Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (11): 119-124.doi: 10.13475/j.fzxb.20180807107

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of oxidized chitosan/sericin composite and its functional finish on cotton fabrics

WANG Hao(), DU Zhaofang, XU Yunhui   

  1. College of Light-Textile Engineering and Art, Anhui Agricultural University, Hefei, Anhui 230036, China
  • Received:2018-08-31 Revised:2019-08-23 Online:2019-11-15 Published:2019-11-26

RichHTML

13

PDF (PC)

206

Abstract:

In order to develop high quality cotton product, the oxidized chitosan/sericin composite was prepared by covalent binding of oxidized chitosan and sericin, and then applied to functional finish of cotton fabrics. The influences of various factors on the weighting percentage of cotton fabrics were analyzed and the optimized process parameters were obtained. The composite and its finished cotton fabrics were characterized by Fourier transform infrared spectroscopy, scanning electron microscope analysis. The results show that the active aldehyde group is introduced into chitosan after chitosan is oxidized with sodium periodate, subsequently the oxidized chitosan is subjected to a Schiff base reaction with sericin to prepare the composite finishing agent. When the composite is applied to the finishing of cotton fabrics, it can be chemically bonded to cotton fibers and cross-linked to form the thin film on the surface. With the increase of the oxidation degree of chitosan, the sericin loss rate of the composite decreases significantly. The breaking strength and moisture absorption of the modified cotton fabrics with oxidized chitosan/sericin composite show little change, whereas the properties of the wrinkle recovery, ultraviolet resistance and bacterial resistance of the modified fabrics are significantly improved. The weighting percentage of the cotton fabrics is stabilized at about 4% after 3 washing cycles, indicating that modified cotton fabrics have good washing fastness.

Key words: cotton fabric, functional finish, sodium periodate, oxidized chitosan, sericin

CLC Number: 

  • TS195.5

Fig.1

Schematic diagram of reaction between oxidized chitosan and sericin"

Fig.2

Infrared spectrum variation of different samples"

Fig.3

Effect of oxidation time on oxidation degree of chitosan and dissolution rate of sericin in composite"

Fig.4

SEM images of modified cotton fibers(×3 000) (a)Original cotton fiber;(b)Sericin modified cotton fiber;(c)Composite modified cotton fiber"

Fig.5

XPS spectrum of cotton fabric before and after composite modification"

Fig.6

Effect of chitosan oxidation time on weighting percentage of cotton fabric"

Tab.1

Effect of molar ratio of composite on weighting percentage of cotton fabric"

n(SS):n(OCS) 3:1 2:1 1:1 1:2 1:3
质量增加率/% 3.39 4.78 8.62 8.48 7.72

Fig.7

Effect of composite mass fraction on weighting percentage of cotton fabric"

Fig.8

Effect of composite treatment time on weighting percentage of cotton fabric"

Tab.2

Performance of cotton fabric before and after composite modification"

样品 断裂强力/N 毛细效应(30 min)/cm UPF值 折皱回复角/(°) 抑菌率/%
金黄色
葡萄球菌		 大肠
杆菌
原棉织物 286.3 8.53 8.83 135.4 — —
复合物改
性棉织物		 269.4 9.02 21.07 189.5 96.4 95.5

Tab.3

Effect of washing times on weighting percentage of fabrics"

洗涤次数 0 1 2 3 4 5
质量增加率/% 8.57 5.33 4.45 4.18 4.15 4.08
[1] 蒋挺大. 壳聚糖[M]. 北京: 化学工业出版社, 2001:160-224.
JIANG Tingda. Chitosan[M]. Beijing: Chemical Industry Press, 2001: 160-224.
[2] MUXIKA A, ETXABIDE A, URANGA J, et al. Chitosan as a bioactive polymer: processing, properties and applications[J]. International Journal of Biological Macromolecules, 2017,105(12):1358-1368.
[3] YOO S H, LEE J S, PARK S Y. Effects of selective oxidation of chitosan on physical and biological properties[J]. International Journal of Biological Macromolecules, 2014(35):27-31.
[4] MAJETI N V, RAVI K M. A review of chitin and chitosan applications[J]. Reactive & Functional Polymers, 2000,46(1):1-27.
[5] JIANG H L, KIM Y K, AROTE R, et al. Chitosan-graft-polyethylenimine as a gene carrier[J]. Journal of Controlled Release, 2011,117(2):273-280.
pmid: 17166614
[6] 董雪, 盛家镛, 邢铁玲, 等. 丝胶蛋白的研究与应用综述[J]. 丝绸, 2011,48(12):16-20.
DONG Xue, SHENG Jiayong, XING Tieling, et al. Overview of sericin protein's research and application[J]. Journal of Silk, 2011,48(12):16-20.
[7] 肖肖, 陈昌盛, 刘伟强, 等. 丝胶蛋白的结构、性能及生物医学应用[J]. 化学进展, 2017,29(5):513-523.
XIAO Xiao, CHEN Changsheng, LIU Weiqiang, et al. Structure, features and biomedical applications of silk sericin[J]. Progress in Chemistry, 2017,29(5):513-523.
[8] 叶皓华, 陈国强, 唐孝明. 改性丝胶在棉织物上的应用[J]. 纺织学报, 2011,32(8):87-90.
YE Haohua, CHEN Guoqiang, TANG Xiaoming. Application of modified sericin on cotton fabrics[J]. Journal of Textile Research, 2011,32(8):87-90.
[9] 董雪, 邢铁玲, 盛家镛, 等. 棉织物的丝胶涂层整理及其性能[J]. 纺织学报, 2014,35(11):112-117.
DONG Xue, XING Tieling, SHENG Jiayong, et al. Study on sericin coated finishing of cotton fabric and its properties[J]. Journal of Textile Research, 2014,35(11):112-117.
[10] 宋世洪. 丝胶蛋白的改性与固定[D]. 重庆:西南大学, 2008:12.
SONG Shihong. Study on reshaping and fixing of silk gelatin[D]. Chongqing: Southwest University, 2008:12.
[11] JIANG H L, LIM H T, KIM Y K, et al. Chitosan-graft-(PEI-beta-cyclodextrin) copolymers and their supramolecular PEGylation for DNA and siRNA delivery[J]. Biomaterials, 2011,32(32):8328-8341.
pmid: 21840593
[12] 李新玥. 生物酶法制备蛋白膜及膜性能研究[D]. 苏州:苏州大学, 2014:13-14.
LI Xinyue. Study on preparation and properties of protein membrane based on biological enzyme[D]. Suzhou: Soochow University, 2014:13-14.
[13] LV Y, LONG Z, SONG C, et al. Preparation of dialdehyde chitosan and its application in green synjournal of silver nanoparticles[J]. Bioresources, 2013,8(4):6162-6170.
[14] 吕勇. 选择性氧化壳聚糖衍生物制备及在造纸中的应用[D]. 无锡:江南大学, 2014: 30.
LÜ Yong. Preparation of selective oxidation chitosan derivatives and their application in papermaking[D]. Wuxi: Jiangnan University, 2014: 30.
[15] 陈华, 朱良均, 闵思佳, 等. 蚕丝丝胶蛋白的结构、性能及利用[J]. 功能高分子学报, 2001,14(3):344-347.
CHEN Hua, ZHU Liangjun, MIN Sijia, et al. Structure, property and utilization of silk sericin[J]. Journal of Functional Polymers, 2001,14(3):344-347.
[1] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole / cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[2] CHEN Shiping, CHEN Min, WEI Cen, WANG Fujun, WANG Lu. Structure and functions of medical protective clothing and trend for research and development [J]. Journal of Textile Research, 2020, 41(08): 179-187.
[3] LIU Guojin, SHI Feng, CHEN Xinxiang, ZHANG Guoqing, ZHOU Lan. Preparation of polyurethane / phase change wax functional finishing agents for heat storage and temperature regulation and their applications on cotton fabrics [J]. Journal of Textile Research, 2020, 41(07): 129-134.
[4] WANG Yating, ZHAO Jiaqi, WANG Bijia, FENG Xueling, QIAN Guochun, SUI Xiaofeng. Research progress in dyeing and functional finishing of artificial microfiber leather [J]. Journal of Textile Research, 2020, 41(07): 188-196.
[5] CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying. Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics [J]. Journal of Textile Research, 2020, 41(06): 93-98.
[6] ZHENG Hongfei, WANG Ruiqi, WANG Qing, ZHU Ying, XU Yunhui. Preparation and properties of antibacterial silk fabric modified with oxidized chitosan [J]. Journal of Textile Research, 2020, 41(05): 121-128.
[7] ZHOU Qingqing, CHEN Jiayi, QI Zhenming, CHEN Weijian, SHAO Jianzhong. Preparation and characterization of flame retardant and antibacterial cotton fabric [J]. Journal of Textile Research, 2020, 41(05): 112-120.
[8] TAN Lin, SHI Yidong, ZHOU Wenya. Study on enhancement of hydrophobicity treatment of cotton fabrics using silica sol [J]. Journal of Textile Research, 2020, 41(04): 106-111.
[9] WEI Tengxiang, LI Min, PENG Hongyun, FU Shaohai. Relationship between open-width mercerization condition and loop structure of weft plain-knitted cotton fabrics [J]. Journal of Textile Research, 2020, 41(04): 98-105.
[10] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[11] GAO Simeng, WANG Hongbo, DU Jinmei, WANG Wencong. Synthesis of polybetaine antibacterial agent and its applications in cotton textiles finishing [J]. Journal of Textile Research, 2020, 41(02): 89-94.
[12] CHANG Shuo, SHEN Jiajia. Research progress of graphene durable finishing of textiles [J]. Journal of Textile Research, 2020, 41(02): 179-186.
[13] YI Ling, ZHANG He, FU Xin, LI Wen. Preparation and far-infrared emission performance of graphene based zirconium / titanium composites modified cotton fabrics [J]. Journal of Textile Research, 2020, 41(01): 102-109.
[14] LI Yuzhou, ZHANG Yufan, ZHOU Qingqing, CHEN Guoqiang, XING Tieling. Preparation and electrochemical properties of MnO2 / graphene / cotton fabric composite electrode [J]. Journal of Textile Research, 2020, 41(01): 96-101.
[15] CHEN Ying, ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei. Preparation and properties of polypyrrole composite fabric by soft template process [J]. Journal of Textile Research, 2019, 40(12): 93-97.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd