Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (01): 96-101.doi: 10.13475/j.fzxb.20190105006

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and electrochemical properties of MnO2/graphene/cotton fabric composite electrode

LI Yuzhou, ZHANG Yufan, ZHOU Qingqing, CHEN Guoqiang, XING Tieling()   

  1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
  • Received:2019-01-23 Revised:2019-06-05 Online:2020-01-15 Published:2020-01-14
  • Contact: XING Tieling E-mail:xingtieling@suda.edu.cn

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Abstract:

In order to enhance the electrochemical properties of flexible fabric electrodes, high concentration graphene oxide hydrosol was prepared by improved Hummers method, the graphene oxide was then coated onto cotton fabric through an environmentally friendly ″dry-coating″ method, and graphene/cotton fabric was prepared by subsequent ″two-step reduction″ method of chemical-microwave reduction. Then the MnO2/graphene/cotton fabric composite electrode materials were prepared through electrochemical deposition of MnO2 on graphene/cotton fabric material. The morphology and structure of composite electrode materials were characterized by scanning electron microscopy, X-ray diffraction, and infrared spectrum. The results show that the specific capacitance of composite electrode material reaches 490 F/g at current density of 0.25 A/g. After 1 000 capacitance discharges, the capacitance remains at 95.5% and the energy density reaches 17.01 W·h/kg.

Key words: graphene, MnO2, cotton fabric, composite material, electrode, electrochemical property

CLC Number: 

  • TS190.2

Fig.1

SEM images of different fabrics magnified by different multiples. (a) Pristine cotton fabric at 100 ratios; (b) Pristine cotton fabric at 1 000 ratios; (c) GO-coated cotton fabric at 1 000 ratios;(d) GO-coated cotton fabric at 10 000 ratios;(e) MnO2/GO/cotton fabric at 1 000 ratios; (f) MnO2/GO/cotton fabric at 10 000 ratios;(g) MnO2/GO/cotton fabric at 50 000 ratios;(h) MnO2/GO/cotton fabric at 100 000 ratios"

Fig.2

XRD curves of GO/cotton fabric and MnO2/GO/cotton fabric"

Fig.3

FT-IR spectra of GO/cotton fabric and MnO2/GO/cotton fabric"

Fig.4

CV curves of MnO2/GO/cotton fabric at different scan rates. (a) Cyclic voltammetry curve;(b) Galvanostatic charge-discharge curves at different current densities; (c) Calculated areal capacitance curve of electrode according to the GCD curve; (d) Nyquist plots; (e) Cyclic stability at current density of 0.25 A/g; (f) Ragone plot relating energy density to power density"

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