纺织学报 ›› 2022, Vol. 43 ›› Issue (07): 90-96.doi: 10.13475/j.fzxb.20210601008
摘要:
为解决纯棉织物的阻燃及其耐洗性问题,以生物质植酸和双氰胺为原料,制备了无卤生物质环保耐洗阻燃剂PD,并应用于棉织物的阻燃整理。借助傅里叶红外光谱仪和X射线能谱仪等分析表征了PD化学结构和元素组成,并对整理织物的表面形貌、热稳定性、阻燃及耐水洗性等进行了分析。结果表明:阻燃剂PD为多活性磷氮型阻燃剂;纯棉织物阻燃整理时,阻燃剂PD质量分数为35%;PD处理样在800 ℃热解残炭量为13.32%(氮气气氛),垂直燃烧的损毁长度为4.5 cm,极限氧指数达43.6%,且阻燃织物经40次标准洗涤后,极限氧指数仍能达到29.1%;制备的阻燃剂PD是一种阻燃效果和耐水洗性能优良的生物质环保阻燃剂。
中图分类号:
[1] |
QIU X, LI Z, LI X, et al. Flame retanlant coatings prepared ueing layer by layer assembly:a review[J]. Chemical Engineering Journal, 2018, 334(15):108-122.
doi: 10.1016/j.cej.2017.09.194 |
[2] |
SHEN Zhenqi, CHEN Li, LIN Lin, et al. Synergistic effect of layered nanofillers in intumescent flame-retardant EPDM: montmorillonite versus layered double hydroxides[J]. Industrial & Engineering Chemistry Research, 2013, 52(25) : 8454-8463.
doi: 10.1021/ie4010546 |
[3] |
ABOU-OKEIL A, EI-SAWY S M, ABDEL-MOHDY F A. Flame retardant cotton fabrice treated with organophosphorus polymer[J]. Carbohydrate Polymers, 2013, 92(2):2293-2298.
doi: 10.1016/j.carbpol.2012.12.008 |
[4] | 徐爱玲, 王春梅. 植酸的铵化及其对Lyocell织物的阻燃整理[J]. 纺织学报2020, 41(2):83-88. |
XU Ailing, WANG Chunmei. Ammonium modification of phytic acid and flame retardant finishing of Lyocell fabric[J]. Journal of Textile Research, 2020, 41(2):83-88. | |
[5] |
FENG Yajuan, ZHOU Yang, LI Daikun, et al. A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric[J]. Carbohydrate Polymers, 2017, 175: 636-644.
doi: S0144-8617(17)30766-X pmid: 28917912 |
[6] | 谷晓昱, 张军营. 用FT-IR研究双氰胺固化环氧树脂的反应机理[J]. 高分子材料科学与工程, 2006(5):182-184. |
GU Xiaoyu, ZHANG Junying. FT-IR Study on reaction mechanism of dicyandiamide curing epoxy resin[J]. Polymer Materials Science and Engineering, 2006(5):182-184. | |
[7] | 孙玉发, 周向东. 棉用新型含磷氮阻燃剂的合成及其应用[J]. 纺织学报, 2019, 40(12) : 79-85. |
SUN Yufa, ZHOU Xiangdong. Synthesis and application of a novel phosphorous nitrogen flame retardant for cotton[J]. Journal of Textile Research, 2019, 40(12) : 79-85. | |
[8] | GUO Xiaoyu, MIAO Yun, YE Pingping, et al. Multi-walled carbon nanotubes in aqueous phytic acid for enhancing biosensor[J]. Mater Res Express, 2014. DOI:10.1088/2053-1591/1/2/025403. |
[9] | 张广知, 黄小华. 纯棉篷盖布涂料染色拒水拒油阻燃复合涂层[J]. 纺织学报, 2013, 34(2):125-128. |
ZHANG Guangzhi, HUANG Xiaohua. One-bath pigment dyeing water-and oil-repellent-flame retardant coating finish of cotton canvas[J]. Journal of Textile Research, 2013, 34(2):125-128. | |
[10] |
VESEL A, MOZETIC M, KOVAC J, et al. XPS study of the deposited Ti layer in a magnetron-type sputter ion pump[J]. Applied Surface Science, 2006, 253(5):2941-2946.
doi: 10.1016/j.apsusc.2006.06.033 |
[11] |
HYDE G K, MCCULLEN S D, JEON S, et al. Atomic layer deposition and biocompatibility of titanium nitride nano-coatings on cellulose fiber substrates[J]. Biomedical Materials, 2009. DOI: 10.1088/1748-6041/4/2/025001.
