Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (12): 182-188.doi: 10.13475/j.fzxb.20200305507

• Comprehensive Review • Previous Articles    

Research progress of bio-based lignin flame retardant and its applications

XIAO Mengyuan1, ZHOU Xinke1, ZHANG Jiayue1, REN Yuanlin1,2()   

  1. 1. School of Textile Science and Technology, Tiangong University, Tianjin 300387, China
    2. Key Laboratory of Advanced Textile Composite, Ministry of Education, Tiangong University, Tianjin 300387, China
  • Received:2020-03-23 Revised:2020-09-22 Online:2020-12-15 Published:2020-12-23
  • Contact: REN Yuanlin E-mail:yuanlinr@163.com

RichHTML

26

PDF (PC)

1186

Abstract:

Lignin is a flame retardant material with complex chemical structure and low flame retardant efficiency, the research status of lignin in flame retardant materials at home and abroad was reviewed. This paper introduced four types of lignin flame retardants: single-component lignin-based flame retardants, lignin-based composite flame retardants, chemically modified lignin flame retardants and nano-lignin flame retardants. The specific role and problems of lignin in the flame retardant system was reviewed and analyzed. The characteristics and flame retardant mechanisms of all types of flame retardants were examined, leading to proposals of lignin development direction as bio-based flame retardants. The review revealed that among the four types of flame retardants, lignin-based composite flame retardants and chemically modified lignin flame retardants have the best flame retardant properties, and the combination of lignin with other materials and structural modification of lignin will be the focus of future research.

Key words: lignin, bio-based flame retardant, chemical modification, functional material, flame retardant material

CLC Number: 

  • TS195.2

Fig.1

SEM images of residual carbon of PBS. (a) Pure PBS; (b) PBS with 2.5% lignin; (c) PBS with 2.5% modified-lignin; (d) PBS with 10% modified-lignin"

[1] BOURBIGOT S, DUQUESNE S. Fire retardant polymers: recent developments and opportunities[J]. Journal of Materials Chemistry, 2007,17(22):2283.
[2] 陈沁, 赵涛. 阻燃纤维及纺织品的研究进展[J]. 印染, 2015,41(5):49-54.
CHEN Qin, ZHAO Tao. Research development of flame retardant fibers and textiles[J]. China Dyeing & Finishing, 2015,41(5):49-54.
[3] 鲁哲宏, 康兴隆, 冯伟丽, 等. 生物质阻燃剂的研究进展[J]. 河南大学学报(自然科学版), 2018,48(6):710-716.
LU Zhehong, KANG Xinglong, FENG Weili, et al. Research progress of bio-based flame retardants[J]. Journal of Henan University(Natural Science Edition), 2018,48(6):710-716.
[4] 陈璐怡, 许素新, 王碧佳. 木质素的预处理和工业应用的新进展[J]. 南通职业大学学报, 2012,26(1):100-104.
CHEN Luyi, XU Suxin, WANG Bijia. The pretreatment and new development of lignin in industrial applica-tion[J]. Journal of Nantong Vocational College, 2012,26(1):100-104.
[5] 陶磊, 黄元波, 郑云武, 等. 木质素制备低成本碳纤维的研究进展[J]. 高分子材料科学与工程, 2017,33(1):179-185, 190.
TAO Lei, HUANG Yuanbo, ZHENG Yunwu, et al. Review on the low-cost carbon fiber from lignin as precursors[J]. Polymer Materials Science & Engineering, 2017,33(1):179-185,190.
[6] GEUNYOO C, MENG X, PU Y, et al. The critical role of lignin in lignocellulosic biomass conversion and recent pretreatment strategies: a comprehensive review[J]. Bioresource Technology, 2020,301:122784.
pmid: 31980318
[7] LIU Wujun, JIANG Hong, YU Hanqing. Thermochemical conversion of lignin to functional materials: a review and future directions[J]. Green Chemistry, 2015,17(11):4888-4907.
[8] FEOFILOVA E P, MYSYAKINA I S. Lignin: chemical structure, biodegradation, and practical application (a review)[J]. Applied Biochemistry & Microbiology, 2016,52(6):573-581.
[9] 任苗苗, 吕惠生, 张敏华, 等. 木质素资源利用的研究进展[J]. 高分子通报, 2012(8):44-49.
REN Miaomiao, LV Huisheng, ZHANG Minhua, et al. Research progress on the application of lignin[J]. Polymer Bulletin, 2012(8):44-49.
[10] SHI Zhengjun, MA Mingguo. Synjournal, structure, and applications of lignin-based carbon materials: a review[J]. Science of Advanced Materials, 2019,11(1):18-32.
[11] CANETTI M, BERTINI F, CHIRICO A D, et al. Thermal degradation behaviour of isotactic polypropylene blended with lignin[J]. Polymer Degradation and Stability, 2006,91(3):494-498.
[12] SONG Pingan, CAO Zhenhu, FU Shenyuan, et al. Thermal degradation and flame retardancy properties of ABS/lignin: effects of lignin content and reactive compatibilization[J]. Thermochimica Acta, 2011,518(1/2):59-65.
[13] YANG Haitang, YU Bin, XU Xiaodong, et al. Lignin-derived bio-based flame retardants toward high-performance sustainable polymeric materials[J]. Green Chemistry, 2020,22:2129-2161.
doi: 10.1039/D0GC00449A
[14] 陈涛, 许肖丽, 汪济奎, 等. 无卤膨胀阻燃剂研究进展[J]. 上海塑料, 2017(4):1-8.
CHEN Tao, XU Xiaoli, WANG Jikui, et al. Research progress in halogen-free intumescent flame retar-dants[J]. Shanghai Plastics, 2017(4):1-8.
[15] 白洁, 薛宝霞, 杨雅茹, 等. 壳聚糖/聚磷酸铵膨胀阻燃PP的阻燃及抑烟性能[J]. 工程塑料应用, 2017,45(7):119-123.
BAI Jie, XUE Baoxia, YANG Yaru, et al. Flame retardancy and smoke suppression of intumescent flame retardant PP with chitosan/ammonium phosphate[J]. Engineering Plastics Application, 2017,45(7):119-123.
[16] 何小芳, 张崇, 代鑫, 等. 聚磷酸铵膨胀型阻燃剂在聚合物中应用的研究进展[J]. 塑料助剂, 2011(2):14-17,38.
HE Xiaofang, ZHANG Chong, DAI Xin, et al. Research progresses in application of ammonium polyphosphate intumescent flame retardants for polymer[J]. Plastics Additives, 2011(2):14-17,38.
[17] VERDOLOTTI L, OLIVIERO M, LAVORGNA M, et al. On revealing the effect of alkaline lignin and ammonium polyphosphate additives on fire retardant properties of sustainable zein-based composites[J]. Polymer Degradation and Stability, 2016,134:115-125.
[18] CAYLA A, RAULT F, GIRAUD S, et al. Influence of ammonium polyphosphate/lignin ratio on thermal and fire behavior of biobased thermoplastic: the case of polyamide 11[J]. Materials, 2019,12(7):1146.
doi: 10.3390/ma12071146
[19] 王佳楠, 边勇军, 羿颖, 等. 碱木质素/聚磷酸铵膨胀阻燃聚氨酯泡沫的制备及性能研究[J]. 塑料科技, 2019,47(7):42-45.
WANG Jia'nan, BIAN Yongjun, YI Ying, et al. Study on preparation and properties of PUF intumescent flame retarded by alkali lignin/APP[J]. Plastics Science and Technology, 2019,47(7):42-45.
[20] 杨鑫, 李学敏, 王奉强, 等. 木质素-木粉/高密度聚乙烯复合材料的制备及阻燃性能[J]. 复合材料学报, 2020,37(3):1-10.
YANG Xin, LI Xuemin, WANG Fengqiang, et al. Preparation and flame retardancy of lignin-wood flour/high density polyethylene composites[J]. Acta Materiae Compositae Sinica, 2020,37(3):1-10.
[21] COSTES L, LAOUTID F, AGUEDO M, et al. Phosphorus and nitrogen derivatization as efficient route for improvement of lignin flame retardant action in PLA[J]. European Polymer Journal, 2016,84:652-667.
[22] 张涛, 闫红强, 王丽莉, 等. 基于层层组装法构建阻燃天然纤维素纤维织物的研究进展[J]. 复合材料学报, 2015,32(1):13-20.
ZHANG Tao, YAN Hongqiang, WANG Lili, et al. Research progress on preparation of flame retardant natural cellulosic fiber fabric via layer-by-layer assembly method[J]. Acta Materiae Compositae Sinica, 2015,32(1):13-20.
[23] 魏志彪, 陈希磊. 磷化纤维素和壳聚糖组合层层自组装技术制备棉织物阻燃材料的性能研究[J]. 青岛科技大学学报(自然科学版), 2019,40(1):77-83.
WEI Zhibiao, CHEN Xilei. Flame retardant cotton fabric based on combination of cellulose phosphate and chitosan in layer by layer self-assembly technique[J]. Journal of Qingdao University of Science and Techno-logy(Natural Science Edition), 2019,40(1):77-83.
[24] 吕仲, 杨砚超, 关晋平, 等. 阻燃真丝织物的壳聚糖/磺化木质素/植酸钠层层自组装制备[J]. 印染, 2019,45(17):7-12.
LÜ Zhong, YANG Yanchao, GUAN Jinping, et al. Layer-by-layer self-assembly preparation of flame retardant silk fabric with chitosan/sulfonated lignin/sodium phytate[J]. China Dyeing & Finishing, 2019,45(17):7-12.
[25] SAFI K, KANT K, BRAMHECHA I, et al. Multifunctional modification of cotton using layer-by-layer finishing with chitosan, sodium lignin sulphonate and boric acid[J]. International Journal of Biological Macromolecules, 2020,158:903-910.
pmid: 32360464
[26] 单巨川, 赵天骄, 李盼, 等. 静电层层自组装在棉织物阻燃整理中的应用[J]. 印染, 2018(7):40-44.
SHAN Juchuan, ZHAO Tianjiao, LI Pan, et al. Application of electrostatic layer-by-layer assembly to the flame retardancy of cotton fabrics[J]. China Dyeing & Finishing, 2018(7):40-44.
[27] 郝凤岭, 耿伟涛, 张健, 等. 壳聚糖基阻燃剂的研究进展[J]. 毛纺科技, 2019,47(2):80-85.
HAO Fengling, GENG Weitao, ZHANG Jian, et al. Research progress of chitosan-based flame retar-dants[J]. Wool Textile Journal, 2019,47(2):80-85.
[28] 黄曹兴, 何娟, 梁辰, 等. 木质素的高附加值应用研究进展[J]. 林业工程学报, 2019,4(1):17-26.
HUANG Caoxing, HE Juan, LIANG Chen, et al. Progress in applications of high value-added lignin materials[J]. Journal of Forestry Engineering, 2019,4(1):17-26.
[29] FERRY L, DOREZ G, TAGUET A, et al. Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate[J]. Polymer Degradation and Stability, 2015,113(3):135-143.
doi: 10.1016/j.polymdegradstab.2014.12.015
[30] MENDIS G P, WEISS S G, KOREY M, et al. Phosphorylated lignin as a halogen-free flame retardant additive for epoxy composites[J]. Green Materials, 2016,4(4):150-159.
[31] PRIEUR B, MEUB M, WITTEMANN M, et al. Phosphorylation of lignin to flame retard acrylonitrile butadiene styrene(ABS)[J]. Polymer Degradation and Stability, 2016,127:32-43.
[32] 王楠, 宋艳, 李锦春, 等. 含磷木质素基成炭剂的合成及在阻燃聚丙烯中的应用[J]. 高分子材料科学与工程, 2018,34(4):7-13.
WANG Nan, SONG Yan, LI Jinchun, et al. Synjournal of lignin based charring agent containing phosphorus and its application in flame retardant polypropylene[J]. Polymer Materials Science & Engineering, 2018,34(4):7-13.
[33] 宋艳, 王楠, 李锦春, 等. 有机蒙脱土协同含磷木质素基成炭剂阻燃聚乳酸[J]. 复合材料学报, 2019,36(1):60-68.
SONG Yan, WANG Nan, LI Jinchun, et al. Synergistic effect of organic montmorillonite and lignin-based charring agent with phosphorus on flame retardant poly(lactic acid)[J]. Acta Materiae Compositae Sinica, 2019,36(1):60-68.
[34] FU Rulin, CHENG Xiansu. Xiansu. Synjournal and flame retardant properties of melamine modified EH lignin[J]. Advanced Materials Research, 2011, 236-238:482-485.
doi: 10.4028/www.scientific.net/AMR.236-238
[35] ZHANG Rui, XIAO Xifu, TAI Qilong, et al. Modification of lignin and its application as char agent in intumescent flame-retardant poly(lactic acid)[J]. Polymer Engineering & Science, 2012,52(12):2620-2626.
[36] COSTES L, LAOUTID F, BROHEZ S, et al. Phytic acid-lignin combination: a simple and efficient route for enhancing thermal and flame retardant properties of polylactide[J]. European Polymer Journal, 2017,94:270-285.
[37] ZHOU Shuai, TAO Ran, DAI Peng, et al. Two-step fabrication of lignin-based flame retardant for enhancing the thermal and fire retardancy properties of epoxy resin composites[J]. Polymer Composites. 2020,41(5):2025-2035.
[38] 钟柔潮, 林修端, 黄少淮, 等. 哌嗪改性木质素/磷酸铝双重包覆红磷的制备与阻燃性能[J]. 高分子材料科学与工程, 2019,35(12):143-148,154.
ZHONG Rouchao, LIN Xiuduan, HUANG Shaohuai, et al. Preparation and flame retardancy of piperazine modified lignin/aluminum phosphate double-coated red phosphorus[J]. Polymer Materials Science & Engineering, 2019,35(12):143-148,154.
[39] LIU Lina, QIAN Mengbo, SONG Ping'an, et al. Fabrication of green lignin-based flame retardants for enhancing the thermal and fire retardancy properties of polypropylene/wood composites[J]. ACS Sustainable Chemistry & Engineering, 2016,4(4):2422-2431.
[40] LIU Lina, HUANG Guobao, SONG Ping'an, et al. Converting industrial alkali lignin to biobased functional additives for improving fire behavior and smoke suppression of polybutylene succinate[J]. ACS Sustainable Chemistry & Engineering, 2016,4(9):4732-4742.
[41] WANG Xiu, JI Songlin, WANG Xinqi, et al. Thermally conductive, super flexible and flame-retardant BN-OH/PVA composite film reinforced by lignin nano-particles[J]. Journal of Materials Chemistry C, 2019,7:14159.
[42] CHOLLET B, LOPEZ-CUESTA J M, LAOUTID F, et al. Lignin nanoparticles as a promising way for enhancing lignin flame retardant effect in poly-lactide[J]. Materials, 2019,12(13):2132.
[1] QU Yongshuai, SHI Zhaohe, ZHANG Ruiyun, ZHAO Shuyuan, LIU Liu. Effect of anthraquinone additive on properties of glycol solvent degummed ramie fibers [J]. Journal of Textile Research, 2020, 41(11): 81-88.
[2] MEI Jingxia, ZHANG Nan, WANG Qiang, YUAN Jiugang, FAN Xuerong. Wool anti-felting treatment based on modified protease [J]. Journal of Textile Research, 2019, 40(06): 73-78.
[3] LI Qianglin, HUANG Fangqian, XIAO Xiuchan, QIU Cheng, WU Juzhen. Review on novel halogen-free polymer flame retardants [J]. Journal of Textile Research, 2019, 40(04): 177-184.
[4] . Application of plasma oxidation in hemp fiber degumming [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(07): 75-79.
[5] . Research progress of graphene-plus adsorption and separation functional materials [J]. JOURNAL OF TEXTILE RESEARCH, 2016, 37(10): 162-0169.
[6] . Progress in technologies for functional modifications of cotton fibers [J]. JOURNAL OF TEXTILE RESEARCH, 2015, 36(05): 153-157.
[7] . Acetyl bromide test method for determining amount of lignin in cottonseed coat [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(9): 12-0.
[8] . Performance evaluation of novel thermo color-change and energy-storage materials [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(8): 95-0.
[9] Yong-Bing ZHANG FAN Xue-Rong. Effect of laccase treatment on lignin structure of jute fibers [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(11): 94-0.
[10] FAN Xue-rong;JI Hui-jun;WANG Qiang;TAI Wen-feng. Removing linen/cotton fabric impurities by enzymatic treatment [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(9): 71-74.
[11] QIAN Wei-jun;FENG Xin-xing;CHEN Jian-yong. Influence of the water quality for retting on the hemp degumming effect [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(6): 19-22.
[12] LUO Rong;LIU Bai-ling;ZHANG Hui-zhen;LEI De-song;LI Yuan;WU Yong-zhong. Effects of biodegradation of polyvinyl alcohol by oxidation of the hydroxyl groups with hydrogen peroxide [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(12): 37-40.
[13] YU Chun-hua;FENG Xin-xing;JIA Chang-lan;CHEN Jian-yong. Effect of high temperature degumming of hemp on its composition and structure [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(10): 80-83.
[14] ZHENG Lai-jiu;ZHANG Ning. Research on kenaf pectin detection after bio-scouring [J]. JOURNAL OF TEXTILE RESEARCH, 2005, 26(4): 59-61.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd