纺织学报 ›› 2015, Vol. 36 ›› Issue (10): 73-79.

• 染整与化学品 • 上一篇    下一篇

废旧棉织物活性炭的制备与性能

  

  • 收稿日期:2014-08-21 修回日期:2014-12-28 出版日期:2015-10-15 发布日期:2015-10-12

Preparation and properties of activated carbon from waste cotton fabrics

  • Received:2014-08-21 Revised:2014-12-28 Online:2015-10-15 Published:2015-10-12

摘要:

以日常生活中废旧棉织物(WCF)为原料,采用氯化锌法活化制备了废旧棉织物活性炭(AC-WCF),考察了氯化锌质量分数ω、氯化锌浸渍时间t1、活化温度T和活化时间t2四个因素对AC-WCF吸附性能的影响。采用比表面积及微孔/中孔分析仪、扫描电镜(SEM)和红外光谱仪(FT-IR)对AC-WCF样品进行表征。结果表明,AC-WCF各项吸附性能良好,最佳制备工艺为:ω=45%,t1=16 h,T=700℃,t2=30 min,该条件下制备的AC-WCF的BET比表面积高达1462 m2/g,总孔容积0.78 cm3/g,平均孔径2.1 nm,碘吸附值(QI2)1193.8 mg/g,亚甲基蓝吸附值(QMB)25 ml/0.1g,苯酚吸附值(QPhOH)160.7 mg/g,且对模拟染料废水具有良好脱色效果。

Abstract:

Waste cotton fabrics abtivated carbon (AC-WCF) was prepared from waste cotton fabrics (WCF )by zinc chloride activation. The mass fraction (ω), impregnation time (t1), activation temperature (T) and activation time (t2) on adsorption properties of activated carbons were investigated by using the orthogonal experiment method. The obtained activated carbons (AC-WCF) were characterized by Nitrogen adsorption-desorption isotherms, scanning electron microscope (SEM) and FT-IR spectroscopy. Results show that the best sample of AC-WCF is obtained under the conditions: ω=45%; t1=16 h; T=700℃ and t2=30 min. And the AC-WCF possesses a large apparent surface area (SBET=1462 m2/g) and high adsorption pore volume (V=0.78 cm3/g) with average pore size diameter of 2.1 nm. The iodine, methylene blue and phenol adsorption value of the AC-WCF are 1193.8 mg/g, 25 ml/0.1g, and 160.7 mg/g respectively. Meanwhile, AC-WCF shows high decolorization capability for dye waste water.

中图分类号: 

  • TQ102.9
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