溶胶-凝胶法在玻璃纤维表面制备锑掺杂二氧化锡薄膜的工艺

纺织学报 ›› 2013, Vol. 34 ›› Issue (11): 11-0.

溶胶-凝胶法在玻璃纤维表面制备锑掺杂二氧化锡薄膜的工艺

李明超^1,2,张毅^1,2

1. 天津工业大学纺织学部
2. 天津工业大学先进纺织复合材料教育部重点实验室

收稿日期:2012-11-19 修回日期:2013-07-23 出版日期:2013-11-15 发布日期:2013-11-07
通讯作者: 张毅 E-mail:tianjinzhangyi@126.com

Process for preparing Sb-doped tin dioxide film on surface of glass fiber by sol-gel method

Received:2012-11-19 Revised:2013-07-23 Online:2013-11-15 Published:2013-11-07

摘要/Abstract

摘要： 在热处理条件和掺锑的质量比例不同的情况下，对玻璃纤维的表面进行锑掺杂二氧化锡（ATO）镀膜处理，进而测得纤维比电阻值。采用田口实验法对实验数据进行优化分析，并探讨了初始SnCl4浓度、热处理温度、处理时间、掺杂比例对实验结果的影响程度。使用扫描式电子显微镜（SEM）对比观察了玻璃纤维表面结构在处理前后的差异。实验表明：ATO镀膜处理后的玻璃纤维，导电性能明显增强；最优工艺条件是热处理温度50℃，掺杂比例0.9%,热处理时间1.5h，初始SnCl4浓度0.8mol/L，且因子影响程度依次递减。

关键词: ATO薄膜, 溶胶-凝胶法, 田口实验法, 玻璃纤维

Abstract: In case of different heat treatment conditions and the mass ratio of antimony-doped, fiber specific resistance value was measured after the Sb- doped tin dioxide (ATO) coating process on the surface of the glass fiber. Taguchi method, which explored influence degree of the initial concentration, heat treatment temperature, treatment time and doping mass ratio on the experimental results, was used to optimize and analyze the experimental data. After the treatment, differences were contrastively observed by scanning electron microscopy (SEM). It shows that the conductive property of the glass fiber is significantly enhanced. Moreover, the obtained optimum condition is 450℃ of heat treatment temperature, 0.9% of doping mass ratio, 1.5 h of heat treatment time and 0.8mol / L of initial concentration. Furthermore, the influence is in descending order.

Key words: ATO film, sol-gel method, Taguchi method, glass fiber

中图分类号:

TS 151

李明超张毅. 溶胶-凝胶法在玻璃纤维表面制备锑掺杂二氧化锡薄膜的工艺[J]. 纺织学报, 2013, 34(11): 11-0.

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