纺织学报 ›› 2022, Vol. 43 ›› Issue (04): 90-96.doi: 10.13475/j.fzxb.20210202807

• 染整与化学品 • 上一篇    下一篇

胺化活性红195/聚合物微球的制备及其在棉织物染色中的应用

王东伟1,2, 房宽峻1,3,4(), 刘秀明1, 张鑫卿5, 安芳芳1   

  1. 1.天津工业大学 纺织科学与工程学院, 天津 300387
    2.中原工学院 纺织学院, 河南 郑州 450007
    3.青岛大学 生物多糖纤维成形与生态纺织国家重点实验室, 山东 青岛 266071
    4.山东省生态纺织省部共建协同创新中心, 山东 青岛 266071
    5.西安工程大学 纺织科学与工程学院, 陕西 西安 710048
  • 收稿日期:2021-02-09 修回日期:2022-01-11 出版日期:2022-04-15 发布日期:2022-04-20
  • 通讯作者: 房宽峻
  • 作者简介:王东伟(1978—),女,博士生。主要研究方向为纺织品清洁染整技术。
  • 基金资助:
    国家重点研发计划项目(2017YFB0309800);国家重点研发计划项目(2016YFC0400503)

Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics

WANG Dongwei1,2, FANG Kuanjun1,3,4(), LIU Xiuming1, ZHANG Xinqing5, AN Fangfang1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    3. State Key Laboratory for Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China
    4. Eco-Textiles Collaborative Innovation Center of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China
    5. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
  • Received:2021-02-09 Revised:2022-01-11 Published:2022-04-15 Online:2022-04-20
  • Contact: FANG Kuanjun

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摘要：

针对活性染料水解导致染料利用率低和环境污染等问题,采用乙二胺改性活性红195/聚合物微球制备了胺化活性红195/聚合物微球。探究了初始体系pH值、乙二胺质量分数、改性温度和时间对胺化活性红195/聚合物微球粒径和Zeta电位的影响,并考察在最佳工艺条件下制备的胺化活性红195/聚合物微球染色阳离子化棉织物的K/S值和颜色参数。结果表明:在初始体系pH值为11,乙二胺质量分数为40%,改性温度为60 ℃和改性时间为120 min条件下,可制得粒径为96.5 nm,多分散指数为0.075,Zeta电位为-33.7 mV的胺化活性红195/聚合物微球;染色后阳离子化棉织物的K/S值可达9.3,是相同用量活性红195上染棉织物K/S值的3.1倍,且色彩鲜艳度提高,耐摩擦色牢度和耐皂洗色牢度均达到4级及以上。

关键词: 活性染料, 彩色聚合物微球, 阳离子化改性, 棉织物染色

Abstract:

In view of the problems that hydrolysis of reactive dyes leads to low utilization and environmental pollution, nanospheres were prepared by using ethylenediamine modified Reactive Red 195/polymer. The influence of initial bath pH value, mass fraction of ethylenediamine, temperature and time on the size and Zeta potential of amino-modified Reactive Red 195/polymer nanospheres were discussed, and the K/S values and color parameters of the cationic cotton fabrics dyed with the amino-modified Reactive Red 195/polymer nanospheres under the optimal conditions were investigated. The results show that the amino-modified Reactive Red 195/polymer nanospheres with an average hydration diameter of 96.5 nm, polydispersity index of 0.075 and Zeta potential of -33.7 mV were fabricated after modified with ethylenediamine under the conditions of the initial pH value 11, the mass fraction of ethylenediamine 40%, 60 ℃ for 120 min. The K/S value of the cationic cotton fabric dyed with the amino-modified Reactive Red 195/polymer nanospheres reaches up to 9.3, which is 3.1 times higher than the K/S value of the cotton fabric dyed with same dosage of Reactive Red 195, with improvement of color saturation. The rubbing and washing color fastness of dyed cotton fabrics are both equal to or higher than grade 4.

Key words: reactive dye, colored polymer nanosphere, cationic modification, cotton fabric dyeing

中图分类号: 

  • TS193.2

图1

pH值对胺化彩色微球粒径和Zeta电位的影响"

图2

乙二胺质量分数对胺化彩色微球粒径和Zeta电位的影响"

图3

温度对胺化彩色微球粒径和Zeta电位的影响"

表1

时间对胺化彩色微球粒径和Zeta电位的影响"

改性时间/min 粒径/nm Zeta电位/mV
120 99.0 -34.1
240 97.7 -37.4

图4

聚合物微球的红外光谱图"

图5

聚合物微球的XPS谱图"

表2

聚合物微球的表面元素分析"

聚合物微球 结合能/eV 元素含量/% 元素含量比
C1s O1s N1s C1s O1s N1s O与C含量比 N与C含量比
彩色微球 284.8 531.2 400.1 73.14 18.81 2.72 0.26 0.04
胺化彩色微球 78.54 13.57 4.36 0.17 0.06

表3

染色棉织物的颜色值"

色素 染料用量/
%(o.w.f)		 K/S
值		 L* a* b* C* h0
胺化彩
色微球		 0.5 1.9 62.7 42.5 -9.2 43.5 347.8
0.9 5.3 51.9 53.5 -7.0 54.0 352.6
1.4 9.3 46.9 57.9 -4.6 58.1 355.5
活性
染料		 0.5 1.3 67.1 40.0 -10.0 41.2 346.0
0.9 2.2 61.7 46.2 -10.3 47.3 347.4
1.4 3.0 58.4 49.5 -9.8 50.5 348.8

图6

不同放大倍数的胺化彩色微球染色阳离子化棉纤维的SEM照片"

表4

染色棉织物的色牢度"

色素 染料用量/
%(o.w.f)		 耐摩擦色牢度/级 耐皂洗色牢度/级
干 湿 棉沾 毛沾 变色
胺化彩
色微球		 0.5 4 ~ 5 4 5 5 4 ~ 5
0.9 4 ~ 5 4 5 5 4 ~ 5
1.4 4 ~ 5 4 5 5 4
活性
染料		 0.5 5 4 ~ 5 5 5 4 ~ 5
0.9 4 ~ 5 4 5 5 4 ~ 5
1.4 4 ~ 5 4 5 5 4 ~ 5
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