三聚氰胺氰尿酸盐对阻燃PET的影响

纺织学报 ›› 2012, Vol. 33 ›› Issue (11): 20-26.

三聚氰胺氰尿酸盐对阻燃PET的影响

梁科文,王锐,朱志国,董振峰

北京服装学院材料科学与工程学院

收稿日期:2011-10-17 修回日期:2012-02-15 出版日期:2012-11-15 发布日期:2012-11-20
通讯作者: 王锐 E-mail:wangrui166@sohu.com
基金资助:
北京市人才强教计划—高层次人才项目

Influence of melamine cyanurate on flame retardancy of poly(ethylene terephthalate)

Received:2011-10-17 Revised:2012-02-15 Online:2012-11-15 Published:2012-11-20

摘要/Abstract

摘要： 使用三聚氰胺氰尿酸盐（MCA）分别与聚对苯二甲酸乙二醇酯（PET）及含磷共聚酯（CP-PET）合成PET-MCA复合物和CP-PET-MCA复合物。借助TGA、LOI、垂直燃烧仪（UL-94）、锥形量热仪、SEM和EDS等测试方法对其热稳定性、阻燃性能和成炭情况等进行研究，并初步分析了其作用机理。研究结果表明，PET-MCA复合物和CP-PET-MCA复合物的初始热分解温度有所降低，燃烧后残炭量提高，极限氧指数（LOI）有所提高，并且CP-PET-MCA复合物在UL-94测试中达到V-0级标准，成炭情况良好，MCA与2-羧乙基苯基次膦酸（CPEEA）复合使用对PET具有一定的氮-磷协效阻燃作用。

关键词: 含磷共聚酯, 三聚氰胺氰尿酸盐, 氮-磷协效, 阻燃性能

Abstract: PET-MCA composites (PET-MCA) and phosphorus-contanining poly(ethylene terephthalate) (CP-PET)-MCA composites (CP-PET-MCA ) were prepared by melamine cyanurate (MCA) and poly(ethylene terephthalate) (PET) and CP-PET. The thermal stability, flame retardancy and char forming characteristics of the product were investigated by TGA, LOI, UL-94, Cone Calorimeter, SEM and EDS, and the mechanism were discussed. The result suggested that the temperature of thermal decomposition of PET and CP-PET showed a slight decrease with the incorporation of MCA, and the mass of residual char and LOI increased. CP-PET reached V-0 rating standard from UL-94 test and more uniform char granules were acquired. The addition of MCA compounded with 2-carboxyethyl(phenylphosphinic) acid (CEPPA) imparted N-P synergism effect on the flame retardancy of PET.

Key words: phosphorus-containing poly(ethylene terephthalate), melamine cyanurate, N-P synergism, flame retardancy

中图分类号:

342.29

梁科文王锐朱志国董振峰. 三聚氰胺氰尿酸盐对阻燃PET的影响[J]. 纺织学报, 2012, 33(11): 20-26.

参考文献

相关文章 9

[1]	邓继勇柳芊董新理汪南方. 新型氮-磷阻燃剂制备及其对棉织物的阻燃性能[J]. 纺织学报, 2017, 38(11): 97-101.
[2]	陈威关晋平陈国强匡小慧. 静电层层自组装法整理多巴胺改性涤/棉混纺织物的阻燃性能[J]. 纺织学报, 2017, 38(09): 94-100.
[3]	王志伟齐鲁. 采用1-膦酸丙烷-1，2-二羧酸的羽绒纤维阻燃改性[J]. 纺织学报, 2015, 36(10): 7-0.
[4]	楼利琴励宏黄锐镇. 不同混纺比芳纶、芳砜纶隔热层水刺非织造布性能分析[J]. 纺织学报, 2013, 34(6): 46-50.
[5]	吕丽华刘桂彬孙艳丽. 阻燃型玄武岩织物/聚乳酸复合材料的研制[J]. 纺织学报, 2013, 34(1): 20-24.
[6]	季涛, 李杰, 高强, 余进, 刘其霞. 粘胶基炭化织物的制备及工艺优化[J]. 纺织学报, 2012, 33(4): 49-54.
[7]	李明月;张天骄. 聚醚醚酮织物的阻燃性能[J]. 纺织学报, 2010, 31(1): 91-95.
[8]	杜兆芳;刘晓华;宋雷;程贤生. 大麻纤维针刺毡的阻燃性能分析[J]. 纺织学报, 2009, 30(08): 64-68.
[9]	郑振荣;顾振亚;杨文芳;王乐军. 织物结构对安芙赛纺织品阻燃性能的影响[J]. 纺织学报, 2009, 30(02): 56-60.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed