硼酸锌/氢氧化铝对聚氯乙烯纺织结构材料阻燃及稳定性的影响

doi:10.13475/j.fzxb.20160301006

纺织学报 ›› 2017, Vol. 38 ›› Issue (01): 105-110.doi: 10.13475/j.fzxb.20160301006

硼酸锌/氢氧化铝对聚氯乙烯纺织结构材料阻燃及稳定性的影响

收稿日期:2016-03-04 修回日期:2016-11-04 出版日期:2017-01-15 发布日期:2017-01-16

Influence of zinc borate/aluminum hydroxide on flame retardancy and stability of polyvinyl chloride textile structure material

Received:2016-03-04 Revised:2016-11-04 Online:2017-01-15 Published:2017-01-16

摘要/Abstract

摘要：

为改善聚氯乙烯（PVC）纺织结构材料的阻燃、抑烟、防熔滴等性能，采用无机阻燃剂硼酸锌和氢氧化铝协同作用制备阻燃PVC纺织结构材料。利用极限氧指数仪、烟密度仪、热重分析仪、扫描电子显微镜分析了硼酸锌和氢氧化铝复配对PVC纺织结构材料性能的影响。结果表明：硼酸锌和氢氧化铝复配阻燃PVC纺织结构材料具有优异的阻燃性、抑烟性、防熔滴性，随着硼酸锌含量的增加，抑烟效果更佳；老化处理对PVC稳定性存在一定程度的影响，其极限氧指数值随热氧老化时间的延长先增加再降低，且随光氧老化时间的延长而增加。

关键词: 聚氯乙烯, 纺织结构材料, 硼酸锌, 氢氧化铝, 阻燃

Abstract:

In order to improving flame retardant,smoke suppressant and anti droplet properties of polyvinyl chloride (PVC) textile strucure materials, inorganic flame retardant zinc(2ZnO ?3B2O3 ?3.5H2O) and aluminum hydroxide were synergisticto prepare flame retardant polyvinyl chloride textile structure materials. The influence of 2ZnO ?3B2O3 ?3.5H2O/Al(OH)3 on the properties of polyvinyl chloride textile structure materials were analyzed by limiting oxygen index instrument, smoke density instrument TG and SEM. The results showed that 2ZnOB ?3B2O3 ?3.5H2O/Al(OH)3 is effective in flame retardancy, smoke suppression and anti-droplet properties of polyvinyl chloride chloride textile structure material. The higher the contents of 2ZnO ?3B2O3 ?3.5H2O are, the better smoke suppressant properties of polyvinyl chloride textile structure materials. The aging treatment also influences the stability of PVC, and its limiting oxygen index value is first increased and then decreased with the thermal oxidative treatment time increasing. The limiting oxygen index value increased with the increase of photo-oxidative treatment time.

Key words: polyvinyl chloride, textile structure material, zinc borate, aluminum hydroxide, flame retardancy

赵程波张斌韩建. 硼酸锌/氢氧化铝对聚氯乙烯纺织结构材料阻燃及稳定性的影响[J]. 纺织学报, 2017, 38(01): 105-110.

参考文献

相关文章 15

[1]	靳昕怡王颖朱志国刘彦麟王锐. 复合抑熔滴剂对阻燃聚酯共混物燃烧性能的影响[J]. 纺织学报, 2018, 39(08): 15-21.
[2]	高树珍迟文锐王兵兵汪亮. 磷-氮耐氯阻燃整理剂的合成及其应用[J]. 纺织学报, 2018, 39(06): 101-105.
[3]	吴海婷蒋小娟蔡再生. 环保阻燃型静电植绒黏合剂的合成及其应用[J]. 纺织学报, 2018, 39(06): 96-100.
[4]	刘文帅刘海亮徐红燕肖长发. 非织造布增强聚氯乙烯多孔膜的制备及其微结构调控[J]. 纺织学报, 2018, 39(06): 6-12.
[5]	尉霞逯凯美董晓宁. 间位芳纶织物的导湿排汗整理[J]. 纺织学报, 2018, 39(05): 80-86.
[6]	卢声林杰路艳华黄凤远程德红. 用含三嗪结构苯基磷酸酯的涤纶织物阻燃整理[J]. 纺织学报, 2018, 39(03): 98-102.
[7]	张思吴敏. 三聚氰胺纤维毡的制备与性能[J]. 纺织学报, 2017, 38(12): 65-68.
[8]	薛日杰王树根施楣梧. TiO2-SnO2复合溶胶在羊毛阻燃整理中的应用[J]. 纺织学报, 2017, 38(12): 95-100.
[9]	贾丽霞金崇业刘瑞单国华. 硅磷杂化阻燃整理对羊毛结构与热稳定性能的影响[J]. 纺织学报, 2017, 38(12): 101-105.
[10]	邓继勇柳芊董新理汪南方. 新型氮-磷阻燃剂制备及其对棉织物的阻燃性能[J]. 纺织学报, 2017, 38(11): 97-101.
[11]	汪泽幸何斌陈妍李洪登. 损伤条件下聚氯乙烯涂层膜结构材料拉伸蠕变特性[J]. 纺织学报, 2017, 38(10): 57-64.
[12]	魏丽菲朱志国靳昕怡董振峰王锐. 基于三（2-羟乙基）异氰尿酸酯的膨胀型阻燃剂对聚合物燃烧性能的影响[J]. 纺织学报, 2017, 38(09): 24-31.
[13]	陈威关晋平陈国强匡小慧. 静电层层自组装法整理多巴胺改性涤/棉混纺织物的阻燃性能[J]. 纺织学报, 2017, 38(09): 94-100.
[14]	任元林张悦曾倩谷叶童. 织物阻燃涂层新工艺的研究进展[J]. 纺织学报, 2017, 38(09): 168-173.
[15]	陈云博陈国强邢铁玲. 磷酸硼掺杂硅溶胶对蚕丝织物的阻燃整理[J]. 纺织学报, 2017, 38(08): 96-101.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

硼酸锌/氢氧化铝对聚氯乙烯纺织结构材料阻燃及稳定性的影响

Influence of zinc borate/aluminum hydroxide on flame retardancy and stability of polyvinyl chloride textile structure material

PDF (PC)

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0