纺织学报 ›› 2024, Vol. 45 ›› Issue (07): 230-239.doi: 10.13475/j.fzxb.20230203802

• 综合评述 • 上一篇    下一篇

静电溶吹微纳无机纤维制备技术及其应用进展

于雯1,2, 邓南平1,2, 唐湘泉1, 康卫民1,2(), 程博闻3   

  1. 1.天津工业大学 纺织科学与工程学院, 天津 300387
    2.天津工业大学 分离膜与膜过程国家重点实验室, 天津 300387
    3.天津科技大学, 天津 300457
  • 收稿日期:2023-02-06 修回日期:2024-01-31 出版日期:2024-07-15 发布日期:2024-07-15
  • 通讯作者: 康卫民(1979—),男,教授,博士。主要研究方向为规模化静电纺纳米纤维制备技术,微纳纤维材料设计、成形理论与应用。E-mail:kweimin@126.com。
  • 作者简介:于雯(1996—),女,博士。主要研究方向为无机微纳纤维结构设计与应用。
  • 基金资助:
    国家自然科学基金项目(51973157);天津市科技计划项目(19PTSYJC00010)

Review on preparation and applications of electro-blown spun micro-nano inorganic fibers

YU Wen1,2, DENG Nanping1,2, TANG Xiangquan1, KANG Weimin1,2(), CHENG Bowen3   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
    3. Tinjin University of Science & Technology, Tianjin 300457, China
  • Received:2023-02-06 Revised:2024-01-31 Published:2024-07-15 Online:2024-07-15

RichHTML

7

PDF (PC)

25

摘要：

静电纺丝技术存在生产效率低和对高黏纺丝溶液限制大等问题,阻碍了高性能无机纤维的大规模产业化进程,而静电溶吹技术基于静电力与气流力的耦合作用,可助力微纳纤维的高产高质。为推广静电溶吹纺丝技术并为微纳无机纤维生产提供理论和实践依据,综述了该技术的基础研究,包括原理和先进设备;具体分析了该技术生产无机纤维的影响因素,尤其明晰了产业化的可控工艺;总结了目前国内外静电溶吹技术制备无机纤维的应用进展,通过与其它纺丝技术的对比阐明了静电溶吹技术目前存在的优势和挑战,并指出协同提升纤维质量和产量、赋予纤维结构/功能多样化以及研发多孔轻质无机纤维和超细无机纱线是该技术未来的重要发展方向。

关键词: 静电溶吹纺丝, 气电纺, 无机微纳纤维, 静电纺丝, 无机纤维

Abstract:

Significance With the development of sophisticated technologies, novel materials are required for compatibility, lightweight, high strength and temperature resistance. Combined with the large length-to-diameter ratio and high specific surface area of one-dimensional materials, micro-nano inorganic fibers with size effect show great potential for many applications. However, there are some problems including insufficient fineness, poor controllability and continuity in the current methods of preparing micro-nano fibers, such as stretching method, chemical vapor deposition and phase separation. Moreover, the most mature and widely used electrospinning technology has some problems, such as low production efficiency and strict restrictions on spinning solution with high viscosity, which hinder the large-scale industrialization of high-performance inorganic fibers. Recently, electro-blown spinning, based on the coupling effect between electric field force and ejection force of the air stream, has demionstrated capability of contributing to the high yield and high quality of micro-nano fibers. Meanwhile, the airflow can assist in starting, stabilizing, and completing the rotation process of jet. Compared with traditional electrospinning and solution blow spinning technologies, inorganic fibers prepared by electro-blown spinning are characterized by higher yield (dozens to hundreds of times more than electrospinning), small diameter (nanometer and submicron scale) and uniformity.

Progress In order to promote the electro-blown spinning technology and provide theoretical and practical basis for preparing inorganic fiber, this paper reviews the basic researches, including the principle and advanced equipment. The core components are composed of feeding device, spinning die, high-voltage power supply, gas control system and receiving device. For large-scale production, there are many novel designs for spinning die, such as disc multi-nozzle, multi-branch/tip equipment, solution channel surrounded by internal/external double-layer air flow. The influencing factors of fabricating inorganic fibers by this technology are analyzed in detail in terms of the properties of spinning solution, the geometric characteristics of spinneret, the properties of air flow, the spinning voltage and the tip-collector distance, especially the controllable process of industrialization. Moreover, taking Al2O3 fiber as an example, the electro-blown spinning technology is compared with solution-blown spinning and conventional electrospinning technology from fiber morphology, pore size of membrane and production efficiency. The advantages and drawbacks of electro-blown spinning technology are discussed and clarified. In addition, the applications of electro-blown spinning inorganic fibers are presented, which concentrates on the fields of dye adsorption and degradation, biomedicine, energy, catalysis and industrial manufacturing.

Conclusion and Prospect It has been demonstrated that the superimposed airflow and electrostatic effect, with a double drafting force makes the electro-blown spinning technology achieve certain breakthroughs in the pursuit of both high yield and high quality of micro-nano inorganic fibers. The technology is suitable for preparing a wide range of ceramic materials and carbon fibers, especially for high-concentration solutions or gels. However, there are still some problems such as insufficient understanding of the jet motion under the dual control of airflow and voltage, poor toughness of produced inorganic fibers and mostly short fibers, and the lack of large-scale electro-blown spinning equipment. Therefore, efforts need to be made in the following aspects in the future. 1) It is crucial to improve the quality of inorganic fiber while ensuring the yield. The laws of jet motion and synergistic control methods under the dual control of airflow/voltage need to be clarified through the establishment of mathematical models and simulation. 2) It is necessary to diversify the structure/function of inorganic fibers. The first is to develop macro/micro special structure inorganic fibers, while the second is to play the advantages of electro-blown spinning technology easily combined with functional materials. 3) It is also necessary to strengthen the development and application of the porous and lightweight inorganic fibers and the ultrafine inorganic yarn.

Key words: electro-blown spinning, air/jet-electrospinning, inorganic micro-nano fiber, electrospinning, inorganic fiber

中图分类号: 

  • TS174

图1

静电溶吹装置及工艺参数示意图"

图2

不同技术的纺丝射流和制备的Al2O3纤维对比 注:B1为溶液喷射;B2为静电溶吹。"

[1] FILATOV Y, BUDYKA A, KIRICHENKO V. Electrospinning of micro-and nanofibers: fundamentals in separation and filtration processes[J]. Journal of Engineered Fibers and Fabrics, 2008. DOI: 10.1177/155892500800300106.
[2] UM I C, FANG D, HSIAO B S, et al. Electro-spinning and electro-blowing of hyaluronic acid[J]. Biomacromolecules, 2004, 5(4): 1428-1436.
pmid: 15244461
[3] PENG M, SUN Q, MA Q, et al. Mesoporous silica fibers prepared by electroblowing of a poly(methyl methacrylate)/tetraethoxysilane mixture in N,N-dimethylformamide[J]. Microporous and Mesoporous Materials, 2008, 115(3): 562-567.
[4] LIN Y, YAO Y, YANG X, et al. Preparation of poly(ether sulfone) nanofibers by gas-jet/electros-pinning[J]. Journal of Applied Polymer Science, 2008, 107(2): 909-917.
[5] YAO Y, ZHU P, YE H, et al. Polysulfone nanofibers prepared by electrospinning and gas/jet-electro-spinning[J]. Frontiers of Chemistry in China, 2006, 1(3): 334-339.
[6] HOLOPAINEN J, HEIKKILÄ M J, SALMI L D, et al. Zeolitic imidazole framework-8 (ZIF-8) fibers by gas-phase conversion of electroblown zinc oxide and aluminum doped zinc oxide fibers[J]. Microporous and Mesoporous Materials, 2018, 267: 212-220.
[7] PAAJANEN J, LÖNNROT S, HEIKKILÄ M, et al. Novel electroblowing synthesis of submicron zirconium dioxide fibers: effect of fiber structure on antimony(V) adsorption[J]. Nanoscale Advances, 2019, 1(11): 4373-4383.
doi: 10.1039/c9na00414a pmid: 36134400
[8] JU J, DENG N, ZHANG D, et al. Facile construction of PCNF & CNT composite material by one-step simultaneous carbonization and chemical vapor deposition[J]. Journal of Materials Science, 2019, 54(2): 1616-1628.
[9] KANG J, DENG N, SHI D, et al. Heterojunction-accelerating lithium salt dissociation in polymer solid electrolytes[J]. Advanced Function Materials, 2023. DOI: 10.1002/adfm.202307263.
[10] FILATOV I, BOKOVA E, SMULSKAYA M, et al. Comparative analysis of electrospinning methods for producing fibres and materials with a predicted structure and complex of properties[J]. Fibres and Textiles in Eastern Europe, 2021, 29: 69-74.
[11] ZHAO Y, JIANG J, LI W, et al. Electrospinning jet behaviors under the constraints of a sheath gas[J]. AIP Advances, 2016, 6(11): 167-628.
[12] LIU Y, JIA C, LI P, et al. Mass production of hierarchically designed engine-Intake air filters by multinozzle electroblow spinning[J]. Nano Letters, 2022, 22(11): 4354-4361.
doi: 10.1021/acs.nanolett.2c00704 pmid: 35611952
[13] AN S, LEE C, LIOU M, et al. Supersonically blown ultrathin thorny devil nanofibers for efficient air cooling[J]. ACS Applied Materials & Interfaces, 2014, 6(16): 13657-13666.
[14] XU G, CHEN X, ZHU Z, et al. Pulse gas-assisted multi-needle electrospinning of nanofibers[J]. Advanced Composites and Hybrid Materials, 2019, 3(1): 98-113.
[15] 周兴海. 气电纺制备中空CeO2/Al2O3超细纤维及其染料吸附性能研究[D]. 天津: 天津工业大学, 2016: 19-20.
ZHOU Xinghai. Preparation of hollow CeO2/Al2O3 microfibers by electro-blown spinning and dye adsorption properties[D]. Tianjin:Tiangong University, 2016: 19-20.
[16] 房飞宇, 陈新, 王晗, 等.一种基于负压收集的气电纺三维支架制备方法及装置: 201510779113.0[P]. 2017-12-26.
FANG Feiyu, CHEN Xin, WANG Han, et al. Preparation method and device for a electro-blown spinning three-dimensional support based on negative pressure collection: 201510779113.0[P]. 2017-12-26.
[17] 房飞宇, 王晗, 陈新, 等.一种大量制备三维纳米纤维支架的离心气电纺装置: 201510780518.6 [P]. 2018-05-22.
FANG Feiyu, WANG Han, CHEN Xin, et al. A centrifugal electro-blown spinning device for preparing a large number of three-dimensional nanofiber scaffolds: 201510780518.6 [P]. 2018-05-22.
[18] 徐寅踊, 赵炳光, 徐尚哲, 等. 用于电纺丝的射出喷嘴及使用该射出喷嘴的电纺丝装置: 201080031458.3 [P]. 2015-07-01.
XU Yinyong, ZHAO Bingguang, XU Shangzhe, et al. An injection nozzle for electrospinning and device using the injection nozzle: 201080031458.3[P]. 2015-07-01.
[19] SINHA-RAY Suman, LEE M W, SINHA-RAY Sunit, et al. Supersonic nanoblowing: a new ultra-stiff phase of nylon 6 in 20-50 nm confinement[J]. Journal of Materials Chemistry C, 2013, 1(21): 3491-3498.
[20] 侯豪情, 程楚云. 高速气流和高压静电生产聚合物纳米纤维的方法及装置: 201410667969.4[P]. 2017-02-22.
HOU Haoqing, CHENG Chuyun. Method and device for producing polymer nanofibers by high-speed air flow and high pressure electrostatic: 201410667969.4[P]. 2017-02-22.
[21] LIU Y, WEN J, CHEN B, et al. Electro-blown spinning driven by cylindrical rotating triboelectric nanogenerator and its applications for fabricating nanofibers[J]. Applied Materials Today, 2020. DOI: 10.1016/j.apmt.2020.100631.
[22] LI L, LIU X, WANG G, et al. Research progress of ultrafine alumina fiber prepared by sol-gel method: a review[J]. Chemical Engineering Journal, 2021. DOI: 10.1016/j.cej.2020.127744.
[23] ZHENG G, JIANG J, WANG X, et al. Nanofiber membranes by multi-jet electrospinning arranged as arc-array with sheath gas for electrodialysis applications[J]. Materials & Design, 2020. DOI: 10.1016/j.matdes.2020.108504.
[24] 王鹏. 基于喷气静电纺纳米纤维成纱机理及纺纱关键设备研究[D]. 西安: 西安工程大学, 2016: 12-45.
WANG Peng. Research on formation mechanism and key spinning equipment of nano-fibre yarn based on air-jet electrospun[D]. Xi'an: Xi'an Polytechnic University, 2016: 12-45.
[25] POKORNY M, RASSUSHIN V, WOLFOVA L, et al. Increased production of nanofibrous materials by electroblowing from blends of hyaluronic acid and polyethylene oxide[J]. Polymer Engineering and Science, 2016, 56(8): 932-938.
[26] GAO Y, ZHANG J, SU Y, et al. Recent progress and challenges in solution blow spinning[J]. Materials Horizons, 2021, 8(2): 426-446.
doi: 10.1039/d0mh01096k pmid: 34821263
[27] KHAYET M, GARCÍA-PAYO M C, QUSAY F A, et al. Effects of gas gap type on structural morphology and performance of hollow fibers[J]. Journal of Membrane Science, 2008, 311(1): 259-269.
[28] WANG B, YAO Y, PENG J, et al. Preparation of poly(ester imide) ultrafine fibers by gas-jet/electro-spinning[J]. Journal of Applied Polymer Science, 2009, 114(2): 883-891.
[29] KONG C S, YOO W S, LEE K Y, et al. Nanofiber deposition by electroblowing of PVA (polyvinyl alcohol)[J]. Journal of Materials Science, 2009, 44(4): 1107-1112.
[30] CAO L, LIU Q, REN J, et al. Electro-blown spun silk/graphene nanoionotronic skin for multifunctional fire protection and alarm[J]. Advanced Materials, 2021. DOI: 10.1002/adma.202102500.
[31] LI L, KANG W, ZHUANG X, et al. A comparative study of alumina fibers prepared by electro-blown spinning (EBS) and solution blowing spinning (SBS)[J]. Materials Letters, 2015, 160: 533-536.
[32] ZHOU X H, LI L, LI Z H, et al. The preparation of continuous CeO2/CuO/Al2O3 ultrafine fibers by electro-blowing spinning (EBS) and its photocatalytic act-ivity[J]. Journal of Materials Science: Materials in Electronics, 2017, 28(17): 12580-12590.
[33] LI L, REN H, LIU Y, et al. Facile construction of hierarchical porous ultrafine alumina fibers (HPAFs) and its application for dye adsorption[J]. Microporous and Mesoporous Materials, 2020. DOI: 10.1016/j.micromeso.2020.110544.
[34] ZHOU X H, KANG W M, XU W, et al. Flexible hollow CeO2/Al2O3 fibers: preparation, characterization and dye adsorption efficiency[J]. RSC Advances, 2015, 5(103): 84535-84542.
[35] ZHANG Y, GAO L, DENG N, et al. Fabrication of porous and magnetic Fe/FeNX fibers by electro-blown spinning method for efficient adsorption of Cr (VI) ions[J]. Materials Letters, 2018, 212: 235-238.
[36] 李磊, 程博闻, 康卫民, 等. 静电溶液喷射Fe2O3/Al2O3超细纤维负载型光催化剂的制备及催化性能研究[J]. 材料导报, 2018, 32(2): 207-212.
LI Lei, CHENG Bowen, KANG Weimin, et al. Fe2O3 photocatalyst supported on ultra-fine fibrous Al2O3 prepared via electro-blown spinning (EBS) with an application to organic dye degradation[J]. Materials Reports, 2018, 32(2): 207-212.
[37] ZHOU X H, SONG K H, LI Z H, et al. The excellent catalyst support of Al2O3 fibers with needle-like mullite structure and HMF oxidation into FDCA over CuO/Al2O3 fibers[J]. Ceramics International, 2019, 45(2): 2330-2337.
[38] HOLOPAINEN J, RITALA M. Rapid production of bioactive hydroxyapatite fibers via electroblowing[J]. Journal of the European Ceramic Society, 2016, 36(13): 3219-3224.
[39] GUAN D, CHEN Z, HUANG C, et al. Attachment, proliferation and differentiation of BMSCs on gas-jet/electrospun nHAP/PHB fibrous scaffolds[J]. Applied Surface Science, 2008, 255(2): 324-327.
[40] MANDAKHBAYAR N, EL-FIQI A, DASHNYAM K, et al. Feasibility of defect tunable bone engineering using electroblown bioactive fibrous scaffolds with dental stem cells[J]. ACS Biomaterials Science & Engineering, 2018, 4(3): 1019-1028.
[41] 范兰兰. 锂硫电池正极用多孔碳纤维制备及电化学性能的研究[D]. 天津: 天津工业大学, 2018: 17-47.
FAN Lanlan. Study on preparation and electrochemical properties of porous carbon fiber for cathode of lithium-sulfur battery[D]. Tianjin: Tiangong University, 2018: 17-47.
[42] DENG N, KANG W, JU J, et al. Polyvinyl alcohol-derived carbon nanofibers/carbon nanotubes/sulfur electrode with honeycomb-like hierarchical porous structure for the stable-capacity lithium/sulfur batte-ries[J]. Journal of Power Sources, 2017, 346: 1-12.
[43] JU J, LV Y, WANG L, et al. The construction of Fe-compounds doped porous carbon nanofiber and carbon nanotube composite material by one-step carbonization and CVD for Li-ion capacitor[J]. Journal of The Electrochemical Society, 2019, 166: A1223-A1230.
[44] 周兴海. 多孔碳纤维基锂离子电池负极材料的设计、构筑与性能研究[D]. 天津: 天津工业大学, 2020: 27-49.
ZHOU Xinghai. Design, construction and properties of porous carbon fiber based cathode material for lithium ion batteries[D]. Tianjin: Tiangong University, 2020: 27-49.
[45] ZHOU X H, GAO Y, LYU L H, et al. General construction of molybdenum-based compounds embedded in flexible 3-D interconnected porous carbon nanofibers with protective porous shell for high-performance lithium-ion battery[J]. Carbon, 2021, 179: 142-150.
[46] JU J, ZHAO H, KANG W, et al. Designing MnO2 & carbon composite porous nanofiber structure for supercapacitor applications[J]. Electrochimica Acta, 2017, 258: 116-123.
[47] WANG L, JU J, DENG N, et al. Embedding red phosphorus in hierarchical porous carbon nanofibers as anodes for lithium-ion battery[J]. Materials Letters, 2019, 240: 39-43.
[48] ZHOU X H, WANG Y F, ZHU L, et al. Metal sulfide nano-frameworks anchored into 3D honeycomb-like porous carbon nanofibers as freestanding anodes for high performance lithium-ion batteries[J]. Applied Surface Science, 2022. DOI: 10.1016/j.apsusc.2022.153627.
[49] WEI L Y, DENG N P, JU J G, et al. ZnF2 doped porous carbon nanofibers as separator coating for stable lithium-metal batteries[J]. Chemical Engineering Journal, 2021. DOI: 10.1016/j.cej.2021.130346.
[50] WEI L, DENG N, ZHAO H, et al. ZnF2/ZnS heterostructures@NC doped porous carbon nanofibers as interlayers for stable lithium metal anodes[J]. Composites Part B: Engineering, 2022. DOI: 10.1016/j.compositesb.2021.109531.
[51] QIN Q, DENG N, WANG L, et al. Novel flexible Mn-based carbon nanofiber films as interlayers for stable lithium-metal battery[J]. Chemical Engineering Journal, 2019, 360: 900-911.
[52] LIU M, DENG N, JU J, et al. Silver nanoparticle-doped 3D porous carbon nanofibers as separator coating for stable lithium metal anodes[J]. ACS Applied Materials & Interfaces, 2019, 11(19): 17843-17852.
