纺织学报 ›› 2011, Vol. 32 ›› Issue (1): 67-72.

• 染整与化学品 • 上一篇    下一篇

低熔点皮芯复合纤维分散染料染色机制

丁飞飞1;汪澜1;林俊雄2   

  1. 1. 浙江理工大学先进纺织材料与制备技术教育部重点实验室 2. 浙江理工大学生态染整技术教育部工程研究中心
  • 收稿日期:2010-01-15 修回日期:2010-05-28 出版日期:2011-01-15 发布日期:2011-01-15
  • 通讯作者: 汪澜

Dyeing mechanism of disperse dye on bi-component sheath-core fiber with low melting point

DING Feifei1;WANG Lan1;LIN Junxiong2   

  1. 1.Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University 2.Engineering Research Center for Ecp-Dyeing and Finishing of Textiles, Zhejiang Sci-Tech University, Ministry of Education
  • Received:2010-01-15 Revised:2010-05-28 Online:2011-01-15 Published:2011-01-15

摘要:

以低熔点皮芯复合纤维为主要研究对象,用2种典型结构的分散染料——分散红玉SE-GFL(偶氮型)和分散蓝2BLN(蒽醌型)对其进行染色,研究低熔点皮芯复合纤维分散染料染色动力学和热力学。实验结果表明:分散染料上染低熔点皮芯复合纤维的吸附等温线与分散染料上染普通聚酯纤维一样,都符合Nernst分配型;与普通聚酯纤维分散染料染色相比,分散染料在低熔点皮芯复合纤维上的染色速率常数大大增加,半染时间缩短,扩散系数增大,染色亲和力增加,染色热和染色熵降低。

Abstract:

The paper took bi-component sheath-core fiber with low melting point as the main research object. Two typical disperse dyes such as Disperse Red SE-GFL( azo ) and Disperse Blue 2BLN(anthraquinone) were used to dye the fiber. The dyeing kinetics and dyeing thermodynamics of disperse dye on the bi-component sheath-core fiber with low melting point were studied as well. The results showed that the type of adsorption isotherm of disperse dye on bi-component sheath-core fiber with low melting point was the same as that on conventional polyester fiber, both of which are conforming with Nernst distribution mechanism. Compared with dyeing with disperse dye on the conventional polyester fiber, dyeing with disperse dye on the bi-component sheath-core fiber has some features, i.e. the dyeing rate increases greatly, half-dyeing time decreases, diffusion coefficient and dyeing affinity enhance, dyeing heat and dyeing entropy reduce.

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