Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (04): 112-116.doi: 10.13475/j.fzxb.20190603505

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of polypyrrole/silver conductive polyester fabric by ultraviolet exposure

WANG Xiaofei1, WAN Ailan1,2()   

  1. 1. Engineering Research Center for Knitting Technology, Ministry of Education, Jiangnan University,Wuxi, Jiangsu 214122, China
    2. Key Laboratory of Eco-Textiles(Jiangnan University),Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2019-06-17 Revised:2019-09-21 Online:2020-04-15 Published:2020-04-27
  • Contact: WAN Ailan E-mail:ailan.wan@jiangnan.edu.cn

RichHTML

4

PDF (PC)

193

Abstract:

In order to obtain excellent electrical conductivity for a polyester fabric, a polypyr-role/silver (PPy/Ag) conductive polyester fabric was prepared by in-situ polymerization with ultraviolet exposure. The effects of AgNO3 concentration, sodium dodecylbenzene sulfonate(SDBS) concentration, polyvinylpyrrolidone(PVP) concentration and reaction time on the electrical conductivity of PPy/Ag conductive polyester fabric were investigated and the optimal preparation process was explored. The results show that when the low temperature vacuum plasma treatment power is set to 220 W, the treatment time is 4 min, the AgNO3 concentration is 0.4 mol/L, the SDBS concentration is 0.02 mol/L, the PVP concentration is 0.8 mol/L, the reaction time is 8 h, the composite fabric obtains the smallest sheet resistance, which is 61.54 Ω/□. There forms a continuous polypyrrole conductive film on the surface. The composite fabric demonstrats good antibacterial properties due to the presence of nano silver particles on surface and the width of the antibacterial band of escherichia coli and staphylococcus oureus is greater than 1 mm.

Key words: ultroviolet exposure, polypyrrole, conductive polyester fabric, in-situ polymerization, nano silver particle, antibacterial property

CLC Number: 

  • TS195

Fig.1

Effect of polymerization time on surface square resistance of conductive polyester fabric"

Fig.2

Effect of SDBS concentration on surface square resistance of conductive polyester fabric"

Fig.3

Effect of PVP concentration on surface square resistance of conductive polyester fabric"

Fig.4

Effect of AgNO3 concentration on surface square resistance of conductive polyester fabric"

Fig.5

SEM images of samples at different reaction conditions(×1 500). (a)Untreated fabric;(b) Conductive polyester fabric;(c) Fabric with reaction for 5 h"

Fig.6

XRD pattern of conductive polyester fabric"

Fig.7

Infrared spectra of untreated and conductive polyester fabrics"

Fig.8

Bacteriostasis test result of untreated and conductive polyester fabrics. (a) Escherichia coli;(b) Staphylococcus aureus"

Tab.1

Bacteriostatic effect of untreated and conductive polyester fabrics"

试样名称 抑菌带宽度/mm 效果评价
大肠杆菌 金黄色葡萄球菌
未处理织物 0 0 无效果
导电涤纶织物 >2 >1 效果较好
[1] 王秀昀, 聂浩宇, 阚丽丽, 等. 聚吡咯导电薄膜原位聚合工艺的研究[J]. 化工新型材料, 2014(11):184-185.
WANG Xiuyun, NIE Haoyu, KAN Lili, et al. Study on in-situ polymerization of polypyrrole conductive film[J]. New Chemical Materials, 2014(11):184-185.
[2] ULLAH M H, HA C S. In situ prepared polypyrrole-Ag nanocomposites: optical properties and morphology[J]. Journal of Materials Science, 2016, 51(16):7536-7544.
[3] ALEKSEEVA E, BOBER P, TRCHOVÁ M, et al. The composites of silver with globular or nanotubular polypyrrole: the control of silver content[J]. Synthetic Metals, 2015,209:105-111.
[4] BABU K F, DHANDAPANI P, MARUTHAMUTHU P S, et al. One pot synjournal of polypyrrole silver nanocomposite on cotton fabrics for multifunctional property[J]. Carbohydrate Polymers, 2012,90(4):1557-1563.
doi: 10.1016/j.carbpol.2012.07.030 pmid: 22944416
[5] GASHTI M P, GHEHI S T, AREKHLOO S V, et al. Electromagnetic shielding response of UV-induced polypyrrole/silver coated wool[J]. Fibers and Polymers, 2015,16(3):585-592.
[6] BHARTI M, SINGH A, SAMANTA S, et al. Flexo-green polypyrrole-silver nanocomposite films for thermoelectric power generation[J]. Energy Conversion and Management, 2017,144:143-152.
[7] ATTIA M F, AZIB T, SALMI Z, et al. One-step UV-induced modification of cellulose fabrics by polypyrrole/silver nanocomposite films[J]. Journal of Colloid and Interface Science, 2013,393:130-137.
[8] 李俊, 林俊雄, 汪澜. 聚吡咯/棉复合导电织物的制备[J]. 印染, 2010,36(14):5-7.
LI Jun, LIN Junxiong, WANG Lan. Preparation of polypyrrole/cotton composite conductive fabric[J]. China Dyeing & Finishing, 2010,36(14):5-7.
[9] CHEN A, KAMATA K, NAKAGAWA M, et al. Formation process of silver-polypyrrole coaxial nanocables synthesized by redox reaction between AgNO3 and pyrrole in the presence of poly(vinylpyrrolidone)[J]. Journal of Physical Chemistry B, 2005,109(39):18283-18288.
[10] 董猛, 田俊莹. 聚吡咯/银导电涤纶织物的开发[J]. 印染, 2015,41(22):1-4.
DONG Meng, TIAN Junying. Preparation of polypyrrole/Ag conductive polyester fabric[J]. China Dyeing & Finishing, 2015,41(22):1-4.
[11] SINGH A, SALMI Z, JOSHI N, et al. Photo-induced synjournal of polypyrrole-silver nanocomposite films on N-(3-trimethoxysilylpropyl) pyrrole-modified biaxially oriented polyethylene terephthalate flexible sub-strates[J]. RSC Advances, 2013,3(16):5506.
[12] UPADHYAY J, KUMAR A, GOGOI B, et al. Antibacterial and hemolysis activity of polypyrrole nanotubes decorated with silver nanoparticles by an in-situ reduction process[J]. Materials Science and Engineering: C, 2015,54:8-13.
[1] YU Jia, XIN Binjie, ZHUO Tingting, ZHOU Xi. Preparation and characterization of Cu/polypyrrole-coated wool fabrics for high electrical conductivity [J]. Journal of Textile Research, 2021, 42(01): 112-117.
[2] LI Junyu, JIANG Peiqing, ZHANG Wenqi, LI Wenbin. Effect of atomic layer deposition technology on functionalization of cellulose membrane [J]. Journal of Textile Research, 2020, 41(12): 26-30.
[3] JIANG Xingmao, LIU Qi, GUO Lin. Structure and antibacterial properties of silica coated silver-copper nanoparticles [J]. Journal of Textile Research, 2020, 41(11): 102-108.
[4] ZHANG Yanyan, ZHAN Luyao, WANG Pei, GENG Junzhao, FU Feiya, LIU Xiangdong. Research progress in preparation of durable antibacterial cotton fabrics with inorganic nanoparticles [J]. Journal of Textile Research, 2020, 41(11): 174-180.
[5] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole / cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[6] JIA Lin, WANG Xixian, TAO Wenjuan, ZHANG Haixia, QIN Xiaohong. Preparation and antibacterial property of polyacrylonitrile antibacterial composite nanofiber membranes [J]. Journal of Textile Research, 2020, 41(06): 14-20.
[7] WANG Tingting, LIU Liang, CAO Xiuming, WANG Qingqing. Preparation and photodynamic antimicrobial properties of hypocrellinpoly(methyl methacrylate-co-methacrylic acid) nanofibers [J]. Journal of Textile Research, 2020, 41(05): 1-7.
[8] HU Chengye, MIAO Runwu, HAN Xiao, HONG Jianhan, GIL Ignacio. Effect of polyvinyl alcohol on durability of polyaniline conductive layer on poly(p-phenylene terephthamide) yarn surface [J]. Journal of Textile Research, 2020, 41(04): 91-97.
[9] WU Yingxin, HU Chengye, ZHOU Xiaoya, HAN Xiao, HONG Jianhan, GIL Ignacio. Strain sensing property of flexible wearable spandex/polyaniline/polyurethane composites [J]. Journal of Textile Research, 2020, 41(04): 21-25.
[10] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[11] LIN Jiameng, WAN Ailan, MIAO Xuhong. Preparation and properties of polypyrrole / silver conductive polyester fabrics [J]. Journal of Textile Research, 2020, 41(03): 113-117.
[12] WU Qianqian, LI Ke, YANG Lishuang, FU Yijun, ZHANG Yu, ZHANG Haifeng. Preparation and properties of drug-loaded polyvinylidene fluoride wound dressings [J]. Journal of Textile Research, 2020, 41(01): 26-31.
[13] CHEN Ying, ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei. Preparation and properties of polypyrrole composite fabric by soft template process [J]. Journal of Textile Research, 2019, 40(12): 93-97.
[14] ZHANG Jiao, GAO Xuefeng, WANG Yuzhou, LIU Haihui, ZHANG Xingxiang. Preparation and properties of polyamide 66/amino-functionalized multi-walled carbon nanotubes fibers [J]. Journal of Textile Research, 2019, 40(11): 1-8.
[15] ZHANG Zhibin, LI Gang, MAO Senxian, LI Xunxun, CHEN Yushuang, MAO Qingshan, LI Yi, PAN Zhijuan, WANG Xiaoqin. Preparation and antibacterial activity of silk fibroin/chitosan microspheres [J]. Journal of Textile Research, 2019, 40(10): 7-12.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd