Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (05): 94-98.doi: 10.13475/j.fzxb.20190704206

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of berberine in polyacrylonitrile/cellulose acetate composite fiber dyeing

LIU Yanchun1,2, BAI Gang1,2()   

  1. 1. School of Textile and Apparel, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
  • Received:2019-07-12 Revised:2019-10-04 Online:2020-05-15 Published:2020-06-02
  • Contact: BAI Gang E-mail:gbg2000@21cn.com

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Abstract:

In order to widen the application domain of berberine, the physical and chemical properties of berberine were studied. Dyeing of polyacrylonitrile/cellulose acetate composite fibers with berberine was also investigated in this research. The dyeing process of polyacrylonitrile/cellulose acetate composite fiber with berberine was optimized through the use of orthogonal test. The dyeing rate curve and adsorption isotherm were determined, and the antimicrobial activity of dyed samples against Staphylococcus aureus and Escherichia coli was tested. The results indicate that berberine can be dissolved in water, and it has good acid and alkali resistance in the pH range of 3-11 and good thermal stability below 120 ℃. The dyeing adsorption isotherm of berberine on polyacrylonitrile/cellulose acetate composite fiber present Langmuir sorption model. The half dyeing time of berberine is 15.5 minutes, and the percentage of equilibrium dyeing is 97%. The best dyeing condition of berberine is found to be: dyeing temperature is 100 ℃, dyeing time is 40 min, dyeing pH value is 8. After dyeing, the bacteriostatic rate of polyacrylonitrile/cellulose acetate composite fiber to Staphylococcus aureus and Escherichia coli is over 92%.

Key words: berberine, natural dye, polyacrylonitrile/cellulose acetate composite fiber, physical and chemical properties, fiber dyeing, antimicrobial property

CLC Number: 

  • TS193.62

Fig.1

Visible spectrum of berberine"

Tab.1

Effect of pH on stability of berberine"

pH值 λmax/nm 吸光度A
3 420 0.270
5 419 0.271
7 421 0.266
9 420 0.268
11 420 0.263

Tab.2

Effect of temperature on heat-stability of berberine"

温度/℃ λmax/nm 吸光度A
40 419 0.272
60 421 0.269
80 421 0.274
100 419 0.274
120 420 0.272

Fig.2

TG and DTA curves of berberine"

Tab.3

Factors and levels of orthogonal experiments for dyeing"

水平 A B C
染色温度/℃ 保温时间/min pH值
1 40 10 5
2 60 20 7
3 80 30 8
4 100 40 9

Tab.4

Results of orthogonal experiments for dyeing"

试验号 A B C K/S值
1 1 1 1 2.784 2
2 1 2 2 3.345 1
3 1 3 3 4.427 6
4 1 4 4 4.158 1
5 2 1 2 4.791 4
6 2 2 1 5.383 6
7 2 3 4 5.624 4
8 2 4 3 5.916 2
9 3 1 3 5.612 1
10 3 2 4 6.536 2
11 3 3 1 6.335 7
12 3 4 2 6.714 8
13 4 1 4 6.428 6
14 4 2 3 7.165 8
15 4 3 2 6.802 5
16 4 4 1 6.512 9
K1 3.679 4.904 5.254
K2 5.429 5.608 5.413
K3 6.300 5.798 5.780
K4 6.727 5.825 5.687
R 3.048 0.921 0.526

Fig.3

Rate of berberine dyeing curves"

Fig.4

Adsorption isotherm of berberine"

Fig.5

Building-up property curve of berberine"

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