Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (10): 101-106.doi: 10.13475/j.fzxb.20191102506

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and electric storage performance of stretchable polypyrrole/cotton knitted fabric

WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia()   

  1. College of Textile Science and Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2019-11-08 Revised:2020-06-30 Online:2020-10-15 Published:2020-10-27
  • Contact: WANG Chaoxia E-mail:wchaoxia@sohu.com

Abstract:

To endow knitted cotton fabrics with new function such as conductance and electricity storage for wearable devices, pyrrole monomers were in-situ polymerized on a knitted cotton fabric to fabricate the polypyrrole/cotton knitted fabric. Scanning electron microscope and Fourier transform infrared spectra were used to detect the morphologies and chemical structures of the polypyrrole/cotton knitted fabric. The surface resistances and the electrochemical performances of polypyrrole/cotton knitted fabric at different tensile strain were also measured. The results show that sufficient polypyrrole is coated on knitted cotton fibers, and the surface resistances decreases from 429.2 Ω to 231.4 Ω when the strain is changed from 0% to 40%. The areal capacitance of the polypyrrole/cotton knitted fabric is 680.6 mF/cm 2 at the scan rate of 5 mV/s, and is 1 014.2 mF/cm2 at the current density of 2 mA/cm2. The symmetric supercapacitor device prepared from the polypyrrole/cotton knitted fabric shows an areal capacitance of 229.8 mF/cm2 at 1 mA/cm2 and 161.5 mF/cm2 at 5 mA/cm2, and this device exhibits a capacitance retention of 76.3% after 10 000 galvanostatic charging/discharging cycles.

Key words: conductive fabric, strain sensor, polypyrrole, cotton fabric, electrode, supercapacitor

CLC Number: 

  • TS106

Fig.1

Morphologies of cotton knitted fabric and PPy/cotton knitted fabric. (a) Cotton knitted fabric (×100); (b) Cotton knitted fabric (×3 000); (c) PPy/knitted cotton fabric (×100); (d) PPy/cotton knitted fabric (×5 000)"

Fig.2

FT-IR spectra of cotton knitted fabric and PPy/cotton knitted fabric"

Fig.3

Surface resistances of PPy/cotton knitted fabric at different strains(a) and its monitoring function for finger bending(b)"

Fig.4

Electrochemical performances of PPy/knitted cotton fabric tested in three-electrode system. (a) Cyclic voltammetry curves; (b) Areal capacitances and scan rates curve; (c) Voltage-time curves; (d) Areal capacitances and current densities curve"

Fig.5

Electrochemical performances of symmetric device based on PPy/cotton knitted fabric tested in two-electrode system. (a) Cyclic voltammetry curves; (b) Areal capacitances and scan rates curve; (c) Voltage and time curves; (d) Areal capacitances current densities curve"

Fig.6

Energy density and power density curve(a), capacitance retention and coulombic efficiency(b) of symmetric device based on PPy/cotton knitted fabric"

[1] 杨静, 刘艳君. 石墨烯-棉针织物电极材料的制备及其性能[J]. 纺织学报, 2019,40(3):90-95.
YANG Jing, LIU Yanjun. Preparation and properties of graphene-knitted electrode materials[J]. Journal of Textile Research, 2019,40(3):90-95.
[2] 王栋, 卿星, 蒋海青, 等. 纤维材料与可穿戴技术的融合与创新[J]. 纺织学报, 2018,39(5):150-154.
WANG Dong, QING Xing, JIANG Haiqing, et al. Integration and innovation of fiber materials and wearable technology[J]. Journal of Textile Research, 2018,39(5):150-154.
[3] SARMAH Devalina, KUMAR Ashok. Ion beam modified molybdenum disulfide-reduced graphene oxide/polypyrrole nanotubes ternary nanocomposite for hybrid supercapacitor electrode[J]. Electrochimica Acta, 2019,312:392-410.
doi: 10.1016/j.electacta.2019.04.174
[4] CHEN Yong, ZHANG Xia, XU Cheng, et al. The fabrication of asymmetry supercapacitor based on MWCNTs/MnO2/PPy composites[J]. Electrochimica Acta, 2019,309:424-431.
doi: 10.1016/j.electacta.2019.04.072
[5] 董科, 张玲, 范佳璇, 等. 织物电极监测心电信号与穿戴压力作用机制分析[J]. 纺织学报, 2019,40(9):75-82.
DONG Ke, ZHANG Ling, FAN Jiaxuan, et al. Action mechanism of wearing pressure on electrocardiogram monitoring of woven fabric electrodes[J]. Journal of Textile Research, 2019,40(9):75-82.
doi: 10.1177/004051757004000111
[6] 陈阳, 张占柱. 石墨烯用于棉织物防静电整理的研究[J]. 棉纺织技术, 2019,47(1):35-38.
CHEN Yang, ZHANG Zhanzhu. Study of graphene used for the anti-static finishing of cotton fabric[J]. Cotton Textile Technology, 2019,47(1):35-38.
[7] LV Jingchun, ZHOU Peiwen, ZHANG Linping, et al. High-performance textile electrodes for wearable electronics obtained by an improved in situ polymerization method[J]. Chemical Engineering Journal, 2019,361:897-907.
doi: 10.1016/j.cej.2018.12.083
[8] LI Xin, SUN Chao, CAI Zaisheng, et al. High-performance all-solid-state supercapacitor derived from PPy coated carbonized silk fabric[J]. Applied Surface Science, 2019,473:967-975.
doi: 10.1016/j.apsusc.2018.12.244
[9] 何青青, 徐红, 毛志平, 等. 高导电性聚吡咯涂层织物的制备[J]. 纺织学报, 2019,40(10):113-119.
HE Qingqing, XU Hong, MAO Zhiping, et al. Preparation of high-electrical conductivity polypyrrole-coated fabrics[J]. Journal of Textile Research, 2019,40(10):113-119.
[10] KULANDAIVALU Shalini, SUHAIMI Nadhrah, SULAIMAN Yusran. Unveiling high specific energy supercapacitor from layer-by-layer assembled polypyrrole/graphene oxide|polypyrrole/manganese oxide electrode material[J]. Scientific Reports, 2019,9(1):4884.
doi: 10.1038/s41598-019-41203-3 pmid: 30894621
[11] SHIVAKUMARA S, MUNICHANDRAIAH N. In-situ preparation of nanostructured α-MnO2/polypyrrole hybrid composite electrode materials for high performance supercapacitor[J]. Journal of Alloys and Compounds, 2019,787:1044-1050.
doi: 10.1016/j.jallcom.2019.02.131
[12] SUN Chao, LI Xin, CAI Zaisheng, et al. Carbonized cotton fabric in-situ electrodeposition polypyrrole as high-performance flexible electrode for wearable supercapacitor[J]. Electrochimica Acta, 2019,296:617-626.
doi: 10.1016/j.electacta.2018.11.045
[13] KULANDAIVALU Shalini, SULAIMAN Yusran. Designing an advanced electrode of mixed carbon materials layered on polypyrrole/reduced graphene oxide for high specific energy supercapacitor[J]. Journal of Power Sources, 2019,419:181-191.
doi: 10.1016/j.jpowsour.2019.02.079
[14] YUN Junyeong, SONG Changhoon, LEE Hanchan, et al. Stretchable array of high-performance micro-supercapacitors charged with solar cells for wireless powering of an integrated strain sensor[J]. Nano Energy, 2018,49:644-654.
doi: 10.1016/j.nanoen.2018.05.017
[15] YUE Binbin, WANG Caiyun, DING Xin, et al. Electrochemically synthesized stretchable polypyrrole/fabric electrodes for supercapacitor[J]. Electrochimica Acta, 2013,113:17-22.
doi: 10.1016/j.electacta.2013.09.024
[16] HU Liangbing, PASTA Mauro, MANTIA Fabio La, et al. Stretchable, porous, and conductive energy textiles[J]. Nano Letters, 2010,10(2):708-714.
doi: 10.1021/nl903949m pmid: 20050691
[17] YUE Binbin, WANG Caiyun, DING Xin, et al. Polypyrrole coated nylon lycra fabric as stretchable electrode for supercapacitor applications[J]. Electrochimica Acta, 2012,68:18-24.
doi: 10.1016/j.electacta.2012.01.109
[18] DONG Liubing, LIANG Gemeng, XU Chengjun, et al. Stacking up layers of polyaniline/carbon nanotube networks inside papers as highly flexible electrodes with large areal capacitance and superior rate capability[J]. Journal of Materials Chemistry A, 2017,5(37):19934-19942.
doi: 10.1039/C7TA06135H
[19] YU Miao, HAN Yingying, LI Yao, et al. Polypyrrole-anchored cattail biomass-derived carbon aerogels for high performance binder-free supercapacitors[J]. Carbohydrate Polymers, 2018,199:555-562.
doi: 10.1016/j.carbpol.2018.04.058 pmid: 30143162
[20] WANG Siliang, LIU Nishuang, RAO Jiangyu, et al. Vertical finger-like asymmetric supercapacitors for enhanced performance at high mass loading and inner integrated photodetecting systems[J]. Journal of Materials Chemistry A, 2017,5(42):22199-22207.
doi: 10.1039/C7TA06306G
[21] BAI Yang, LIU Rong, LI Enyuan, et al. Graphene/carbon nanotube/bacterial cellulose assisted supporting for polypyrrole towards flexible supercapacitor applications[J]. Journal of Alloys and Compounds, 2019,777:524-530.
doi: 10.1016/j.jallcom.2018.10.376
[22] ZHANG Yan, JI Tengxiao, HOU Shihui, et al. All-printed solid-state substrate-versatile and high-performance micro-supercapacitors for in situ fabricated transferable and wearable energy storage via multi-material 3D printing[J]. Journal of Power Sources, 2018,403:109-117.
doi: 10.1016/j.jpowsour.2018.09.096
[23] BARAKZEHI Marjan, MONTAZER Majid, SHARIF Farhad, et al. A textile-based wearable supercapacitor using reduced graphene oxide/polypyrrole com-posite[J]. Electrochimica Acta, 2019,305:187-196.
doi: 10.1016/j.electacta.2019.03.058
[1] HOU Wenshuang, MIN Jie, JI Feng, ZHANG Jianxiang, SU Meng, HE Ruixian. Influence of fabric tightness and anti-crease finishing on wrinkle recovery of pure cotton woven fabrics [J]. Journal of Textile Research, 2021, 42(01): 118-124.
[2] YU Jia, XIN Binjie, ZHUO Tingting, ZHOU Xi. Preparation and characterization of Cu/polypyrrole-coated wool fabrics for high electrical conductivity [J]. Journal of Textile Research, 2021, 42(01): 112-117.
[3] ZENG Fanxin, QIN Zongyi, SHEN Yueying, CHEN Yuanyu, HU Shuo. Preparation and flame retardant properties of self-extinguishing cotton fabrics by spray-assisted layer-by-layer self-assembly technology [J]. Journal of Textile Research, 2021, 42(01): 103-111.
[4] WANG He, WANG Hongjie, RUAN Fangtao, FENG Quan. Preparation and properties of carbon nanofiber electrode made from electrospun polyacrylonitrile/linear phenolic resin [J]. Journal of Textile Research, 2021, 42(01): 22-29.
[5] WANG Jilong, LIU Yan, JING Yuanyuan, XU Qingli, QIAN Xiangyu, ZHANG Yihong, ZHANG Kun. Advances in fiber-based wearable electronic devices [J]. Journal of Textile Research, 2020, 41(12): 157-165.
[6] ZHANG Yanyan, ZHAN Luyao, WANG Pei, GENG Junzhao, FU Feiya, LIU Xiangdong. Research progress in preparation of durable antibacterial cotton fabrics with inorganic nanoparticles [J]. Journal of Textile Research, 2020, 41(11): 174-180.
[7] HAN Jiarui, HUANG Zhenzhen, WANG Jiajun, YIN Hao, GAO Jing, LAO Jihong, WANG Lu. Preparation and cytotoxicity analysis of flexible metal electrodes for medical dressings [J]. Journal of Textile Research, 2020, 41(09): 174-182.
[8] LIU Guojin, SHI Feng, CHEN Xinxiang, ZHANG Guoqing, ZHOU Lan. Preparation of polyurethane/phase change wax functional finishing agents for heat storage and temperature regulation and their applications on cotton fabrics [J]. Journal of Textile Research, 2020, 41(07): 129-134.
[9] CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying. Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics [J]. Journal of Textile Research, 2020, 41(06): 93-98.
[10] ZHOU Qingqing, CHEN Jiayi, QI Zhenming, CHEN Weijian, SHAO Jianzhong. Preparation and characterization of flame retardant and antibacterial cotton fabric [J]. Journal of Textile Research, 2020, 41(05): 112-120.
[11] WANG Xiaofei, WAN Ailan. Preparation of polypyrrole/silver conductive polyester fabric by ultraviolet exposure [J]. Journal of Textile Research, 2020, 41(04): 112-116.
[12] TAN Lin, SHI Yidong, ZHOU Wenya. Study on enhancement of hydrophobicity treatment of cotton fabrics using silica sol [J]. Journal of Textile Research, 2020, 41(04): 106-111.
[13] WEI Tengxiang, LI Min, PENG Hongyun, FU Shaohai. Relationship between open-width mercerization condition and loop structure of weft plain-knitted cotton fabrics [J]. Journal of Textile Research, 2020, 41(04): 98-105.
[14] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[15] ZHANG Jiahui, WANG Jianping. Electric conduction and resistance theory model of circular weft knitted electrodes [J]. Journal of Textile Research, 2020, 41(03): 56-61.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!