Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (06): 93-98.doi: 10.13475/j.fzxb.20190900606

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics

CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying()   

  1. State Key Laboratory for Hubei New Textile Materials and Advanced Processing Technology, Wuhan Textile University, Wuhan, Hubei 430020, China
  • Received:2019-09-02 Revised:2020-02-28 Online:2020-06-15 Published:2020-06-28
  • Contact: ZUO Danying E-mail:zdy@wtu.edu.cn

RichHTML

9

PDF (PC)

266

Abstract:

In order to improve the UV-resistant ability of cotton fabrics, boron-nitrogen-doped carbon dots (BN-CDs) were synthesized by a one-step hydrothermal method with citric acid, ethylenediamine and borax as raw materials. BN-CDs aqueous solution, BN-CDs/PVA aqueous solution and BN-CDs/waterborne polyurethane aqueous solution were sprayed on the surface of cotton fabric, respectively, and then the cotton fabric was rolled and dried. The results show that the prepared BN-CD is a graphite-like nanocrystal having a rich hydroxyl group and amine group on the surface, which make BN-CDs soluble in water. BN-CDs has a strong absorption peak in the ultraviolet region, and could emit bright blue fluorescence which is independent of excitation wavelengths. The finished cotton fabrics show high UV protection factors (UPF), BN-CDs/WPU finishing has the optimal effect. After 10 times washing, the UPF value remained at around 48, achieving the excellent protection level. The surface morphology of the cotton fabric is basically unchanged, and the hand feel was good, and meeting the ultraviolet protection requirement of the cotton fabrics.

Key words: boron nitrogen doping, carbon dot, cotton fabric, UV resistance, UV protection value, water washing performance

CLC Number: 

  • TS195.5

Fig.1

FT-IR spectrum of BN-CDs"

Fig.2

TEM image of BN-CDs"

Fig.3

UV-vis absorption spectra of BN-CDs and its photoluminescence (PL) excitation"

Fig.4

Irradiation pattern of BN-CDs under 365 nm UV lamp"

Fig.5

PL emission spectra of BN-CDs excited by different wavelengths"

Fig.6

Infrared spectrum of cotton. (a) Cotton fabrics finished with different solutions; (b) Cotton fabrics finished with different solutions after washing for 10 times"

Tab.1

UV protection factor of cotton fabric samples after finishing and different washing times"

编号 初始棉布 整理后 洗1次 洗2次 洗5次 洗10次
F1 31.2 130.5 39.5 44.0 35.3 36.3
F2 31.4 170.2 124.7 103.0 91.1 61.7
F3 31.2 97.1 53.0 49.2 48.4 50.1

Fig.7

Mass change rate of cotton fabric with washing times after finishing"

