高灵敏超压缩生物基炭化材料柔性压力传感器的制备及其性能

doi:10.13475/j.fzxb.20211100908

纺织学报 ›› 2022, Vol. 43 ›› Issue (02): 61-68.doi: 10.13475/j.fzxb.20211100908

高灵敏超压缩生物基炭化材料柔性压力传感器的制备及其性能

林美霞¹^,², 王嘉雯¹, 肖爽¹^,², 王晓云¹, 刘皓¹^,², 何崟¹^,²()

1.天津工业大学纺织科学与工程学院, 天津 300387
2.天津工业大学智能可穿戴电子纺织品研究所, 天津 300387

收稿日期:2021-11-02 修回日期:2021-12-02 出版日期:2022-02-15 发布日期:2022-03-15
通讯作者: 何崟
作者简介:林美霞(1996—),女,硕士生。主要研究方向为智能可穿戴纺织品。
基金资助:
中国博士后基金项目(2021M691699);国家自然科学基金项目(51473122);天津市自然科学基金项目(18JCYBJC18500)

Preparation and performance of high sensitive ultra-compressed bio-based carbonized flexible pressure sensor

LIN Meixia¹^,², WANG Jiawen¹, XIAO Shuang¹^,², WANG Xiaoyun¹, LIU Hao¹^,², HE Yin¹^,²()

1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
2. Institute of Smart Wearable Electronic Textiles, Tiangong University, Tianjin 300387, China

Received:2021-11-02 Revised:2021-12-02 Published:2022-02-15 Online:2022-03-15
Contact: HE Yin

摘要/Abstract

摘要：

为获得灵敏度高、响应范围广和环境友好的柔性力学传感器,以巴尔杉木为基材,采用自上而下的炭化木材技术,制备了聚氨酯/炭化木气凝胶复合导电材料,并利用聚氨酯浸泡处理方法提高炭化材料的压缩性和回弹性。使用扫描电子显微镜等仪器表征了炭化前后木气凝胶的表观结构、热稳定性、力电学性能及其柔性压力传感器的传感性能。结果表明,炭化木气凝胶具有独特的三维拱形层状结构,孔隙率达55.73%,且具有较高的热稳定性和可压缩性,其中质量分数为4%的聚氨酯/炭化木气凝胶具有良好的传感性能,在1~60 kPa的宽检测限下灵敏度达到61.02 kPa^-1,迟滞率低于4.87%,可重复性达10 000次循环。以该气凝胶为敏感材料构建的柔性压力传感器可应用于人体生理信号及运动行为的监测。

关键词: 生物基炭化材料, 柔性压力传感器, 炭化木气凝胶, 热塑性聚氨酯, 多孔材料

Abstract:

In order to obtain flexible mechanical sensors with high sensitivity, wide response range and environment-friendliness, the top-down carbonized wood technology was adopted to prepare polyurethane/carbonized wood aerogel composite conductive materials, with balsa fir as the base material. The compression and resilience of the carbonized materials were improved by soaking the materials in polyurethane. Scanning Electronic microscopy and other instruments were used to characterize the apparent structure, thermal stability, mechanical and electrical properties of wood aerogels before and after carbonization, as well as the sensing properties of flexible pressure sensors. The results show that the carbonized wood aerogel has a unique three-dimensional arched layer structure with a porosity of 55.73% and high thermal stability and compressibility. The 4% polyurethane/wood carbide aerogels have demonstrated good sensing properties, with the sensitivity being 61.02 kPa^-1, the hysteresis less than 4.87%, and the repeatability 10 000 cycles under the wide detection limit of 1-60 kPa. The flexible pressure sensor based on the aerogel can be used to monitor physiological signals and human movement behavior.

Key words: bio-based carbonized material, flexible pressure sensor, carbonized wood aerogel, thermoplastic polyurethane, porous material

中图分类号:

TP212.2

林美霞, 王嘉雯, 肖爽, 王晓云, 刘皓, 何崟. 高灵敏超压缩生物基炭化材料柔性压力传感器的制备及其性能[J]. 纺织学报, 2022, 43(02): 61-68.

LIN Meixia, WANG Jiawen, XIAO Shuang, WANG Xiaoyun, LIU Hao, HE Yin. Preparation and performance of high sensitive ultra-compressed bio-based carbonized flexible pressure sensor[J]. Journal of Textile Research, 2022, 43(02): 61-68.

