Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (8): 69-75.doi: 10.13475/j.fzxb.20180602707

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of silicone-containing pigment capsules by miniemulsionpolymerization and printing performance thereof on polyester fabric

CHEN Zhijie1, HU Xudong1, HUANG Zhuo2, SONG Limiao3, QI Dongming3, XIANG Zhong1()   

  1. 1. Key Laboratory of Modern Textile Equipment Technology in Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Hangzhou Baihe Clariant Pigments Co., Ltd., Hangzhou, Zhejiang 310018, China
    3. Silk Institute, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
  • Received:2018-06-05 Revised:2019-05-14 Online:2019-08-15 Published:2019-08-16
  • Contact: XIANG Zhong E-mail:xz@zstu.edu.cn

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Abstract:

In order to build a high-pigment mass fraction low-thickness organosilicone-modified composite film coating on the fabric surface, octamethylcyclotetrasiloxane (D4) was introduced into the pigment/monomer dispersion, then a silicone pigment capsules containing organic pigment particles (PB) and polydimethylsiloxane(PDMS) were prepared by miniemulsion polymerization. These pigment capsule emulsions were used in the pigment printing of polyester plain weave fabrics. The influence of D4 content on the morphology of fabric surface film was studied. The dry and wet rubbing fastness, K/S value, and stiffness of the printed fabric were tested and compared. The results show that when the mass fraction of D4 is 50%, a uniform and stable latex dispersion with an average particle size of 170 nm can be obtained. The investigation of the film morphology reveals that during the miniemulsion polymerization, part of D4 is ring-opened and polymerized into PDMS, which can be adopted to blend and modify the composite film. The corresponding pigment printing fabric has high rubbing fastness, low stiffness, and good color depth. It is believed that the introduction of D4 in the capsule preparation process can effectively increase the pigment mass fraction and water resistance of the composite film, and reduce the coefficient of friction on the surface of the film without affecting the dispersion state of the pigment.

Key words: organic pigment, encapsulation, octamethylcyclotetrasiloxane, pigment printing

CLC Number: 

  • TS194.443

Fig.1

Effect of D4 content on particle size and distribution of pigment capsules"

Fig.2

TEM images of pigment capsule composite film with different D4 content"

Fig.3

Quality and K/S value of composite film made of different D4 pigment capsules"

Fig.4

Thermogravimetric curves of composite films made of different D4 pigment capsules"

Fig.5

Effect of D4 content on structure and attachment of composite film on fabric surface. (a) Uncoated fabric; (b) 0%; (c) 10%; (d) 30%; (e) 50%; (f) 80%"

Tab.1

Effect of D4 content on rubbing fastness of pigment capsule printed fabrics"

D4质量分数/% 干摩擦牢度/级 湿摩擦牢度/级
0 4 3
10 4~5 3
30 4~5 4
50 4~5 4~5
80 1~2 1~2

Fig.6

Effect of D4 content on K/S and stiffness of pigment capsules printed fabrics"

Fig.7

Film-forming model of silicon-containing pigment capsule on fabric surface"

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