Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (03): 188-196.doi: 10.13475/j.fzxb.20181205709

• Comprehensive Review • Previous Articles    

Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond

ZHAO Bing1,2,3(), HUANG Xiaocui4, QI Ning1, ZHONG Zhou2, CHE Mingguo2, GE Liangliang3   

  1. 1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215006, China
    2. X-FIPER New Material Co., Ltd., Suzhou, Jiangsu 215200, China
    3. Suzhou Jctex Co., Ltd., Suzhou, Jiangsu 215104, China
    4. Institute of Applied Technology of Silk, Suzhou Vocational University, Suzhou, Jiangsu 215104, China
  • Received:2018-12-26 Revised:2019-12-04 Online:2020-03-15 Published:2020-03-27

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Abstract:

In view of unaffinity, weak physical adsorption and poor washing fastness between cotton fabric and silver nanoparticles (AgNPs), the latest research progress of AgNPs antibacterial cotton fabric based on covalent bond was systematically reviewed. Two covalent bond mechanisms, schiff base reaction and esterification reaction, were described. Combined with the data of inhibition rate and silver content, preparation process, antibacterial property and wash fastness of AgNPs antibacterial cotton fabric based on covalent bond were discussed, which were classified by covalent crosslinkers between AgNPs and cotton fabric, such as hyperbranched polymers, dendrimers, silk fibroin, sericin, cysteine, methionine, mercaptoacetic acid, chitosan derivatives, polystyrene-b-polyacrylic acid, butane tetracarboxylic acid, and so on. Finally, the shortcomings and the concerns in future of AgNPs antibacterial cotton fabric based on covalent bond were introduced. It is pointed out that the covalent crosslinking methods greatly improve the antibacterial washability of AgNPs and provide a new thought and a new way for developing environmentally friendly and durable antibacterial AgNPs textiles.

Key words: cotton fabric, covalent bond, silver nanoparticles, antibacterial property, schiff base reaction, esterification reaction

CLC Number: 

  • TB333

Fig.1

Schematic diagram of dialdehyde cellulose reacting with AgNPs-NH2"

Fig.2

Schematic diagram of reaction principle of silk fibroin/AgNPs modifying oxidized cotton fabric"

Fig.3

Schematic diagram of L-cysteine/carboxymethyl chitosan/cotton fiber covalent crosslinking with AgNPs"

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