纺织学报 ›› 2022, Vol. 43 ›› Issue (02): 149-155.doi: 10.13475/j.fzxb.20211102207

• 染整与化学品 • 上一篇    下一篇

具有低角度依赖性的全可见光谱结构色薄膜的制备

林田田, 杨丹, 高伟洪(), 张之悦, 赵小燕   

  1. 上海工程技术大学 纺织服装学院, 上海 201620
  • 收稿日期:2021-11-03 修回日期:2021-12-01 出版日期:2022-02-15 发布日期:2022-03-15
  • 通讯作者: 高伟洪
  • 作者简介:林田田(1996—),女,硕士生。主要研究方向为非晶光子晶体材料。
  • 基金资助:
    国家自然科学基金项目(51803117);上海高校青年东方学者岗位计划资助项目(QD2018040)

Low angle-dependent structurally coloured films over full visible spectrum

LIN Tiantian, YANG Dan, GAO Weihong(), ZHANG Zhiyue, ZHAO Xiaoyan   

  1. School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
  • Received:2021-11-03 Revised:2021-12-01 Published:2022-02-15 Online:2022-03-15
  • Contact: GAO Weihong

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摘要：

为解决传统染料高污染、高能耗等问题,实现无污染的全可见光谱结构色的制备,采用基于Stöber法的溶剂调控法合成了3种不同粒径(320、240和200 nm)的SiO2纳米颗粒(SNPs),3种粒径的SNPs分别制备出了红色、绿色和紫色SiO2光子晶体(PC)薄膜,然后通过改变2种粒径SNPs的质量比制备了能够覆盖全可见光谱的结构色PC薄膜。结果表明:当较小尺寸SNPs的比例增加时,PC膜的结构色发生蓝移,另外由2种粒径SNPs组成的PC薄膜显示出低角度依赖性的结构色,这是由其非晶光子晶体(APC)结构所造成的,传统全可见光谱结构色的获取需要合成一系列粒径的微球,这种方法与传统制备方法相比更简单、更快速,可作为颜料和涂料对不同的基材染色。

关键词: 结构色, 光子晶体, 二氧化硅纳米颗粒, 全可见光谱色, 低角度依赖性

Abstract:

In order to solve high pollution and energy consumption of traditional dyes, and prepare full visible spectral structural colours with no pollution, three batches of different sized (320, 240 and 200 nm) silica nanoparticles (SNPs) were synthesized by using a Stöber-based solvent varying method, the silica photonic crystal(PC) films were fabricated from the three sized bare SNPs with vivid red, green, and purple colours, respectively, and structurally coloured PC films over the full visible spectrum were fabricated by varying the mass ratio of two sized SNPs. The result showed that the structural colours of the PC films had a blue shift when the ratio of the smaller sized SNPs increased. The PC films consisting of non-uniform two sized SNPs showed low angle dependent structural colours, due to its amorphous PC structure. This method is simpler and faster than traditional self-assembly of PC materials that require a series of different sized microsphere bathes for each color, and is suitable for making stable colours as pigments and coatings on different substrates.

Key words: structural colour, photonic crystal, silica nanoparticle, full visible spectrum, low angle-dependence

中图分类号: 

  • TS190.2

表1

Sa、Sb 和 Sc的合成配方"

样品 EtOH NH3·H2O H2O TEOS
Sa 60 8 3 6
Sb 75 8 3 6
Sc 90 8 3 6

图1

全可见光谱结构色薄膜的制备流程"

图2

粒径分布图"

图3

Sa、Sb和Sc PC薄膜的反射率曲线以及光学照片"

图4

PC薄膜的光学照片以与射率波谱图以及Sb质量分数与反射峰波长关系"

图5

平均粒径与薄膜的CIE 1931色度图"

图6

PC薄膜的SEM图像以及对应的FFT图像"

图7

不同观察角度下PC薄膜的反射波普图"

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