纺织学报 ›› 2015, Vol. 36 ›› Issue (09): 75-81.

• 染整与化学品 • 上一篇    下一篇

转移印花增稠剂的流变性与微观形貌

  

  • 收稿日期:2014-09-26 修回日期:2015-04-16 出版日期:2015-09-15 发布日期:2015-09-14

Rheology and morphology of thickeners in textile transfer printing

  • Received:2014-09-26 Revised:2015-04-16 Online:2015-09-15 Published:2015-09-14

摘要:

以转移印花纸涂层改性用增稠剂高取代羟丙基纤维素(H-HPC)和羧甲基纤维素钠(CMC)为研究对象,采用稳态剪切和频率扫描相结合的方法研究了H-HPC、CMC溶液的流变性及其共混溶液在不同环境中的相容性,并利用光学和原子力显微镜对H-HPC、CMC和糊料膜的微观形貌进行观测。研究表明:CMC的结构粘度高于H-HPC并体现出更明显的假塑性和触变性;随着H-HPC或CMC含量的增加,溶液的弹性增强且粘性减弱;酸性、弱碱性以及尿素对H-HPC/CMC溶液的表观粘度和黏弹性影响不大;在80 ℃以上干燥时,可获得H-HPC和CMC共混均匀且表面平整的糊料膜。

Abstract:

The subjects in this study were high-substituted hydroxypropyl cellulose (H-HPC) and carboxymethyl cellulose (CMC) used as the thickeners in the textile transfer printing. The rheology of H-HPC, CMC and the compatibility of H-HPC/CMC blend solution under the different conditions were investigated using the methods of steady-shear and frequency sweep, meanwhile, the micro-morphology of H-HPC, CMC and paste films were observed using optical and atomic force microscopes. Results show that: CMC has a higher structural viscosity and exhibits more obvious pseudo-plastic characteristic and thixotropy; the two thickeners both display an increasing elasticity and a decreasing viscous with the promotion of solid content; acidic, weakly alkali and urea have little influence on the apparent viscosity and viscoelasticity of H-HPC/CMC blend solution; the distribution of H-HPC and CMC in the paste film is uniform and the surface of the paste film is flat when drying at over 80℃.

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