纺织学报 ›› 2022, Vol. 43 ›› Issue (09): 64-69.doi: 10.13475/j.fzxb.20210800506

• 纤维材料 • 上一篇    下一篇

磁场诱导结构生色海藻酸钙纤维的快速制备及其性能

杨春利1,2, 周伟贤2, 梁京龙2, 林桂圳2, 刘杰1,2,3, 倪延朋1,2,3, 刘云1,2,3, 商胜龙1,2,3(), 朱平1,2,3   

  1. 1.青岛大学 功能纺织品与先进材料研究院, 山东 青岛 266071
    2.青岛大学 纺织服装学院, 山东 青岛 266071
    3.青岛大学 省部共建生物多糖纤维成形与生态纺织国家重点实验室, 山东 青岛 266071
  • 收稿日期:2021-08-02 修回日期:2022-05-02 出版日期:2022-09-15 发布日期:2022-09-26
  • 通讯作者: 商胜龙
  • 作者简介:杨春利(1994—),女,硕士生。主要研究方向为智能控温纤维及纺织品。
  • 基金资助:
    国家重点研发计划项目(2020YFC1910305);省部共建生物多糖纤维成形与生态纺织国家重点实验室(青岛大学)开放课题资助项目(TSKT202105)

Rapid preparation and properties of structural colored calcium alginate fibers triggered by magnetic field

YANG Chunli1,2, ZHOU Weixian2, LIANG Jinglong2, LIN Guizhen2, LIU Jie1,2,3, NI Yanpeng1,2,3, LIU Yun1,2,3, SHANG Shenglong1,2,3(), ZHU Ping1,2,3   

  1. 1. Institute of Functional Textiles and Advanced Materials, Qingdao University, Qingdao, Shandong 266071, China
    2. College of Textile & Clothing, Qingdao University, Qingdao, Shandong 266071, China
    3. State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China
  • Received:2021-08-02 Revised:2022-05-02 Published:2022-09-15 Online:2022-09-26
  • Contact: SHANG Shenglong

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摘要：

为制备颜色饱和度高、力学性能优良的结构生色海藻酸钙纤维,首先以溶剂热法制备了磁性微球,然后将其分散至聚乙二醇二丙烯酸酯中,使磁性微球在磁场下自组装,在海藻酸钙纤维表面构筑结构色涂层,分析了影响结构生色海藻酸钙纤维显色性能和力学性能的因素。结果表明:当磁性微球的粒径分别为125、145、190 nm时,其在海藻酸钙纤维表面固化后得到了蓝色、绿色和红色的结构色,磁性微球结构色涂层可对海藻酸钙纤维进行较好地包覆,其主要成分为立方相Fe3O4,可使纤维的断裂强力由纯海藻酸钙纤维的78 cN分别增加到158、162、169 cN,断裂伸长率也得到了显著提高。

关键词: 海藻酸钙纤维, 结构生色, 磁场诱导, 磁性微球, 紫外光固化, 湿法纺丝

Abstract:

To prepare structural colored calcium alginate fibers with high color saturation and satisfactory mechanical properties, magnetic particles were prepared by solvothermal method before dispersing them in the polyethylene glycol diacrylate. A structural color coating was constructed on the surface of calcium alginate fibers by self-assembly of magnetic particles, and factors affecting the color rendering and mechanical properties of the fiber were analyzed. The results show that when the diameters of the magnetic particle are 125, 145 and 190 nm, blue, green and red structural colors were obtained after curing on the surface of calcium alginate fibers, respectively. The coatings of magnetic particles structure color can better achieved on calcium alginate fiber, and the main component is cubic Fe3O4. The mechanical properties of the structural colored calcium alginate fibers have been significantly improved, and the breaking strength has been increased from 78 cN to 158, 162 and 169 cN, respectively, along with the improved elongation at break.

Key words: calcium alginate fiber, structural color, magnetic field triggered, magnetic particle, ultraviolet curing, wet spinning

中图分类号: 

  • TS102.6

图1

结构生色海藻酸钙纤维制备流程图"

图2

不同粒径磁性微球SEM照片和粒径分布图"

图3

平均粒径为190 nm磁性微球的TEM照片和能谱图"

图4

不同粒径磁性微球的PEGDA分散液 在外界磁场作用下的显色情况"

图5

磁性微球的XRD图"

图6

不同粒径磁性微球制备的结构生色海藻酸钙纤维的数码照片和光谱图"

图7

结构色为红色的海藻酸钙纤维的SEM照片"

图8

结构生色海藻酸钙纤维力学性能"

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