Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (03): 102-108.doi: 10.13475/j.fzxb.20180300807

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of acrylate-silicone/organic pigment submicron capsules in pigment printing

CHEN Zhijie1, ZHOU Peng1, DU Chunxiao1, JIN Qianhong2, QI Dongming1, XIANG Zhong3()   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Yiwu Zhongli Industry and Trade Co., Ltd., Yiwu, Zhejiang 322007, China
    3. Key Laboratory of Modern Textile Equipment Technology in Zhejiang Province, Hangzhou, Zhejiang 310018, China
  • Received:2018-03-01 Revised:2018-12-04 Online:2019-03-15 Published:2019-03-15
  • Contact: XIANG Zhong E-mail:xz@zstu.edu.cn

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Abstract:

In order to further improve the handle feeling, permeability and other performance of the fabric printed by the organic pigment submicron capsules, vinyl-terminated polydimethylsiloxane (ViPDMS) was co-polymerized with acrylic monomer (Acr) by miniemulsion polymerization, and a series of P(DMS-Acr)/PB submicron capsules were prepared. Then the P(DMS-Acr)/PB submicron capsules with high viscous flowability were used for the pigment printing of polyester plain weave fabric, and the air permeability, stiffness, dry and wet rubbing fastness and K/S values of the printed fabric were tested and compared. The results show that when the mass fraction of ViPDMS is 30%, a uniform and stable dark latex with an average particle size of 318 nm can be obtained. The K/S values and the dry and wet rubbing fastness of the fabric printed by the P(DMS-Acr)/PB submicron capsules are similar with these of the PAcr/PB printed fabric, while the air permeability and the fabric stiffness are much better than the later. It is considered that the introduction of the silicone composition into the submicron capsule wall material can significantly enhance the viscous flowability and the phase separation capability of the coating on the fabric surface during the baking process.

Key words: organic pigment, capsule, vinyl-terminated polydimethylsiloxane, pigment printing, permeability

CLC Number: 

  • TQ32517

Tab.1

Reaction formulations, average particle size and size distribution of pigment submicron capsules prepared by miniemulsion polymerization"

样品组
编号		 各配方质量/g 平均粒径/
nm		 粒径分布
指数
MMA BA ViPDMS PB HD SDS KPS H2O
1 5.0 5.0 0 0.5 160 0.107
2 4.5 4.5 1 0.5 194 0.154
3 3.5 3.5 3 0.5 0.2 0.5 0.3 88.5 318 0.212
4 2.5 2.5 5 0.5 652 0.523
5 3.5 3.5 3 0 290 0.115

Fig.1

TEM images of composite latex films of PAcr/PB, P(DMS-Acr) and P(DMS-Acr)/PB"

Fig.2

Influence of ViPDMS content of submicron capsules on air permeability of coated fabric"

Fig.3

SEM images of surface morphology of fabric coated by submicron capsules with different ViPDMS contents"

Fig.4

Stiffness of coated fabric with different ViPDMS contents"

Fig.5

SEM images of surface morphology of single fiber with different ViPDMS contents"

Tab.2

Dry, wet rubbing and soaping fastness of coated fabric with different ViPDMS contents"

ViPDMS
质量分数/%		 耐皂洗
牢度/级		 耐摩擦牢度/级
干 湿
0 4~5 4~5 4
10 4~5 4 4
30 4~5 4 4
50 4~5 3~4 2~3

Fig.6

K/S values of coated fabric with different ViPDMS contents"

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