聚酯/聚苯胺复合织物化学镀铜效果的影响因素

纺织学报 ›› 2011, Vol. 32 ›› Issue (7): 99-105.

聚酯/聚苯胺复合织物化学镀铜效果的影响因素

符晓兰¹,赵亚萍²,蔡再生²

1. 上海东华大学化学化工与生物工程学院
2. 东华大学

收稿日期:2010-07-26 修回日期:2010-11-30 出版日期:2011-07-15 发布日期:2011-09-15
通讯作者: 符晓兰 E-mail:fu123lan@126.com
基金资助:
国家级

The Study on electroless of copper on polyester/polyaniline composite fabric with ultrasonic

Received:2010-07-26 Revised:2010-11-30 Online:2011-07-15 Published:2011-09-15

摘要/Abstract

摘要： 利用超声辅助化学镀方法在聚酯/聚苯胺复合织物表面均匀沉积了金属铜。探讨了聚苯胺的沉积条件、化学镀工艺中敏化和活化条件以及超声辅助对复合织物方阻、增重率及结合性能等方面的影响。通过浸泡法和阳极极化法比较了聚酯/聚苯胺、聚酯/铜和聚酯/聚苯胺/铜三种复合织物的耐腐蚀性能。利用扫描电镜对不同织物的表观形貌进行表征，同时探讨了超声对铜在织物表面分布的影响。结果表明，以聚苯胺作为中间导电层，可以降低金属化织物的方阻的同时提高金属与基质之间的结合性能以及导电复合织物的耐腐蚀性能，超声波的引入有效促进了金属粒子在复合织物表面的均匀沉积。

Abstract: Polyester/polyaniline composit fabric were metallized through electroless plating of copper uniformly with the ultrasonic. The effects of depositing conditions of polyaniline, the sensitization and the activation condition of the electroeless plating and ultrasonic on the square resistance surface resistivity, the weight gain rate of PANI and fastness were discussed. The corrosion resistance of polyester/polyaniline, the polyester/copper and the polyester/polyaniline/copper composite fabric were compared by dipping and anodic polarization.The surface properties of the different samples were characterized by scanning electron microscope (SEM). It was indicated that the intermediate polyaniline layers can reduce square resistance of the metallized fabric, at the same time enhanced bond properties between the metal and fabric and increase the corrosion resistance of conductive composite fabric. Also, the ultrasonic can promote copper depositing on the surface of composite fabric uniformly.

中图分类号:

TS195.5

符晓兰赵亚萍蔡再生. 聚酯/聚苯胺复合织物化学镀铜效果的影响因素[J]. 纺织学报, 2011, 32(7): 99-105.

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