doi: 10.1088/1748-6041/4/2/025001 |
[12] | 金晓冬. 含磷/氮/硫新型阻燃剂的制备及其在生物基高分子材料中的应用[D]. 北京: 北京化工大学, 2018:25, 47. |
JIN Xiaodong. Preparation of novel phosphorus/nitrogen/sulfur based flame retardant and their application in bio based polymer[D]. Beijing: Beijing University of Chemical Technology, 2018: 25, 47. | |
[13] | 倪健雄. 核-壳型聚磷酸铵阻燃剂的制备及其阻燃聚氨酯性能和机理的研究[D]. 合肥: 中国科技大学, 2009:27,44. |
NI Jianxiong. Study on preparation, performance and mechanism of the core-shell ammonium polyphosphate flame retardant polyurethane[D]. Hefei: University of Science and Technology of China, 2009:27, 44. | |
[14] | WU K, HU Y, SONG L, et al. Flame retardancy and thermal degradation of intumescent flame retardant starch-based biodegradable composite[J]. Industrial﹠Engineering Chemistry Research, 2009, 48(2):3150-3157. |
[15] | 贾丽霞, 金崇业, 刘瑞, 等. 硅磷杂化阻燃整理对羊毛结构与热稳定性能的影响[J]. 纺织学报, 2017, 38(12):101-105. |
JIA Lixia, JIN Chongye, LIU Rui, et al. Influence of flame retardant finishing with silicon-phosphorus hybridization on structure and thermal stability of wool[J]. Journal of Textile Research, 2017, 38(12):101-105.
doi: 10.1177/004051756803800111 |
|
[16] |
LUO Jie, SUN Yuyu. Acyclic N-halamine coated Kevlar fabric material: preparation and biocidal functions[J]. Industrial and Engineering Chemistry Research, 2008, 47(15): 5291-5297.
doi: 10.1021/ie800021p |
[17] |
LI X, CHEN H, WANG W, et al. Synthesis of a formaldehyde-free phosphorus-nitrogen flame retardant with multiple reactive groups and its application in cotton fabrics[J]. Polymer Degradation and Stability, 2015, 120: 193-202.
doi: 10.1016/j.polymdegradstab.2015.07.003 |
[18] |
YANG Zongyue, WANG Xiaowen, LEI Dapeng, et al. A durable flame retardant for cellulosic fabrics[J]. Polymer Degradation and Stability, 2012, 97(11): 2467-2472.
doi: 10.1016/j.polymdegradstab.2012.05.023 |
[19] |
CHEN Y, FRENDI A, TEWARI S, et al. Combustion properties of pure and fire-retarded cellulose[J]. Combustion and Flame, 1991, 84(1/2): 121-140.
doi: 10.1016/0010-2180(91)90042-A |
[20] |
SHARIATINIA Z, JAVERI N, SHEKARRIZ S. Flame retardant cotton fibers produced using novel synthesized halogen-free phosphoramide nanoparticles[J]. Carbohydrate Polymers, 2015, 118: 183-198.
doi: 10.1016/j.carbpol.2014.11.039 |
[21] |
ALONGI J, MILNES J, MALUCELLI G, et al. Thermal degradation of DNA-treated cotton fabrics under different heating conditions[J]. Journal of Analytical and Applied Pyrolysis, 2014, 108: 212-221.
doi: 10.1016/j.jaap.2014.04.014 |
[22] |
CHANG S, CONDON B, GRAVES E, et al. Flame retardant properties of triazine phosphonates derivative with cotton fabric[J]. Fibers and Polymers, 2011, 12(3): 334-339.
doi: 10.1007/s12221-011-0334-7 |
[23] |
ROSACE Giuseppe, COLLEONI Claudio, TROVATO Valentina, et al. Vinylphosphonic acid/methacrylamide system as a durable intumescent flame retardant for cotton fabric[J]. Cellulose, 2017, 24: 3095-3108.
doi: 10.1007/s10570-017-1294-x |
[24] |
HERNANDEZ-ALVARADO L A, HERNANDEZ L S, LOMELI M A, et al. Phytic acid coating on Mg-based materials for biodegradable temporary endoprosthetic applications[J]. Journal of Alloys and Compounds, 664:609-618.
doi: 10.1016/j.jallcom.2016.01.011 |
[25] | NADA A, HAMED S, SOLIMAN S, et al. Spectroscopic and ion exchange studies on modified cotton linters[J]. J Sci Ind Res, 2005, 64(12): 1003-1009. |
[26] |
LIU Huan, WANG Xiaodong, WU Denzhen. Preparation, isothermal kinetics and performance of a novel epoxy thermosetting system based on phosphazene-cyclomatrix network for halogen-free flame retardancy and high thermal stability[J]. Thermochimica Acta, 2015, 607:60-73.
doi: 10.1016/j.tca.2015.04.002 |
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