Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (8): 117-123.doi: 10.13475/j.fzxb.20190202207

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of multifunctional composite conductive wool fabric

WANG Wencong1,2(), FAN Jingjing1,2, DING Chao1,2, WANG Hongbo1,2   

  1. 1. Jiangsu Engineering Technology Research Center of Functional Textiles, Jiangnan University, Wuxi, Jiangsu 214122, China
    2. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education,Wuxi, Jiangsu 214122, China
  • Received:2019-02-18 Revised:2019-05-13 Online:2019-08-15 Published:2019-08-16

RichHTML

1

PDF (PC)

177

Abstract:

Multifunctional conductive wool fabric was successfully prepared by alternatively depositing carboxylic multi-walled carbon nanotubes (MWCNTs-COOH) and polypyrrole (PPy) on the charged surface of wool fabric. The influence of experimental conditions on the conductivity were determined using digital multimeter, and the structure, wash resistance, antibacterial property and water repellent property of composite conductive wool fabric prepared under the relatively optimal conditions were investigated. The results show that when the concentration of MWCNTs-COOH, PPy and FeCl3·6H2O are 1.0 mg/mL, 1.00 mol/L and 1.00 mol/L, respectively, the reaction time of oxypolymerization is 30 min, the temperature of oxypolymerization is about 0 ℃ and the number of assembly bilayers is 5, composite conductive fabric with the electrical conductivity around 110 S/m exhibits better conductive properties. The surface of wool fabric is covered by MWCNTs-COOH/PPy multilayers. The conductivity can reach 98.8 S/m after washing for 10 cycles, showing that the composite conductive wool fabric has good washing resistance. Besides, the composite fabric possesses a collection of various functions such as antibacterial property and water repellent properties.

Key words: carboxylic multi-walled carbon nanotube, polypyrrole, wool fabric, conductive property, antibacterial property, water repellent property

CLC Number: 

  • TS195.5

Fig.1

Influence of MWCNTs-COOH concentration on conductivity of composite conductive wool fabric"

Fig.2

Influence of Py concentration on conductivity of composite conductive wool fabric"

Fig.3

Influence of FeCl3·6H2O concentration on conductivity of composite conductive wool fabric"

Fig.4

Influence of reaction time of oxypolymerization on conductivity of composite conductive wool fabric"

Fig.5

Influence of temperature of oxypolymerization on conductivity of composite conductive wool fabric"

Fig.6

FT-IR spectra of original wool fabric and composite conductive wool fabrics"

Fig.7

SEM images of original wool fabric (a) and composite conductive wool fabric with 1 (b), 3 (c) and 5 (d) assembly bilayers(×2 000)"

Fig.8

Interaction mechanism of wool, MWCNTs-COOH and PPy"

Fig.9

SEM image of composite conductive wool fabric after washing 10 times(×2 000)"

Tab. 1

Diameters of bacteriostatic zone of composite conductive wool fabrics with different assembly bilayersmm"

组装
次数		 抑菌带宽度
大肠杆菌 金黄色葡萄球菌
0 0.00 0.00
1 4.56 6.17
3 7.35 8.51
5 9.07 10.25

Fig.10

Antibacterial effect of composite conductive wool fabrics with 5 assembly bilayers against Escherichia coli bacteria (a) and Staphylococcus aureus bacteria (b)"

Fig.11

Surface wettability of composite conductive fabrics with 0 (a), 1 (b), 3 (c), and 5 (d) assembly bilayers"

[1] MAITY S, CHATTERJEE A . Conductive polymer-based electro-conductive textile composites for electromagnetic interference shielding: a review[J]. Journal of Industrial Textiles, 2018,47(8):2228-2252.
doi: 10.1177/1528083716670310
[2] HAO T, WANG W, YU D . A flexible cotton-based supercapacitor electrode with high stability prepared by multiwalled CNTs/PANI[J]. Journal of Electronic Materials, 2018,47(7):4108-4115.
doi: 10.1007/s11664-018-6306-6
[3] TIAN M, DU M, QU L , et al. Electromagnetic interference shielding cotton fabrics with high electrical conductivity and electrical heating behavior via layer-by-layer self-assembly route[J]. RSC Advance, 2017,68(7):42641-42652.
[4] ZHOU Y, DING X, ZHANG J , et al. Fabrication of conductive fabric as textile electrode for ECG moni-toring[J]. Fibers and Polymers, 2014,15(11):2260-2264.
doi: 10.1007/s12221-014-2260-y
[5] LIU Y, ZHAO X, TUO X . Preparation of polypyrrole coated cotton conductive fabrics[J]. Journal of The Textile Institute, 2016,108(5):1-6.
doi: 10.1080/00405000.2015.1133105
[6] LU M, XIE R, LIU Z , et al. Enhancement in electrical conductive property of polypyrrole-coated cotton fabrics using cationic surfactant[J]. Journal of Applied Polymer Science, 2016,133(32):43601.
[7] XU Q, LI M, YAN P , et al. Polypyrrole-coated cotton fabrics prepared by electrochemical polymerization as textile counter electrode for dye-sensitized solar cells[J]. Organic Electronics, 2016,29:107-113.
doi: 10.1016/j.orgel.2015.11.007
[8] HAO T, SUN J, WANG W , et al. MWCNTs-COOH/cotton flexible supercapacitor electrode prepared by improvement one-time dipping and carbonization method[J]. Cellulose, 2018,25(7):4031-4041.
doi: 10.1007/s10570-018-1829-9
[9] YANG M, FU C, XIA Z , et al. Conductive and durable CNT-cotton ring spun yarns[J]. Cellulose, 2018,25(7):4239-4249.
doi: 10.1007/s10570-018-1839-7
[10] 董振峰, 朱志国, 王锐 , 等. 碳纳米管/聚合物复合体系阻燃性能的研究进展[J]. 纺织学报, 2009,30(3):136-142.
DONG Zhenfeng, ZHU Zhiguo, WANG Rui , et al. Recent development on flame retardancy of carbon nanotubes polymer composites[J]. Journal of Textile Research, 2009,30(3):136-142.
doi: 10.1177/004051756003000204
[11] 高博, 赵玉真, 张煜星 , 等. 层层组装法制备多功能超疏水性棉织物[J]. 印染, 2017(15):34-37.
GAO Bo, ZHAO Yuzhen, ZHANG Yuxing , et al. Preparation of multifunctional super hydrophobic cotton fabric via layer by layer assembly[J]. China Dyeing & Finishing, 2017(15):34-37.
[12] 崔锦峰, 安进, 裴春娟 , 等. 超疏水导电聚吡咯材料的研究进展[J]. 现代化工, 2013,33(9):36-39.
CUI Jinfeng, AN Jin, PEI Chunjuan , et al. Research progress in superhydrophobic conductive polypyrrole materials[J]. Modern Chemical Industry, 2013,33(9):36-39.
[13] LEE S, KIM B, CHEN S , et al. Layer-by-layer assembly of all carbon nanotube ultrathin films for electrochemical applications.[J]. Journal of the American Chemical Society, 2009,131(2):671-679.
doi: 10.1021/ja807059k pmid: 19105687
[14] ZOU L, ZHANG S, LI X , et al. Step-by-step strategy for constructing multilayer structured coatings toward high-efficiency electromagnetic interference shiel-ding[J]. Advanced Materials Interfaces, 2016,3(5):1-6.
[15] XIN Q, SHAH H, NAWAZ A , et al. Antibacterial carbon-based nanomaterials[J]. Advanced Materials, 2018.DOI: 10.1002/adma.201804838.
doi: 10.1002/adma.202003804 pmid: 33169472
[16] VARESANO A, VINEIS C, ALUIGI A , et al. Antibacterial efficacy of polypyrrole in textile applications[J]. Fibers and Polymers, 2013,14(1):36-42.
doi: 10.1007/s12221-013-0036-4
[17] LI M, WEI Z, JIANG L . Polypyrrole nanofiber arrays synthesized by a biphasic electrochemical strategy[J]. Journal of Materials Chemistry, 2008,18(19):2276-2280.
doi: 10.1039/b800289d
[1] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole / cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[2] JIA Lin, WANG Xixian, TAO Wenjuan, ZHANG Haixia, QIN Xiaohong. Preparation and antibacterial property of polyacrylonitrile antibacterial composite nanofiber membranes [J]. Journal of Textile Research, 2020, 41(06): 14-20.
