纺织学报 ›› 2016, Vol. 37 ›› Issue (12): 1-5.

• 纤维材料 •    下一篇

长余辉发光再生纤维素纤维的制备

  

  • 收稿日期:2016-01-05 修回日期:2016-04-20 出版日期:2016-12-15 发布日期:2016-12-21

Preparation of long-afterglow luminescence regenerated cellulose fiber

  • Received:2016-01-05 Revised:2016-04-20 Online:2016-12-15 Published:2016-12-21

摘要:

对稀土铝酸锶长余辉粉末采用硅烷偶联剂进行包覆处理,增强了稀土铝酸锶粉末在水性溶液中的稳定性。以包覆处理过的稀土铝酸锶粉末为添加剂,以新型碱体系制备的再生纤维素为基材,通过湿法纺丝,制备出长余辉发光再生纤维素纤维。借助傅里叶红外光谱仪、扫描电镜、X 射线衍射仪、单纤维强力测试仪、余辉亮度测试仪对样品的性能进行表征,结果表明:偶联剂通过化学键Si—O—AI 包覆在稀土铝酸锶粉末上;经过偶联剂处理后,发光纤维的外观形貌较为光滑,直径约为60 μm;纤维中稀土铝酸锶结构和纤维素Ⅱ结构同时出现,二者没有相互影响;纤维力学强度提高了10%;余辉初始亮度为0.82 cd ∕ m²。

关键词: 稀土铝酸锶, 偶联剂, 再生纤维素纤维, 湿法纺丝

Abstract:

Silane coupling agent (KH-570) was used to modify the rare-earth strontium aluminate luminescent powder, which has good stability in aqueous solution. The  long-afterglow luminescent regenerated cellulose fibers were prepared regenerated cellulose fibers (prepared from novel NaOH/thiourea/urea solvent system) and the treated rare earth strontium aluminate powder as an additive by wet spinning. The luminescent fiber samples were characterized by Fourier transmission infrared spectroscopy, X-ray diffeaction a tensile tester, and a long-afterglow luminescent tester, respectively. The experimental results showed that the coupling agent was coated on the rare-earth strontium aluminate powder by Si—O—AI chemical bonds. After the coupling process, the luminescent fiber has smooth appearance and the diameter was about 60 μm. The structure of rare-earth strontium aluminate and cellulose Ⅱaluminate in the fiber at the same time, which were not affected by each other. Tensile properties increased by 10%. The initial luminescent intensity was 0.82 cd / m².

Key words: rare-earth strontium aluminate, coupling agent, regenerated cellulose fiber, wet spinning

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