Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (04): 167-173.doi: 10.13475/j.fzxb.20190304907

• Comprehensive Review • Previous Articles     Next Articles

Research progress of functionalized graphene oxide adsorption materials

WANG Jiankun(), JIANG Xiaodong, GUO Jing, YANG Lianhe   

  1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387
  • Received:2019-03-18 Revised:2020-01-03 Online:2020-04-15 Published:2020-04-27

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Abstract:

In order to promote the application of graphene oxide materials in the field of water treatment, research results in functionalized graphene oxide adsorption materials in recent years were reviewed. The paper introduced the preparation methods and structural characteristics of graphene oxide, and the functionalized graphene oxide adsorption material was divided into modified covalent bond materials and non-covalent bond composite materials. According to the chemical modification of different functional groups on graphene oxide, covalent bond modification materials were further divided into five categories: carbonyl functionalization, carboxyl functionalization, hydroxyl functionalization, epoxy functionalization, and carbon-carbon double bond functionalization. Based on the different structural shapes of composite materials, non-covalent bond composite materials were grouped into three categories: graphene oxide-based gels, graphene oxide-based separation membranes and graphene oxide-based magnetic adsorbents. Fundamental problems in functionalized graphene oxide adsorption materials were discussed, and it was pointed out that the combined functional treatment of covalent bonds and non-covalent bonds is expected to become the development direction of graphene oxide adsorption.

Key words: graphene oxide, covalent bond modification material, non-covalent bond composite, adsorption material, waste water treatment

CLC Number: 

  • TQ028.7

Tab.1

Adsorption of MB by four carbon-based materials"

吸附剂名称 吸附量/(mg·g-1) 参考文献
活性炭 277.90 [24]
碳纳米管 188.68 [25]
石墨烯 153.85 [26]
氧化石墨烯 1 095.70 [27]

Fig.1

Schematic diagram of carbonyl functional modification of GO and adsorption of acridine orange"

Fig.2

Schematic diagram of preparation and magnetic separation process of EDTA-MGO"

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