[1] QU L, TIAN M, HU X, et al. Functionalization of cotton fabric at low graphene nanoplate content for ultrastrong ultraviolet blocking[J]. Carbon, 2014,80(1):565-574.
[2] 王晓菊, 王晓云. 抗紫外线纺织品的研究新进展[J]. 纺织导报, 2017(6):74-77.
WANG Xiaoju, WANG Xiaoyun. New research progress on ultraviolet resistant textiles[J]. China Textile Leader, 2017 (6):74-77.
[3] SHAHEEN T I, El-NAGGAR M E, ABDELGAWAD A M, et al. Durable antibacterial and UV protections of in situ synthesized zinc oxide nanoparticles onto cotton fabrics[J]. International Journal of Biological Macromolecules, 2016,83:426-432.
doi: 10.1016/j.ijbiomac.2015.11.003 pmid: 26546870
[4] EMAM H E, ABDELHAMEED R M. Anti UV radiation textiles designed by embracing with nano MIL (Ti, In)-metal organic framework[J]. Acs Applied Materials & Interfaces, 2017,9(33):28034-28045.
pmid: 28745870
[5] TANG X, TIAN M, QU L, et al. Functionalization of cotton fabric with graphene oxide nanosheet and polyaniline for conductive and UV blocking pro-perties[J]. Synthetic Metals, 2015,202:82-88.
[6] 梁慧, 张光先, 张凤秀, 等, 紫外线纳米二氧化钛改性高亲水涤纶织物的制备[J]. 纺织学报, 2013,34(3):82-86.
LIANG Hui, ZHANG Guangxian, ZHANG Fengxiu, et al. Preparation of highly hydrophilic polyester fabrics via UV irradiation/nano-TiO2 modification[J]. Journal of Textile Research, 2013,34(3):82-86.
[7] 李瑞雪, 沈小林, 张兴亚, 等. 原位生成二氧化钛对棉纤维抗紫外线性能的影响[J]. 纺织学报, 2016,37(3):78-81.
LI Ruixue, SHEN Xiaolin, ZHANG Xingya, et al. Study on anti-UV property of cotton fibers by in-situ generation of TiO2[J]. Journal of Textile Research, 2016,37(3):78-81.
[8] 宫国梁, 张朋, 赵德丰. 含苯并三唑基团抗紫外辐射活性染料合成与应用性能研究[J]. 大连理工大学学报, 2009,49(1):24-27.
GONG Guoliang, ZHANG Peng, ZHAO Defeng. Synjournal and application properties of anti-uv radiation reactive dyes containing benz-otriazole groups[J]. Journal of Dalian University of Technology, 2009,49(1):24-27.
[9] 陈和春, 尹桂波. 双元配体转光剂的合成及其在防紫外线织物中的应用[J]. 纺织学报, 2014,35(5):83-86.
CHEN Hechun, YIN Guibo. Synjournal of dual ligand rare-earth light conversion agent and its application on UV-protection fabric[J]. Journal of Textile Research, 2014,35(5):83-86.
[10] BONET-ARACIL M Á, DIAZ-GARCIA P, BOU-BELDA E, et al. UV protection from cotton fabrics dyed with different tea extracts[J]. Dyes & Pigments, 2016,134:448-452.
[11] LIM S Y, SHEN W, GAO Z. Carbon quantum dots and their applications[J]. Chemical Society Reviews, 2015,44(1):362-81.
pmid: 25316556
[12] 陶咏真, 鄢芸, 徐卫林, 等. 丝素蛋白与聚氨酯共混膜的制备及结构和性能[J]. 高分子学报, 2010,31(1):27-32.
TAO Yongzhen, YAN Yun, XU Weilin, et al. Preparation, structure and properties of silk fibroin and polyurethane blend membrane[J]. Journal of Polymer Science, 2010,31(1):27-32.
[13] HEBEISH A, SHARAF S, FAROUK A. Utilization of chitosan nanoparticles as a green finish in multifunctionalization of cotton textile[J]. International Journal of Biological Macromolecules, 2013,60(9):10-17.
[14] LI Z, YU H, BIAN T, et al. Highly luminescent nitrogen-doped carbon quantum dots as effective fluorescent probes for mercuric and iodide ions[J]. Journal of Materials Chemistry C, 2015,3(9):1922-1928.
[15] ZHANG Y Q, MA D K, ZHUANG Y, et al. Onepot synjournal of N-doped carbon dots with tunable luminescence properties[J]. Journal of Materials Chemistry, 2012,22(33):16714-16718.
[16] CHEN X, ZHANG W, WANG Q, et al. C8-structured carbon quantum dots: synjournal, blue and green double luminescence, and origins of surface defects[J]. Carbon, 2014,79:165-173.
[17] RAJABOOPATHI S, THAMBIDURAI S. Evaluation of UPF and antibacterial activity of cotton fabric coated with colloidal seaweed extract functionalized silver nanoparticles[J]. Journal of Photochemistry & Photobiology B: Biology, 2018,183:75-87
[1] HOU Wenshuang, MIN Jie, JI Feng, ZHANG Jianxiang, SU Meng, HE Ruixian. Influence of fabric tightness and anti-crease finishing on wrinkle recovery of pure cotton woven fabrics [J]. Journal of Textile Research, 2021, 42(01): 118-124.
[2] ZENG Fanxin, QIN Zongyi, SHEN Yueying, CHEN Yuanyu, HU Shuo. Preparation and flame retardant properties of self-extinguishing cotton fabrics by spray-assisted layer-by-layer self-assembly technology [J]. Journal of Textile Research, 2021, 42(01): 103-111.
[3] ZHANG Yanyan, ZHAN Luyao, WANG Pei, GENG Junzhao, FU Feiya, LIU Xiangdong. Research progress in preparation of durable antibacterial cotton fabrics with inorganic nanoparticles [J]. Journal of Textile Research, 2020, 41(11): 174-180.
[4] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole/cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[5] LIU Guojin, SHI Feng, CHEN Xinxiang, ZHANG Guoqing, ZHOU Lan. Preparation of polyurethane/phase change wax functional finishing agents for heat storage and temperature regulation and their applications on cotton fabrics [J]. Journal of Textile Research, 2020, 41(07): 129-134.
[6] ZHOU Qingqing, CHEN Jiayi, QI Zhenming, CHEN Weijian, SHAO Jianzhong. Preparation and characterization of flame retardant and antibacterial cotton fabric [J]. Journal of Textile Research, 2020, 41(05): 112-120.
[7] TAN Lin, SHI Yidong, ZHOU Wenya. Study on enhancement of hydrophobicity treatment of cotton fabrics using silica sol [J]. Journal of Textile Research, 2020, 41(04): 106-111.
[8] WEI Tengxiang, LI Min, PENG Hongyun, FU Shaohai. Relationship between open-width mercerization condition and loop structure of weft plain-knitted cotton fabrics [J]. Journal of Textile Research, 2020, 41(04): 98-105.
[9] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[10] GAO Simeng, WANG Hongbo, DU Jinmei, WANG Wencong. Synthesis of polybetaine antibacterial agent and its applications in cotton textiles finishing [J]. Journal of Textile Research, 2020, 41(02): 89-94.
[11] YI Ling, ZHANG He, FU Xin, LI Wen. Preparation and far-infrared emission performance of graphene based zirconium / titanium composites modified cotton fabrics [J]. Journal of Textile Research, 2020, 41(01): 102-109.
[12] LI Yuzhou, ZHANG Yufan, ZHOU Qingqing, CHEN Guoqiang, XING Tieling. Preparation and electrochemical properties of MnO2 / graphene / cotton fabric composite electrode [J]. Journal of Textile Research, 2020, 41(01): 96-101.
[13] CHEN Ying, ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei. Preparation and properties of polypyrrole composite fabric by soft template process [J]. Journal of Textile Research, 2019, 40(12): 93-97.
[14] CUI Yifan, HOU Wei, ZHOU Qianxi, YAN Jun, LU Yanhua, HE Tingting. Influence of silk sericin temperature sensitive hydrogel on properties of cotton fabrics [J]. Journal of Textile Research, 2019, 40(12): 74-78.
[15] SUN Yufa, ZHOU Xiangdong. Synthesis and characterization of novel phosphorous and nitrogen-containing flame retardant for cotton fabrics [J]. Journal of Textile Research, 2019, 40(12): 79-85.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd