纺织学报 ›› 2012, Vol. 33 ›› Issue (6): 48-52.

• 染整与化学品 • 上一篇    下一篇

添加剂/超细包覆分散染料液滴形成的影响因素

 张桂芳, 付少海, 田安丽, 张霞, 王潮霞   

  1. 生态纺织教育部重点实验室(江南大学)
  • 收稿日期:2011-08-15 修回日期:2012-01-09 出版日期:2012-06-15 发布日期:2012-06-04
  • 通讯作者: 付少海 E-mail:shaohaifu@hotmail.com

Study on droplets formation process of additives/capsulated super-fine disperse dye

 ZHANG  Gui-Fang, FU  Shao-Hai, TIAN  An-Li, ZHANG  Xia, WANG  Chao-Xia   

  1. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education
  • Received:2011-08-15 Revised:2012-01-09 Online:2012-06-15 Published:2012-06-04

摘要: 以苯乙烯-马来酸共聚物为壁材,采用相分离技术对分散染料蓝60进行包覆,制备超细包覆分散染料。探讨了甘油、吐温80用量对超细分散染料胶体性质的影响,在选择合适的黏度、表面张力和一定稳定性的基础上,进而分析了影响液滴形成的因素。红外光谱和透射电镜测试结果表明本研究成功制备了超细包覆分散染料。胶体性质研究表明超细分散染料和甘油的的用量越多,体系黏度越大,吐温80可降低体系表面张力,而三者均会影响体系的稳定性。分析液滴形成过程发现黏度增加,表面张力减少,液滴更容易分离,而且表面张力越小,液滴形成的最大体积越小,黏度是影响“卫星液滴”形成和滴落的主要因素,黏度较低时,“卫星液滴”较易形成,且不易与主液滴重合。

关键词: 超细包覆分散染料 , 添加剂 , 黏度 , 表面张力 , 液滴

Abstract: The capsulated super-fine disperse dye was prepared by phase separation technique with styrene maleic copolymer. The effects of glycerin and Tween 80 content on colloidal properties of super-fine disperse dye were investigated, and then discussing the effect factors of droplets formation process based on suitable viscosity, surface tension and certain stability. The FTIR and TEM results showed that capsulated super-fine disperse dye was prepared successfully. Capsulated super-fine disperse dye and glycerin could improve viscosity and Tween 80 could greatly affect surface tension. Besides, they could affect storage stability of the dispersion. Either viscosity increasing or surface tension reducing made the droplets break easily. In addition, decreasing surface tension could lead to droplet’s maximum volume smaller. Viscosity might be the main factor of “satellite droplet” why formed. Especially, when viscosity was lower the “satellite droplet” was more obvious, coinciding with the lord droplets more difficultly.

Key words: capsulated super-fine disperse dye , additive , viscosity , surface tension , droplet

中图分类号: 

  • TS 194.4
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