基于固相萃取-液相色谱-串联质谱法的纺织品中三氯生和三氯卡班的测定

纺织学报 ›› 2014, Vol. 35 ›› Issue (4): 71-0.

基于固相萃取-液相色谱-串联质谱法的纺织品中三氯生和三氯卡班的测定

韩超¹ 黄芙珍¹ 李舟¹ 朱振瓯¹ 顾学峰² 沈燕²

1. 温州出入境检验检疫局
2. 温州大学化学与材料工程学院

收稿日期:2013-04-15 修回日期:2013-07-22 出版日期:2014-04-15 发布日期:2014-04-14
通讯作者: 沈燕 E-mail:shenyan@wzu.edu.cn
基金资助:
国家级公益性行业科研专项

Determination of triclosan and triclocarban in textiles by solid-phase extraction and liquid chromatography wave-mass spectrometry tandem

Received:2013-04-15 Revised:2013-07-22 Online:2014-04-15 Published:2014-04-14

摘要/Abstract

摘要： 采用固相萃取-液相色谱-串联质谱技术(SPE-LC-MS/MS)建立了同时测定纺织品中三氯生和三氯卡班的分析方法。样品用二氯甲烷超声提取，C18固相萃取净化后分析。串联质谱在多反应监测(MRM)模式下检测目标分析物，以保留时间和特征离子对(母离子和碎片离子)信息比较进行定性和定量分析。三氯生和三氯卡班的线性范围分别为1.0~50.0 ng/mL、0.25~50.0 ng/mL。方法的定量限为1.0和0.25 μg/kg，平均回收率为84.5% ~ 108.2 %，相对标准偏差小于8.1 %。实验结果表明该方法准确、灵敏，可用于纺织品中三氯生和三氯卡班的分析测定。

关键词: 液相色谱-串联质谱, 固相萃取, 三氯生, 三氯卡班

Abstract: A method for the determination of triclosan and triclocarban in textiles was developed by solid phase extraction and liquid chromatography-tandemed mass spectrometry (SPE-LC-MS/MS). The sample was extracted with dichloromethane by ultrasonic and clean-up on a C18 SPE cartridge. The analyte was determined by an electrospray ionization tandem mass spectrometry in multiple reactions monitoring (MRMs) mode. The qualitative and quantitative analyses was based on the retention times and characteristic ion pairs consisting of one parent ion and fragment ions of the analyte. Linearities in the range of 1.0~50.0 ng/mL and 0.25~50.0 ng/mL for triclosan and triclocarban, respectively. The limits of quantification (LOQs) for triclosan and triclocarban were 1.0 and 0.25 μg/kg, respectively, the average recoveries were in the range of 84.5% ~ 108.2 % with the relative standard deviations below 8.1 %. This method is accurate and sensitive, and it is suitable for the analysis of triclosan and triclocarban in textiles.

Key words: liquid chromatography-tandemed mass spectrometry, solid-phase extraction, triclosan, triclocarban, textiles

中图分类号:

TS 190.2

韩超黄芙珍李舟朱振瓯顾学峰沈燕. 基于固相萃取-液相色谱-串联质谱法的纺织品中三氯生和三氯卡班的测定[J]. 纺织学报, 2014, 35(4): 71-0.

参考文献

相关文章 9

[1]	吴刚王力君张明誉郭方龙赵珊红. 涤纶中致癌芳香胺的加速溶剂萃取－UPLC-MS/MS快速测定[J]. 纺织学报, 2014, 35(7): 94-0.
[2]	芦春梅牟峻周博宇张晓燕李墨浠. 基于液相色谱-串联质谱法纺织品中三氯生的普查分析[J]. 纺织学报, 2014, 35(5): 87-0.
[3]	李志刚. 固相萃取-高效液相色谱法测定纺织品中富马酸二甲酯[J]. 纺织学报, 2014, 35(4): 75-0.
[4]	李志刚. 基于固相萃取-高效液相色谱法的纺织品中三氯生的测定[J]. 纺织学报, 2014, 35(3): 98-0.
[5]	顾义师, 谢玲玲, 邵彩英, 高卫东, 黄丹. 三氯卡班/聚乳酸超细纤维的制备及抗菌性能[J]. 纺织学报, 2012, 33(7): 1-5.
[6]	黄惠玲, 王玉健, 陈晓兰, 黄海民, 何志贵. 纺织品中甲醛的快速检测方法[J]. 纺织学报, 2012, 33(3): 98-101.
[7]	丁友超;曹锡忠;蔡建和;周佳;钱凯. 纺织品中有害分散染料的细粒径柱液相色谱-光谱-质谱检测技术[J]. 纺织学报, 2011, 32(1): 89-95.
[8]	孙忠松;王境堂;高永刚;蔡发. 基于气相色谱-离子阱法的纺织品及皮革中的富马酸二甲酯检测[J]. 纺织学报, 2010, 31(2): 73-76.
[9]	牛增元;房丽萍.;杨桂朋;薛秋红;王境堂;孙忠松. 纺织品中邻苯二甲酸酯类环境激素在人工汗液中的迁移[J]. 纺织学报, 2006, 27(2): 74-77.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed