taken as the research object, and the greige was treated with liquid ammonia after pretreatment and before dyeing and finishing. The effect of the liquid ammonia treatment on the tensile strength, tear strength, wrinkle recovery and surface properties were evaluated. Three quantitative indicators, i.e. smoothness, warmth and softness, were used to evaluate handle of the polyamide/cotton blended fabric samples before and after liquid ammonia treatment. The results show that the liquid ammonia finishing can increase both the tensile strength and tear strength of the polyamide/cotton blended fabric. The wrinkle recovery angle of the fabrics treated with liquid ammonia increased from 218° to 252.3°, and the ratio of roughness wavelength-to-amplitude decreased from 50.46 to 44.87, which indicates that the crease resistance and smoothness of the fabrics treated with liquid ammonia were significantly improved. Although liquid ammonia did not significantly improve the softness of the fabric, the thermal conductivity of the treated fabric was lower than that of the untreated fabric to a certain extent, resulting in the improvement of the contact warmth of the fabric.

Key words: liquid ammonia treatment, polyamide/cotton fabric, surface characteristic, wrinkle recovery angle, fabric handle

中图分类号: 

  • TS195.513

表1

染整过程中织物拉伸强力变化情况"

试样 经向拉伸强力 纬向拉伸强力
未经液
氨处理
液氨
处理
未经液
氨处理
液氨
处理
二次预定形织物 1 542.0 1 632.3 1 171.2 1 146.7
染色织物 1 574.8 1 591.7 1 198.5 1 097.1
亲水整理织物 1 706.3 1 736.3 1 152.9 1 167.1
成品织物 1 567.8 1 613.9 1 186.7 1 206.1

表2

染整过程中织物撕破强力变化"

试样 经向撕破强力 纬向撕破强力
未经液
氨处理
液氨
处理
未经液
氨处理
液氨
处理
二次预定形织物 139.3 183.8 96.6 106.6
染色织物 125.7 143.4 74.3 103.1
亲水整理织物 169.8 217.8 92.8 101.1
成品织物 190.5 227.7 146.2 164.6

表3

染整过程中织物折皱回复角变化"

试样 折皱回复角/(°)
未经液氨处理 液氨处理
二次预定形织物 159.9 166.45
染色织物 154.1 174.90
亲水整理织物 186.1 196.90
成品织物 218.0 252.30

表4

液氨处理前后织物手感特性指标变化"

处理
前后
挠曲功/
(cN·mm·rad)
压缩功/
(cN·mm)
压缩恢
复率/%
压缩刚度/
(cN·mm-3)
热导率/(W·(m·℃)-1) 最大热
导率/
(W·mm-2)
表面粗糙
度振幅/
μm
表面粗糙
度波长/
mm
表面摩
擦因数
压缩时 恢复时
未处理 1 049.06 242.40 0.84 1 397.25 54.46 55.28 1 632.59 30.52 1.54 0.29
处理后 1 023.10 237.74 0.80 1 400.89 53.73 53.84 1 585.72 30.53 1.37 0.28

表5

液氨处理前后织物综合手感值"

手感 织物综合手感值
未经液氨处理 液氨处理
平滑感 0.41 0.43
柔软感 0.29 0.29
温暖感 0.45 0.46
综合感 0.39 0.4
[1] 韦永慧. 液氨丝光和潮交联处理对纯棉色织物物理性能的影响[J]. 化纤与纺织技术, 2014 (1):1-3.
WEI Yonghui. Effects of liquid ammonia mercerization and moist-crosslinking treatment on physical property of cotton yarn-dyed fabric[J]. Chemical Fiber & Textile Technology, 2014 (1):1-3.
[2] 何中琴. 气相整理法的棉织物形态稳定整理[J]. 印染译丛, 1999 (2):1-7.
HE Zhongqin. Morphological stability of cotton fabric by gas phase finishing[J]. Translation of Printing and Dyeing, 1999 (2):1-7.
[3] 王晶晶. 液氨整理对棉织物服用性能的影响[J]. 印染助剂, 2014 (9):36-38.
WANG Jingjing. Effects of liquid ammonia treatment on cotton fabric wearability[J]. Textile Auxiliaries, 2014 (9):36-38.
[4] 周永凯, 高燕, 戴春芬, 等. 液氨处理前后大麻纤维结构与性能研究[J]. 北京服装学院学报, 2011, 31(4):59-67.
ZHOU Yongkai, GAO Yan, DAI Chunfen, et al. Structure and properties of hemp fabrics with liquid ammonia treatment[J]. Journal of Beijing Institute of Clothing Technology, 2011, 31(4):59-67.
[5] 张华, 冯家好, 李俊, 等. 液氨处理对亚麻纤维结构与织物性能的影响[J]. 纺织学报, 2008, 29(6):68-72.
ZHANG Hua, FENG Jiahao, LI Jun, et al. Effect of liquid ammonia treatment on fine structure of linen fiber and its fabric properties[J]. Journal of Textile Research, 2008, 29(6):68-72.
[6] 唐占伟, 张华, 来侃. 液氨处理对大麻纤维结构与性能的影响[J]. 纺织学报, 2008, 29(1):69-72.
TANG Zhanwei, ZHANG Hua, LAI Kan. Effect of liquid ammonia treatment on the structure[J]. Journal of Textile Research, 2008, 29(1):69-72.
[7] LEE Muncheul, WAKIDA Tomiji, TOKUYAMA Takako, et al. Liquid ammonia treatment of regenerated cellulosic fabrics[J]. Textile Research Journal, 2005, 75(1):13-18.
doi: 10.1177/004051750507500104
[8] 苏茂尧, 由利丽. 纤维素经液氨预处理对其结构和晶型的影响[J]. 纤维素科学与技术, 1997 (3):7-12.
SU Maoyao, YOU Lili. The effect of treatment anhydrous am monia on the of cellulose with liquid structure and Iattice form[J]. Journal of Cellulose Science and Technology, 1997 (3):7-12.
[9] HUANG Wenyu, ZHAO Min, ZHU Huizhen, et al. Structure of ramie treated by liquid ammonia[J]. Journal of Donghua University, 2006, 23 (1):103-107.
[10] LEE M, LEE M S, WAKIDA T, et al. Liquid ammonia treatment of nylon 6 fabric[J]. Textile Research Journal, 2002, 72(6):539-544.
doi: 10.1177/004051750207200613
[11] 于伟东, 储才元. 纺织物理[M]. 上海: 东华大学出版社, 2009:1-80.
YU Weidong, CHU Caiyuan. Textile physics[M]. Shanghai: Donghua University Press, 2009:1-80.
[12] SAAPAN A A, KANDIL S H, HABIB A M. Liquid ammonia and caustic mercerization of cotton fibers using x-ray, infrared, and sorption measurements[J]. Textile Research Journal, 1984, 54(12):863-867.
doi: 10.1177/004051758405401212
[13] 高嵩, 肖旭高, 王济永. 纯棉液氨抗皱免烫整理[J]. 纺织导报, 1999 (3):32-38.
GAO Song, XIAO Xugao, WANG Jiyong. Liquid ammonia-based anti-crease & easy-care finish of 100% cotton fabic[J]. China Textile Leader, 1999 (3):32-38.
[14] 朱慧珍, 黄小彧, 任小勇, 等. 液氨处理前后棉纤维的结构和性能[J]. 印染, 2003 (4):8-10.
ZHU Huizhen, HUANG Xiaoyu, REN Xiaoyong, et al. Cotton fiber structure and property change after liquid ammoia treatment[J]. China Dyeing & Finishing, 2003 (4):8-10.
[15] 周永凯, 范嘉骥, 奚传霖. 液氨处理中去氨方式对棉纤维结构及织物性能影响[J]. 纺织学报, 1987 (12):37-40.
ZHOU Yongkai, FAN Jiaji, XI Chuanlin. Effect of remove ammoia method on the cotton fiber and fabric[J]. Journal of Textile Research, 1987 (12):37-40.
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