Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (02): 141-146.doi: 10.13475/j.fzxb.20181100306

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preferential and recyclable adsorption of dyes from water by Zr-organic skeleton

LI Qing1(), FAN Zenglu2, ZHANG Luohong1, LI Yong3, CHEN Chuangxun1   

  1. 1. College of Environmental & Chemical Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. Shaanxi Province Key Laboratory of Functional Garment Material, Xi'an Polytechnic University, Xi'an, Shaanxi710048, China
    3. College of Mechanical and Electronic Engineering, Tarim University, Alar, Xinjiang 843300, China
  • Received:2018-11-01 Revised:2018-12-05 Online:2019-02-15 Published:2019-02-01

RichHTML

3

PDF (PC)

139

Abstract:

In view of the water pollution caused by printing and dyeing wastewater, a three dimensional porous Zr-organic skeleton material with high water stability was successfully assembled from ZrCl4 with 2,2'-Biquinoline-4,4'-dicarboxylicacid (H2L) under 100 ℃ with solvothermal synthesis method. It was deployed to realize the selective and recyclable adsorption of dyes with different sizes from water. The results demonstrate that the selective adsorption towards Methylene Blue (MB), Cationic Brilliant Red 5GN (BR14) and Cationic Bright Yellow 7GL (BY24) is achieved in 6 groups of mixed aqueous solution composed of reactive dyes and cationic dyes. The removal efficiency towards cationic dyes are all above 79%, in which the removal efficiency for MB is as high as 99.78%. After 8 rounds of adsorption-desorption cycle experiment, the adsorption efficiency of 40 mL 15.7 mg/L MB is still up to 97.0%. In addition, X-ray powder diffraction measurements shows that the crystallinity of Zr-MOF is almost unchanged after 8 adsorption-desorption cycles and 48 h in strong acid (hydrochloric acid) and strong alkali (NaOH) aqueous solution with pH value of 2-14, demonstrating very reliable stability and recycling ability.

Key words: Zr-organic framework, dyes adsorption, recyclable adsorption, water stability, dyeing waste water

CLC Number: 

  • TS190.2

Fig.1

FT-IR spectra of Zr-MOF and H2L"

Fig.2

TGA plot of Zr-MOF"

Fig.3

XRD patterns of single crystal and bulk samples"

Fig.4

Normalized sequential UV-Vis spectra of mixed aqueous solution after addition of Zr-MOF"

Fig.5

Adsorption of Zr-MOF towards (MB+MO) mixed aqueous solution"

Fig.6

Desorption of MB from MB@Zr-MOF in saturated methanol solution of sodium chloride (a) and adsorption/desorption efficiency varied with recycle number of Zr-MOF towards MB (b)"

Fig.7

XRD patterns of Zr-MOF 8 times of recycle and different pH"

[1] ZHU H Y, JIANG R, XIAO L, et al. Photocatalytic decolorization and degradation of Congo red on innovative crosslinked chitosan/nano-CdS composite catalyst under visible light irradiation[J]. Journal of Hazardous Materials, 2009,169(1-3):933-940.
doi: 10.1016/j.jhazmat.2009.04.037 pmid: 19477069
[2] AJMAL A, MAJEED I, MALIK R N, et al. Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview[J]. RSC Advances, 2014,70(4):37003-37026.
[3] ASGHAR A, ABDUL AZIZ A R, MOHD A W D W. Recent advances, challenges and prospects of in situ production of hydrogen peroxide for textile wastewater treatment in microbial fuel cells[J]. Journal of Chemical Technology & Biotechnology, 2015,89(10):1466-1480.
[4] 李庆, 张莹, 樊增禄, 等. Cu-有机骨架对染料废水的吸附和可见光降解[J]. 纺织学报, 2018,39(2):112-118.
LI Qing, ZHANG Ying, FAN Zenglu, et al. Adsorption and visible-light photodegradation of dye wastewaterover Cu-organic framework[J]. Journal of Textile Research, 2018,39(2):112-118.
[5] WU Z B, YUAN X Z, ZHANG J, et al. Photocatalytic decontamination of wastewater containing organic dyes by metal-organic frameworks and their derivatives[J]. Chem Cat Chem, 2017,9(1):41-64.
[6] 易兵, 胡倩, 杨辉琼, 等. 酸性红37光催化降解动力学的响应曲面法优化及其转化机制[J]. 纺织学报, 2018,39(6):81-88.
YI Bing, HU Qian, YANG Huiqiong, et al. Photocatalytic degradation kinetics optimization of acid red 37 by response surface method and transformation mechanism thereof[J]. Journal of Textile Research, 2018,39(6):81-88.
[7] LI Q, XUE D X, ZHANG Y F, et al. A dual-functional indium-organic framework towards organic pollutant decontamination via physically selective adsorption and chemically photodegradation[J]. Journal of Materials Chemistry A, 2017,5(27):14182-14189
[8] LI Q, FAN Z L, XUE D X, et al. Multi-dyes@MOF composite boosts highly efficient photodegradation of ultra-stubborn dye of reactive blue 21 under visible-light irradiation[J]. Journal of Materials Chemistry A, 2018,6(5):2148-2156.
[9] 郭璇, 王宇航. FeCl3改性活性炭对罗丹明B的吸附性能[J]. 西安工程大学学报, 2017,31(4):474-479.
GUO Xuan, WANG Yuhang. Adsorption of rhodamine B on activated carbon modified by FeCl3[J]. Journal of Xi'an Polytechnic University, 2017,31(4):474-479.
[10] ZHOU H C J, KITAGWA S. Metal-organic frameworks (MOFs)[J]. Chemical Society Reviews, 2014,43(16):5415-5418.
pmid: 25011480
[11] 朱炜, 李庆, 张萍, 等. MOF-177吸附CO2、CH4的模拟研究[J]. 纺织高校基础科学学报, 2018,31(1):90-96.
ZHU Wei, LI Qing, ZHANG Ping, et al. Simulation study of the adsorption of CO2, CH4 by MOF-177[J]. Basic Sciences Journal of Textile Universities, 2018,31(1):90-96.
[12] BAI Y, DOU Y B, XIE L H, et al. Zr-based metal-organic frameworks: design, synjournal, structure, and applications[J]. Chemical Society Reviews, 2016,45(8):2327-2367.
doi: 10.1039/c5cs00837a pmid: 26886869
[13] WANG C H, LIU X L, DEMIR N K, et al. Applications of water stable metal-organic frameworks[J]. Chemical Society Reviews, 2016,45(18):5107-5134.
doi: 10.1039/c6cs00362a pmid: 27406473
[1] LI Qing, GUAN Binbin, WANG Ya, LIU Tianhui, ZHANG Luohong, FAN Zenglu. Photosensitizers sensitized Cu-organic framework for highly efficient photocatalytic degradation of Reactive Dark Blue K-R [J]. Journal of Textile Research, 2020, 41(10): 87-93.
[2] XIN Minyue, ZHENG Qiang, WU Jiangdan, LIANG Liefeng. Preparation of porous ZnO films by coaxial electrospinning and photocatalytic performance thereof [J]. Journal of Textile Research, 2019, 40(10): 42-47.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd