纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 192-200.doi: 10.13475/j.fzxb.20200707709

• 综合述评 • 上一篇    

纺织品着色用有机颜料改性技术的研究进展

汪芬萍1,2, 李家炜1,2, 黄骅隽1, 吴金丹1,2, 付少海3, 戚栋明1,2(), 赵磊4, 何贵平4   

  1. 1.浙江理工大学 先进纺织材料与制备技术教育部重点实验室, 浙江 杭州 310018
    2.浙江理工大学 生态染整技术教育部工程中心, 浙江 杭州 310018
    3.生态纺织教育部重点实验室(江南大学), 江苏 无锡 214122
    4.浙江纳美新材料股份有限公司, 浙江 湖州 313301
  • 收稿日期:2020-07-30 修回日期:2021-04-02 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 戚栋明
  • 作者简介:汪芬萍(1997—),女,硕士生。主要研究方向为颜料胶囊制备及成膜研究。
  • 基金资助:
    国家自然科学基金项目(51703200);浙江省基础公益研究计划项目(LGG20E030006);国家级大学生创新创业训练计划项目(201910338007);浙江理工大学基本科研业务费专项资金项目(2019Q021)

Research progress of organic pigment modification technology for textiles coloration

WANG Fenping1,2, LI Jiawei1,2, HUANG Huajun1, WU Jindan1,2, FU Shaohai3, QI Dongming1,2(), ZHAO Lei4, HE Guiping4   

  1. 1. Key Laboratory of Advanced Textile Materials & Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    3. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
    4. Zhejiang Namei New Material Co., Ltd., Huzhou, Zhejiang 313301, China
  • Received:2020-07-30 Revised:2021-04-02 Published:2021-07-15 Online:2021-07-22
  • Contact: QI Dongming

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摘要：

有机颜料微细粒子存在易团聚、分散稳定性差等问题,对其进行有效改性和稳定分散是目前纺织品着色领域的一个热点与难点问题。综述了国内外有机颜料改性技术的研究进展,介绍了表面活性剂稳定和有机/无机材料封装等方法,讨论了改性技术对颜料性能的影响。研究指出:有机/无机材料包覆改性大大提高了颜料的使用价值,解决了颜料在常见储存与使用情况下分散性、耐光性、耐候性及热稳定性问题,然而颜料墨水的快速印染、色彩的精细控制技术以及涂料印花织物服用性能的提升亟待深入研究。

关键词: 改性颜料, 分散, 染色, 印花, 颜料油墨, 着色剂, 纺织品

Abstract:

Due to easy agglomeration and poor water-dispersion stability of organic pigment micro-particles, the modification of organic pigment micro-particles attracted much research attention in the field of textile coloration. This paper reviews global research progress in modification technology for organic pigments, introduces the stabilization of surfactant and encapsulation of organic/inorganic materials, and discusses the influence of modification technology on the properties of pigments. It is pointed out that coating modification of organic/inorganic materials has greatly improved the use of pigments, solving the problems of pigment dispersibility, light resistance, weather resistance and thermal stability under common storage and use conditions. However, the pigment modification techniques need continued attention and urgent research for achieving rapid printing and dyeing, fine color quality and improved wearing property.

Key words: modified pigment, dispersion, dyeing, printing, pigment ink, colorant, textiles

中图分类号: 

  • TS194.9

表1

有机颜料原位聚合改性技术"

原位聚合改性技术 性能特点 参考文献
乳液聚合法 包覆率高,包覆形态好;提高颜料的分散稳定性 [39-43]
微悬浮聚合法 可制备形态结构可控的颜料/聚合物乳胶 [44-47]
细乳液聚合法 颜料包覆率高;有效提高颜料分散性;体系稳定;胶粒尺寸、组成、结构可调控性强 [48-56]
可逆加成链断裂转移自由基聚合法 聚合物的分子结构可控;颜料包覆率高;适用单体范围广 [57-61]

图1

乳液聚合法包覆酞菁蓝颜料(PB)的工艺流程"

图2

采用悬浮聚合法制备的颜料微胶囊的TEM照片"

图3

包覆前后超细CB的TEM照片"

图4

含硅颜料胶囊在织物表面的成膜模型"

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