[3] WANG Tingting, LIU Liang, CAO Xiuming, WANG Qingqing. Preparation and photodynamic antimicrobial properties of hypocrellinpoly(methyl methacrylate-co-methacrylic acid) nanofibers [J]. Journal of Textile Research, 2020, 41(05): 1-7.
[4] WANG Xiaofei, WAN Ailan. Preparation of polypyrrole / silver conductive polyester fabric by ultraviolet exposure [J]. Journal of Textile Research, 2020, 41(04): 112-116.
[5] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[6] LIN Jiameng, WAN Ailan, MIAO Xuhong. Preparation and properties of polypyrrole / silver conductive polyester fabrics [J]. Journal of Textile Research, 2020, 41(03): 113-117.
[7] WU Qianqian, LI Ke, YANG Lishuang, FU Yijun, ZHANG Yu, ZHANG Haifeng. Preparation and properties of drug-loaded polyvinylidene fluoride wound dressings [J]. Journal of Textile Research, 2020, 41(01): 26-31.
[8] JIANG Shan, WAN Ailan, MIAO Xuhong, JIANG Gaoming, MA Pibo, CHEN Qing. Influence of plasma treatment on electrical conductivity of polypyrrole/polyester composite yarn [J]. Journal of Textile Research, 2019, 40(8): 95-100.
[9] YU Fang, LIU Chengxia. Measurement for bending behavior by bowknot method [J]. Journal of Textile Research, 2019, 40(8): 35-39.
[10] CHEN Ying, ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei. Preparation and properties of polypyrrole composite fabric by soft template process [J]. Journal of Textile Research, 2019, 40(12): 93-97.
[11] ZHANG Zhibin, LI Gang, MAO Senxian, LI Xunxun, CHEN Yushuang, MAO Qingshan, LI Yi, PAN Zhijuan, WANG Xiaoqin. Preparation and antibacterial activity of silk fibroin / chitosan microspheres [J]. Journal of Textile Research, 2019, 40(10): 7-12.
[12] HE Qingqing, XU Hong, MAO Zhiping, ZHANG Linping, ZHONG Yi, LÜ Jingchun. Preparation of high-electrical conductivity polypyrrole-coated fabrics [J]. Journal of Textile Research, 2019, 40(10): 113-119.
[13] LIN Jiameng, MIAO Xuhong, WAN Ailan. Influence of plasma pretreatment on structure and properties of polypyrrole/polyester warp knitted conductive fabric [J]. Journal of Textile Research, 2019, 40(09): 97-101.
[14] WU Jiao, YU Husheng, WAN Xingyun, TIAN Ping, LI Huimin, HOU Xiaoxin. Preparation and properties of anti-bacterial, anti-mite and anti-mildew functional modified viscose fibers [J]. Journal of Textile Research, 2019, 40(07): 19-23.
[15] AN Fangfang, FANG Kuanjun, LIU Xiuming, CAI Yuqing, HAN Shuang, YANG Haizhen. Effect of wool fabric protease modification on droplet spreading and color performance [J]. Journal of Textile Research, 2019, 40(06): 58-63.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] XING Ming-jie;TANG Dian-hua;YU Chong-wen . Effect of three technologic parameters on air-jet spun yarn strength[J]. JOURNAL OF TEXTILE RESEARCH, 2005, 26(1): 49 -51 .
[2] . [J]. JOURNAL OF TEXTILE RESEARCH, 2004, 25(04): 24 -25 .
[3] YANG Ju-ping. Cross-linking flocculants of high molecule and high concentration[J]. JOURNAL OF TEXTILE RESEARCH, 2005, 26(5): 63 -64 .
[4] ZHU Zhi-feng;QIAO Zhi-yong. Causes and elimination of the foams within sizing pastes[J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(7): 86 -89 .
[5] LIN Jian-long;WANG Xiao-bei;GU Xiang. Analysis and design of new model thread-taking-up mechanism of the computerized embroidery machine[J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(12): 105 -108 .
[6] . [J]. JOURNAL OF TEXTILE RESEARCH, 1995, 16(02): 19 -22 .
[7] . [J]. JOURNAL OF TEXTILE RESEARCH, 1995, 16(02): 46 -48 .
[8] . [J]. JOURNAL OF TEXTILE RESEARCH, 1993, 14(03): 19 -21 .
[9] . [J]. JOURNAL OF TEXTILE RESEARCH, 1987, 8(02): 55 .
[10] . [J]. JOURNAL OF TEXTILE RESEARCH, 1986, 7(06): 11 -16 .
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd