纺织学报 ›› 2022, Vol. 43 ›› Issue (05): 26-31.doi: 10.13475/j.fzxb.20211206006

• 特约专栏:第十一届中国纺织学术年会专家观点 • 上一篇    下一篇

蓖麻油基紫外光固化水性涂料墨水制备及其印花性能

戚栋明1, 樊高晴1, 虞一浩2, 符晔2, 张艳1, 陈智杰3()   

  1. 1.浙江理工大学 绿色低碳染整技术浙江省工程研究中心, 浙江 杭州 310018
    2.浙江凯瑞博科技有限公司,浙江 湖州 313100
    3.温州职业技术学院 聚合物材料及机电产品表面改性技术研究重点实验室, 浙江 温州 325035
  • 收稿日期:2021-12-18 修回日期:2022-02-11 出版日期:2022-05-15 发布日期:2022-05-30
  • 通讯作者: 陈智杰
  • 作者简介:戚栋明(1978—),男,教授,博士。主要研究方向为功能性复合乳胶制备及成膜。
  • 基金资助:
    浙江省重点研发计划项目(2021C01077);温州市科技局基础性科研项目(G2020025)

Preparation and printing properties of castor oil-based UV-curable water-based coating ink

QI Dongming1, FAN Gaoqing1, YU Yihao2, FU Ye2, ZHANG Yan1, CHEN Zhijie3()   

  1. 1. Zhejiang Provincial Engineering Center for Green and Low-Carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Zhejiang King Label Technology Co., Ltd., Huzhou, Zhejiang 313100, China
    3. Key Laboratory of Surface Modification Technology for Polymer Materials and Electromechanical Products, Wenzhou Polytechnic, Wenzhou, Zhejiang 325035, China
  • Received:2021-12-18 Revised:2022-02-11 Published:2022-05-15 Online:2022-05-30
  • Contact: CHEN Zhijie

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摘要：

为解决传统涂料印花存在的手感和牢度难以兼顾的问题,以蓖麻油、异佛尔酮二异氰酸酯、2,2-二羟甲基丁酸缩聚,再以季戊四醇三丙烯酸酯为封端剂,制得具有优异分散性、耐水性、黏结牢度的水性聚氨酯乳液,并在加入纳米颜料后制得蓖麻油基紫外光固化水性涂料墨水。研究并分析了蓖麻油含量对乳液粒径、固化胶膜性能、耐水性等的影响及原因。随后以涤纶平纹织物为代表,对比表征了蓖麻油基紫外光固化水性涂料墨水喷墨印花织物表面形貌和硬挺度、耐干湿摩擦色牢度等性能,结果表明,在最佳蓖麻油质量分数为42.1%时,喷墨印花织物具有良好的柔性和色牢度。

关键词: 蓖麻油, 聚氨酯, 涂料印花, 紫外光固化, 喷墨印花织物

Abstract:

Waterborne polyurethane emulsions were prepared aiming at difficulty in achieve good handle and fastness through the traditional coat printing. This emulsion was produced by condensing castor oil, isophorone diisocyanate, and 2,2-bis(hydroxymethyl)butyric acid, using pentaerythritol triacrylate as a capping agent, for improved dispersibility, water resistance, and bonding fastness. Castor oil-based ultraviolet (UV)-curable waterborne coating inks were obtained by adding nano-pigments to the waterborne polyurethane emulsions. The effect and mechanism of castor oil content on the emulsion particle size, cured film performance, and water resistance were studied and analyzed. Subsequently, the castor oil-based UV-curable water-based coating ink was sprayed on polyester plain fabrics, and the surface morphology, stiffness and wet and dry friction fastness of the printed fabrics were comparatively characterized. The results obtained showed that the ink-jet printed fabric has good flexibility and color fastness under the optimum amount of castor oil 42.1%.

Key words: castor oil, polyurethane, pigment printing, ultraviolet curing, ink-jet printed fabric

中图分类号: 

  • TQ325

图1

蓖麻油质量分数对聚氨酯乳液的粒径影响"

图2

不同蓖麻油质量分数的聚氨酯胶膜DSC曲线"

表1

蓖麻油质量分数对聚氨酯胶膜吸水率的影响"

蓖麻油质量分数/% 吸水率/%
30.5 8.64
36.4 6.85
42.1 3.23
47.7 3.12
53.3 3.10

图3

不同蓖麻油质量分数聚氨酯所制印花织物表面扫描电镜照片(×2 000)"

图4

蓖麻油质量分数对印花织物硬挺度的影响"

表2

蓖麻油质量分数对印花织物耐摩擦色牢度的影响"

蓖麻油质量分数/% 耐摩擦色牢度/级
干 湿
30.5 2 2
36.4 4 2
42.1 4~5 4~5
47.7 4 4
53.3 4 4
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