Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (04): 77-82.doi: 10.13475/j.fzxb.20180406506

• Dyeing and Finishig & Chemicals • Previous Articles     Next Articles

Aggregation behavior of Reactive Red 195 in neutral electrolyte solution

WANG Aming1, XIA Liangjun1,2, WANG Yunli1()   

  1. 1. Institute of National Key Laboratory of Textile New Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Institute for Frontier Materials, Deakin University, Geelong VIC 3220, Australia
  • Received:2018-04-27 Revised:2018-08-22 Online:2019-04-15 Published:2019-04-16
  • Contact: WANG Yunli E-mail:ylwang@wtu.edu.cn

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Abstract:

In order to study the aggregation behavior of Reactive Red 195 and its effect on dye uptake, six neutral electrolytes with different concentrations were added into the Reactive Red 195 dye solution. The aggregation behaviors of Reactive Red 195 in different electrolyte solutions were studied by means of UV-Vis spectrophotometer and laser particle size analyzer, and the influence of different electrolytes on the dye uptake of Reactive Red 195 was investigated. The results show that with the increase of the electrolyte concentration, the degree of dye aggregation increases. At room temperature, the degree of influence of the six metal ions on dye aggregation is Al3+ > Ca2+ > Mg2+ > K+ > Na+ > Li+. The degree of dye aggregation is enhanced with the increase in ionic radius and valence of metal ions. Among them, the valence of metal ions is the main factor influencing dye aggregation. During dyeing process, the dye uptake is enhanced with the increase of dye aggregation.

Key words: reactive dye, electrolyte, aggregation behavior, particle size, dye uptake

CLC Number: 

  • TS190

Fig.1

Chemical structure of Reactive Red 195"

Fig.2

Effect of electrolyte concentration on absorption spectra of Reactive Red 195"

Fig.3

Effect of electrolyte concentration on maximum absorbance (a) and maximum absorption wavelength (b) of Reactive Red 195"

Fig.4

Effect of electrolyte concentration on particle size (a) and Zeta potential (b) of Reactive Red 195"

Fig.5

Effect of electrolyte concentration on the increments of particle size (a) and reduction of Zeta potential (b) of Reactive Red 195"

Tab.1

Effect of electrolyte type on exhaustion%"

电解质名称 平均上染率
LiCl· H2O 17.8
NaCl 26.8
KCl 38.1
CaCl2 39.4
MgCl2· 6H2O 29.2
AlCl3· 6H2O 34.3
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