[53] LIANG Y, KANG W, ZHONG C, et al. Multifunctional LaF3 doped pomegranate-like porous carbon nanofibers with high-speed transfer channel and strong polar interface for high stability lithium sulfur battery[J]. Chemical Engineering Journal, 2021. DOI: 10.1016/j.cej.2020.126449.
[54] DENG N, JU J, YAN J, et al. CeF3-doped porous carbon nanofibers as sulfur immobilizers in cathode material for high-performance lithium-sulfur batteries[J]. ACS Applied Materials & Interfaces, 2018, 10(15): 12626-12638.
[55] 郝言. 金属氟化物掺杂多孔碳纳米纤维/硫电极的制备及性能研究[D]. 天津: 天津工业大学, 2020: 45-57.
HAO Yan. Preparation and properties of metal fluoride-doped porous carbon nanofiber/sulfur electrode[D]. Tianjin: Tiangong University, 2020: 45-57.
[56] CAO L, ZHOU X, LI Z, et al. Nitrogen and fluorine hybridization state tuning in hierarchical honeycomb-like carbon nanofibers for optimized electrocatalytic ORR in alkaline and acidic electrolytes[J]. Journal of Power Sources, 2019, 413: 376-383.
[57] 康卫民, 汪港, 高红静, 等.一种电催化用铜团簇增强蜂窝多孔碳纳米纤维的合成方法: 202210830032.9[P]. 2022-11-22.
KANG Weimin, WANG Gang, GAO Hongjing, et al. A synthesizing method for porous carbon nanofibers reinforced with copper clusters for electrocatalysis: 202210830032.9[P]. 2022-11-22.
[58] LIU W, WANG L, LUO Y, et al. An alumina/polyacrylonitrile nanofibrous composite separator via high-efficiency electro-blown spinning and wet-laid technologies for improved lithium-ion batteries[J]. Journal of The Electrochemical Society, 2019, 166(16): A4088-A4096.
[59] LIU W, JU J, DENG N, et al. Designing inorganic-organic nanofibrous composite membrane for advanced safe Li-ion capacitors[J]. Electrochimica Acta, 2020. DOI: 10.1016/j.electacta.2020.135821.
[60] KANG J, YAN Z, GAO L, et al. Improved ionic conductivity and enhanced interfacial stability of solid polymer electrolytes with porous ferroelectric ceramic nanofibers[J]. Energy Storage Materials, 2022, 53: 192-203.
[61] YU W, DENG N, SHI D, et al. One-dimensional oxide nanostructures possessing reactive surface defects enabled a lithium-rich region and high-voltage stability for all-solid-state composite electrolytes[J]. ACS Nano, 2023, 17: 22872-22884.
doi: 10.1021/acsnano.3c07754 pmid: 37947375
[62] JIA C, XU Z, LUO D, et al. Flexible ceramic fibers: recent development in preparation and application[J]. Advanced Fiber Materials, 2022, 4(4): 573-603.
[1] 于承浩, 王元非, 于腾波, 吴桐. 热致自卷曲左旋聚乳酸/聚乳酸-羟基乙酸共聚物纳米纤维血管支架制备及其性能[J]. 纺织学报, 2024, 45(07): 18-23.
[2] 刘思彤, 金丹, 孙东明, 李懿轩, 王艳慧, 王静, 王原. 静电纺纳米纤维结构的研究进展[J]. 纺织学报, 2024, 45(06): 201-209.
[3] 徐振凯, 马鸣, 蔺多佳, 刘航, 张剑峰, 夏鑫. 自支撑聚吡咙基碳纤维负极材料的制备及其电化学性能[J]. 纺织学报, 2024, 45(06): 23-31.
[4] 时吉磊, 陈廷彬, 付少海, 张丽平. 低红外发射率控温热红外伪装材料的制备与性能[J]. 纺织学报, 2024, 45(06): 32-38.
[5] 栗志坤, 于影, 左雨欣, 史豪秦, 金玉珍, 陈洪立. 聚丙烯腈/二硫化钼复合薄膜的挠曲电效应分析及其应用[J]. 纺织学报, 2024, 45(05): 27-34.
[6] 梁文静, 吴俊贤, 何崟, 刘皓. 基于复合纳米纤维膜的离子传感器制备及其性能[J]. 纺织学报, 2024, 45(04): 15-23.
[7] 宋贝贝, 赵浩阅, 李欣宇, 屈展, 方剑. 载有MXene的钴氮掺杂碳纳米纤维在锂硫电池中的应用[J]. 纺织学报, 2024, 45(04): 24-32.
[8] 贾琳, 董晓, 王西贤, 张海霞, 覃小红. 聚己内酯/MgO复合纳米纤维膜的制备及其性能[J]. 纺织学报, 2024, 45(04): 59-66.
[9] 陆瑶瑶, 叶俊涛, 阮承祥, 娄瑾. 二氧化钛/多孔碳纳米纤维复合材料的制备及其光催化性能[J]. 纺织学报, 2024, 45(04): 67-75.
[10] 杨琪, 邓南平, 程博闻, 康卫民. 树枝状磺化聚醚砜纤维基复合固态电解质的制备及其性能[J]. 纺织学报, 2024, 45(03): 1-10.
[11] 赵美奇, 陈莉, 钱现, 李晓娜, 杜迅. 用于铜离子检测的静电纺纤维膜制备及其性能[J]. 纺织学报, 2024, 45(03): 11-18.
[12] 田博阳, 王向泽, 杨湙雯, 吴晶. 非对称结构纤维膜的制备及其热调控性能[J]. 纺织学报, 2024, 45(02): 11-20.
[13] 周歆如, 范梦晶, 岳欣琰, 洪剑寒, 韩潇. 导电微纳纤维复合纱的制备及其气敏特性[J]. 纺织学报, 2024, 45(02): 52-58.
[14] 戎成宝, 孙辉, 于斌. 银-铜双金属纳米粒子/聚乳酸复合纳米纤维膜的制备及其抗菌性能[J]. 纺织学报, 2024, 45(01): 48-55.
[15] 陈江萍, 郭朝阳, 张琪骏, 吴仁香, 钟鹭斌, 郑煜铭. 静电纺聚酰胺6/聚苯乙烯复合纳米纤维膜制备及其空气过滤性能[J]. 纺织学报, 2024, 45(01): 56-64.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发