图/表 11

图1

图2

图3

图4

表1

图5

图6

图7

图8

图9

图10

参考文献 15

[1]	ZHANG Y, HAN F, HU Y G, et al. Flexible and highly sensitive pressure sensors with surface discrete microdomes made from self-assembled polymer microspheres array[J]. Macromolecular Chemistry and Physics, 2020, 221(11): 2000073-2000081. doi: 10.1002/macp.v221.11
[2]	KARNAUSHENKO D, KANG T, BANDARI V K, et al. 3D self assembled microelectronic devices: concepts, materials, applications[J]. Advanced Materials, 2019, 1902994:1-30.
[3]	杨楠. 用于柔性电子材料的智能导电织物性能研究[D]. 上海:东华大学, 2011: 14-20.
	YANG Nan. Research on the performance of intelligent conductive fabric for special electronic materials[D]. Shanghai: Donghua University, 2011:14-20.
[4]	王俊璞. 柔性导电纤维/织物应变传感行为与机理研究[D]. 西安:西北工业大学, 2014: 7-15.
	WANG Junpu. Research on the strain sensing behavior and mechanism of flexible conductive fiber/fabric[D]. Xi'an: Northwestern Polytechnical University, 2014: 7-15.
[5]	WANG C, XIA K, WANG H, et al. Advanced carbon for flexible and wearable electronics[J]. Advanced Materials, 2019, 31(9): 1-37.
[6]	GUAN H, MENG J, CHENG Z, et al. Processing natural wood into a high-performance flexible pressure sensor[J]. ACS Applied Materials & Interfaces, 2020, 12(41): 46357-46365.
[7]	GAO N, ZHANG X, LIAO S, et al. Polymer swelling induced conductive wrinkles for an ultrasensitive pressure sensor[J]. ACS Macro Letters, 2016, 5(7): 823-827. doi: 10.1021/acsmacrolett.6b00338
[8]	LI J, ORREGO S, PAN J, et al. Ultrasensitive, flexible, and low-cost nanoporous piezoresistive composites for tactile pressure sensing[J]. Nanoscale, 2019, 11(6): 2779-2786. doi: 10.1039/C8NR09959F
[9]	KANG D, PIKHITSA P V, CHOI Y W, et al. Ultrasensitive mechanical crack-based sensor inspired by the spider sensory system[J]. Nature, 2014, 516(7530): 222-226. doi: 10.1038/nature14002
[10]	QIU Z, WAN Y, ZHOU W, et al. Ionic skin with biomimetic dielectric layer templated from calathea zebrine leaf[J]. Advanced Functional Materials, 2018, 28(37): 1-9.
[11]	陈媛, 韩雁明, 范东斌, 等. 生物质纤维素基碳气凝胶材料研究进展[J]. 林业科学, 2019, 55(10): 88-98.
	CHEN Yuan, HAN Yanming, FAN Dongbin, et al. Research progress of biomass cellulose-based carbon aerogel materials[J]. Forestry Science, 2019, 55(10): 88-98.
[12]	WANG K, LIU X, TAN Y, et al. Two-dimensional membrane and three-dimensional bulk aerogel materials via top-down wood nanotechnology for multibehavioral and reusable oil/water separation[J]. Chemical Engineering Journal, 2019, 371:769-780. doi: 10.1016/j.cej.2019.04.108
[13]	ZHANG Q, CHEN C, CHEN W, et al. Nanocellulose-enabled, all-nanofiber, high-performance supercapa-citor[J]. ACS Applied Materials & Interfaces, 2019(1): 5919-5927.
[14]	CHEN C, SONG J, ZHU S, et al. Scalable and sustainable approach toward highly compressible, anisotropic, lamellar carbon sponge[J]. Chem, 2018, 4(3): 544-554. doi: 10.1016/j.chempr.2017.12.028
[15]	WANG M, LI R N, CHEN G X, et al. Highly stretchable, transparent, and conductive wood fabricated by in situ photopolymerization with polymerizable deep eutectic solvents[J]. ACS Applied Materials & Interfaces, 2019, 11(15): 14313-14321.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

压缩材料	压缩前高度/cm	压缩后高度/cm	压缩应变/%
天然木块	1.20	0.879	26.7
聚氨酯/炭化木气凝胶	1.00	0.122	87.8

高灵敏超压缩生物基炭化材料柔性压力传感器的制备及其性能

Preparation and performance of high sensitive ultra-compressed bio-based carbonized flexible pressure sensor

RichHTML

PDF (PC)

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 15

相关文章 10

Metrics

本文评价

推荐阅读 10

[1]	许仕林, 杨世玉, 张亚茹, 胡柳, 胡毅. 热塑性聚氨酯/特氟龙无定形氟聚物超疏水纳米纤维膜制备及其性能[J]. 纺织学报, 2021, 42(12): 42-42.
[2]	陈足娇, 张睿, 卓雯雯, 张龙琳, 周莉. 可穿戴足底压力监测系统研究进展[J]. 纺织学报, 2021, 42(09): 31-38.
[3]	叶成伟, 汪屹, 徐岚. 钴基分级多孔复合碳材料的制备及其电化学性能[J]. 纺织学报, 2021, 42(08): 57-63.
[4]	白赫, 钱晓明, 范金土, 钱幺, 刘永胜, 王小波. 纤维质多孔材料中纤维间接触点数量的理论模型[J]. 纺织学报, 2019, 40(12): 21-26.
[5]	王杰, 周茗玮, 汪滨, 李秀艳. 纳米纤维膜基柔性压力传感器的优化设计制备[J]. 纺织学报, 2019, 40(11): 32-37.
[6]	崔俊杰徐旭凡马辉. 多孔绵材料层对防水透湿复合织物性能的影响[J]. 纺织学报, 2016, 37(11): 55-58.
[7]	姚跃飞;高磊;杨琼丽;俞来明;罗勇波;傅雅琴;刘冠峰. 玻璃纤维织物结构参数对隔声性能的影响[J]. 纺织学报, 2009, 30(02): 52-55.
[8]	高欣;张海萍;陈宇;朱良均;闵思佳. 丝素蛋白多孔材料及其在组织工程领域的应用[J]. 纺织学报, 2008, 29(10): 132-136.
[9]	黄机质.;张建春;王锋. 防护服用聚四氟乙烯复合膜的结构和性能[J]. 纺织学报, 2006, 27(9): 78-80.
[10]	王新锋;罗欣;汪晓东;吴慧莉. 改性聚氨酯热粘性能及力学性能[J]. 纺织学报, 2006, 27(2): 58-60.